Results 111 to 120 of about 24,235 (299)

Electrochemical and Optical Properties of Magnesium-Alloy Hydrides Reviewed

open access: yesCrystals, 2012
As potential hydrogen storage media, magnesium based hydrides have been systematically studied in order to improve reversibility, storage capacity, kinetics and thermodynamics.
Thirugnasambandam G. Manivasagam   +2 more
doaj   +1 more source

Elektroenzymatische CO2‐Fixierung

open access: yesAngewandte Chemie, EarlyView.
Die elektroenzymatische CO2‐Fixierung ermöglicht eine energieeffiziente, hochselektive Synthese komplexer Moleküle. Um ihr volles Potenzial auszuschöpfen, ist ein grundlegendes Verständnis von elektrodengekoppelten Reduktasen und Carboxylasen erforderlich.
Leonardo Castañeda‐Losada   +4 more
wiley   +1 more source

Catalytic Dehydrogenation of Complex Hydrides for Hydrogen Storage

open access: yes, 2010
Catalytic Dehydrogenation of Complex Hydrides for Hydrogen ...
陈萍
core  

Isolation of a Highly Reactive CBNC Heterocumulene via Azidoborylene Photolysis: Facile Access to a Crystalline Dioxaborirane

open access: yesAngewandte Chemie, EarlyView.
Azidoborylene photolysis results in the isolation of a reactive C═B═N═C heterocumulene bearing an ambiphilic boron centre. Addition of 3O2 to this species results in the clean conversion to a unique example of a dioxaborirane. ABSTRACT Oxidation of the formal boron(0) complex MeCAAC2B in the presence of tetrabutylammonium azide leads to the formation ...
Hayley King   +4 more
wiley   +2 more sources

Atomic Energy Commission Report AECD-4049

open access: yes, 1943
Synopsis: Metal Hydrides Incorporated was a pioneer in the production of uranium metal on a commercial scale and supplied it to all the laboratories interested in the original research, before other methods for its production were developed.
Alexander, P. P.
core  

Enantioselective Synthesis of a New Class of Stable and Functionalized Cyclopentadienes via CuH‐Catalysis

open access: yesAngewandte Chemie, EarlyView.
Cyclopentadienes (CpHs) are fundamental building blocks with widespread applications in chemistry. However, their inherent acidity and isomeric instability have long limited access to chiral variants in an asymmetric fashion. Here, we introduce a CuH‐catalyzed asymmetric transformation that provides an unprecedented entry into a new class of ...
Piero Soppelsa   +4 more
wiley   +2 more sources

Magnetic properties and hydrides precipitation observation of nitrogen doping niobium used for accelerator applications

open access: yesResults in Physics, 2019
The results from DC magnetization measurements and direct observation of hydrides precipitation of rectangular bulk nitrogen doping niobium (Nb) samples used for the fabrication of superconducting radio frequency (SRF) cavities were presented.
Ziqin Yang   +5 more
doaj   +1 more source

Specific Ion Effects of Chaotropic and Superchaotropic Anions Probed by Raman Hydration‐Shell Spectroscopy

open access: yesAngewandte Chemie, EarlyView.
The vibrational frequencies of “dangling” water O─H bonds can be determined by Raman hydration‐ shell spectroscopy and used to differentiate chaotropes from kosmotropes and hydrophobes. Dangling O─H bonds are also detected around superchaotropic anions of the borate cluster type (B12X122−; X = H, F, Cl, Br, and I) but their frequencies do not directly ...
Werner M. Nau   +6 more
wiley   +2 more sources

Complex Hydrides

open access: yes, 2010
Complex hydrides are salt-like materials in which hydrogen is covalently bound to the central atoms, in this way a crystal structure consisting of so-called "complex anions" is formed.
Weidenthaler, C., Felderhoff, M.
core  

1,7‐Digallatetracarborane: Between Nucleophilic closo‐Cluster and “Inverse Sandwich” Digallylene

open access: yesAngewandte Chemie, EarlyView.
A dianionic π‐ligand is used to make a Janus‐type twofold complex with low‐valent gallium Ga(+I). The resulting compound can be seen as and reveals the reactivity of both: a Wade‐type closo‐carborane cluster with nucleophilic Ga‐sites, as well as π‐ligand stabilized Ga(I) atoms in an inverse sandwich compound.
Julijan Sarcevic   +4 more
wiley   +2 more sources

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