Results 111 to 120 of about 28,089 (235)
InorganicsWe report the synthesis, characterisation and reactivity of the stable imidazol-2-ylidene EtIDip (EtIPr), {EtCN(Dip)}2C:, Dip = 2,6-iPr2C6H3, as a chemically robust alternative to IDip (IPr), {HCN(Dip)}2C:.
Huanhuan Dong +7 more
doaj +1 more source
, 2010 Complex hydrides are salt-like materials in which hydrogen is covalently bound to the central atoms, in this way a crystal structure consisting of so-called "complex anions" is formed.
Weidenthaler, C., Felderhoff, M.
core
Addition of Nitrogen-Containing Heteroallenes to Iron(II)-Hydrides
, 2016 The reactions between cis-Fe(dmpe)2H2 (dmpe = Me2PCH2CH2PMe2) (1) or cis-Fe(PP3)H2 (PP3 = P(CH2CH2PMe2)3) (2) and phenyl isothiocyanate (PhNCS), ethyl isothiocyanate (EtNCS), and phenyl isocyanate (PhNCO) were investigated.
Leslie D. Field (1599472) +2 more
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Advanced Intelligent Discovery, EarlyView.Recent advances in TiO2 modification strategies: structure regulation and composite engineering for improved activity and functionality. TiO2 has emerged as a pivotal catalyst for enhancing MgH2, a high‐capacity solid‐state hydrogen storage material, owing to its structural versatility.
Xiaopeng Chu +10 more
wiley +1 more source
Angewandte Chemie, EarlyView.Electrosynthesis of ammonia from nitrogen gas and water at ambient temperature is demonstrated using a device equipped with an electrochemical palladium membrane, which provides exclusive selectivity for the transfer of protons between the aqueous water oxidation and non‐aqueous nitrogen reduction compartments.
Ngoc‐Trung Nguyen +11 more
wiley +2 more sources
Structure and phase transitions of unstable metal hydrides and hydrides of intermetallic compounds
, 1992 The investigation is concerned with metal hydrides of YI, YII, YIII groups, Laves phases and beta -phases. The object to be attained is structural investigation and development of the concept of constructing complex hydrides.
Irodova Alla Byacheslavovna
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, 2017 This thesis is an investigation into the hydrogenous behavior of Zintl phases. Zintl phases are comprised of an active metal (i.e alkali, alkaline earth, and rare earth) and a p-block element.
Kranak V, Kranak, Verina
core +1 more source
Cobalt‐Catalyzed C─N Bond Formation via Metal‐Hydride Hydrogen Atom Transfer (MHAT)
Angewandte Chemie, EarlyView.Cobalt‐catalyzed metal‐hydride hydrogen atom transfer (Co‐MHAT) converts simple alkenes into C─N bonds under mild, near‐neutral conditions. A shared Co─H‐initiated radical/organocobalt intermediate is channeled into radical trapping, radical‐polar crossover, or radical ligand transfer, unifying hydroamination, hydroazidation, hydroamidation, and remote
Arman Khosravi, Ming‐Yu Ngai
wiley +2 more sources
Double Reduction of Ph3B to a Dianionic Borane With a Powerful SrI Intermediate
Angewandte Chemie, EarlyView.Although dianionic boranes follow the octet rule and are isoelectronic to carbanions or amines, the high electron density combined with the electropositive nature of the B center make them highly unstable species. In this study, we present synthesis and full characterization of a complex in which Ph3B2− is sandwiched between two Sr2+ ions and describe ...
Michael Morasch +4 more
wiley +2 more sources
Шәкәрім университетінің хабаршысы: Техника ғылымдарThe article provides an overview of a number of studies on the use of alloys and intermetallic compounds for hydrogen storage. Among them, a particularly important place is occupied by the inter-metallic compound LaNi₅ eye. The latest achievements in the
M. Skakov, N. Mukhamedova, A. Nassyrova
doaj +1 more source