Results 121 to 130 of about 106,840 (308)

Radical Cascade Combining Cross‐Olefin Coupling with the Smiles‐Truce Rearrangement

Angewandte Chemie International Edition, EarlyView.
We present a cobalt‐catalysed radical cascade that efficiently merges two alkene starting materials to form multiple bonds in a single step. The process begins with a cobalt‐catalysed hydrogen‐atom transfer‐to a styrene double bond, followed by a Giese addition.
Jingyang Qin, Lucas Popek, Moritz Wyrtki, Christopher J. Teskey   +3 more
wiley   +1 more source

Data-driven design of high pressure hydride superconductors using DFT and deep learning

Materials Futures
The observation of superconductivity in hydride-based materials under ultrahigh pressures (for example, H _3 S and LaH _10 ) has fueled the interest in a more data-driven approach to discovering new high-pressure hydride superconductors. In this work, we
Daniel Wines, Kamal Choudhary
doaj   +1 more source

Theoretical Study on the Dynamical Stability, Chemical Bonding, and Electronic Properties of LaBH8 and LaBeH8 Under Pressure

Advanced Physics Research
LaBH8 and LaBeH8, as typical Fm‐3m XYH8‐type hydrides, are predicted with outstanding superconductivity below megabar pressure. Notably, LaBeH8 has been successfully synthesized with the predicted XYH8‐type structure and measured to have a critical ...
Xiaokuan Hao, Xudong Wei, Xiaoxu Song, Jingyu Niu, Cheng Lu, Lin Wang, Guoying Gao, Yongjun Tian   +7 more
doaj   +1 more source

Aluminum versus Gallium: Differences in Bis(bis(trimethylsilyl)methyl) Element Halides, Hydrides, and Oxygen‐Bridged E/P Frustrated Lewis Pairs

ChemistryEurope
Extremely sterically demanding bis(bis(trimethylsilyl)methyl)‐substituted aluminum and gallium compounds are particularly suitable for applications in frustrated Lewis pair (FLP) chemistry. A selective exchange reaction between Bis2GaBr (Bis = CH(SiMe3)2)
Julian Buth, Maximilian J. Klingsiek, Yury V. Vishnevskiy, Andreas Mix, Jan-Hendrik Lamm, Beate Neumann, Hans-Georg Stammler, Norbert Werner Mitzel   +7 more
doaj   +1 more source

Geminal Difunctionalization of Ketones via C─S Bond Insertion of Photogenerated Donor–Donor Diazo Compounds

Angewandte Chemie International Edition, EarlyView.
Geminal difunctionalization of readily available building blocks provides rapid access to molecular complexity. This work introduces a strategy for installing two distinct functional groups on a carbonyl carbon by transforming it into a donor–donor diazo compound, enabling both batch and flow applications with broad solvent compatibility.
Vincent George, Aryaman Pattanaik, Daniel Maddox, Lukas M. Sigmund, Giovanna Mejia, Sara Pahlén, Simon O. Angerer, Maria Schmoll, Lisa Marie Schneider, Nidhal Selmi, Mikhail Kabeshov, Giulia Bergonzini, Julia Rehbein, Burkhard König   +13 more
wiley   +1 more source

Introduction: Metal Hydrides [PDF]

Chemical Reviews, 2016
Jack R, Norton, John, Sowa
openaire   +2 more sources

Forcing the Side‐on π‐Coordination of a C≡C Triple Bond to Technetium Using the As,CC,As Alkyne Pincer Ligand 1,2‐Bis(2‐(diisopropylarsaneyl)‐4‐(trifluoromethyl)phenyl)Ethyne

Angewandte Chemie International Edition, EarlyView.
Technetium alkyne complexes have eluded isolation for decades with the only indicators for their existence being the isolation of vinylidene carbenes or their follow‐up reaction products despite plentiful of reports for neighboring elements. Stable, crystalline Tc(III) and Tc(V) alkyne complexes (and their Re analogs) have now been prepared and fully ...
Maximilian Roca Jungfer, Moritz Johannes Ernst, Lukas Eberle, Marius Kesselring, Guilhem Claude, Joachim Ballmann   +5 more
wiley   +1 more source

Hydrides [PDF]

Nature, 1971
openaire   +1 more source

Integrating agro‐residue valorization and clean hydrogen production: coconut fiber‐based catalysts for NaBH4 hydrolysis

Biofuels, Bioproducts and Biorefining, EarlyView.
Abstract A novel phosphoric acid‐treated green coconut fiber (GCF‐C) was developed as a catalyst for hydrogen production from the hydrolysis of sodium borohydride (NaBH4). Characterization techniques confirmed structural modifications, including X‐ray diffraction, scanning electron microscopy, X‐ray fluorescence, Fourier transform infrared, and ...
Isabelly Silveira Freitas, Francisco Izaias da Silva Aires, Dayana Nascimento Dari, Jacob Tchiyeke António Kandjila, Maurício Quintas Salamba, Diego Lomonaco, Monalisa Moura de Oliveira, Pierre Basílio Almeida Fechine, Rafael Leandro Fernandes Melo, Alan Silva de Menezes, Marcos Carlos de Mattos, Leonardo Farias Serafim, Maria Cristiane Martins de Souza, Ada Amelia Sanders Lopes, John Herbert da Silva Felix, Eveline de Abreu Menezes, José Cleiton Sousa dos Santos   +16 more
wiley   +1 more source

Engineering of CoA‐Acylating Butyraldehyde Dehydrogenase for Enhanced 1,3‐Butanediol Production in Escherichia coli

Biotechnology and Bioengineering, EarlyView.
ABSTRACT Microbial production of 1,3‐butanediol (1,3‐BDO) offers a renewable route to this versatile C4 chemical. However, the low performance of CoA‐acylating butyraldehyde dehydrogenase (Bld), which contains a catalytic cysteine, limits efficient production in recombinant Escherichia coli (E. coli).
Seunghyun Cho, Tayyab Islam, Sobia Islam, Junhak Lee, Sung Won Jung, Sunghoon Park   +5 more
wiley   +1 more source