Results 141 to 150 of about 28,089 (235)

1,2‐Bis(boronate) Arenes by Borylation Directed Borylation

Angewandte Chemie, EarlyView.
Boron electrophiles derived from tetrabromo‐pyrazaboles and AlCl3 affect the regioselective vicinal double C–H borylation of a range of arenes and polycyclic aromatic hydrocarbons (PAHs). A subsequent pinacol installation step then affords the vicinal bis‐boronate ester‐substituted arene/PAH.
Anna V. Schellbach, Mathew J. Cross, Emily Noone, Cate S. Anstöter, Michael J. Ingleson   +4 more
wiley   +2 more sources

Dialkyl Ethers and Sacrificial Zinc: Oxide Synthons for Calcium tert‐Butoxide Formation

Angewandte Chemie, EarlyView.
When treated with dialkyl ethers, [(BDI)Ca‐μ‐H‐Zn(t‐Bu)2(η6‐C7H8)] (BDI = HC{C(Me)NDipp}2 initiates a sequence of twofold ether dealkylation and oxide sequestration as tert‐butoxide in a process predicated on a combination of extreme basicity and a cooperative redox process administered by the dissimilar constituent metals. (Generative AI (ChatGPT) was
Kyle G. Pearce, Agustín Morales, Michael S. Hill, Claire L. McMullin   +3 more
wiley   +2 more sources

DFT and AIMD insights into the stability and hydrogen storage performance of Na₂XH₆ (X = Cr, Mn, and Fe) perovskite hydrides. [PDF]

RSC Adv
Kaleem M, Kanwal S, Khan AN, Illahi A, Parveen A, Abbas Z, Mera A.   +6 more
europepmc   +1 more source

Solid-state hydrogen storage in metal hydrides: mechanistic insights into kinetics, activation, and destabilization strategies. [PDF]

RSC Adv
Qayyum MN, Majid A, Raza MT.
europepmc   +1 more source

Designing Ambient Pressure Superconductivity in Li-Mg-Based Hydrides via Transition-Metal Modulation: From Quaternary to Quinary Systems. [PDF]

Materials (Basel)
Wang X, Wei Q, Luo J, Zhang M.
europepmc   +1 more source

Entdeckung der cyclischen Form des MRT‐pH‐Sensors Z‐OMPD ermöglicht >5% 13C‐Hyperpolarisation durch SABRE

Angewandte Chemie, EarlyView.
Mit „c‐OMPD“ entdeckten wir eine bislang unbekannte fünfgliedrige Lactolstruktur, die durch Homoaldolkondensation des zentralen Metaboliten Brenztraubensäure entsteht. Wir zeigen, dass das Cyclisierungsgleichgewicht für die Funktion von OMPD als MRT‐basierte pH‐Sonde von entscheidender Bedeutung ist, und erreichen erstmals eine 13C‐Polarisation von >5 %
Juanita Ferreira, Ivan A. Trofimov, Martin Grashei, Adriana Sacristán‐Martín, Alexander Huber, David Schleicher, Oleksiy Khavryuchenko, Franz Schilling, Andreas B. Schmidt, Max von Delius   +9 more
wiley   +1 more source

First principles exploration of high hydrogen storage capacity of lithium-based perovskite hydrides. [PDF]

J Mol Model
Geldasa FT, Dejene FB.
europepmc   +1 more source

Hydrogen storage in metal and complex hydrides

, 2010
A promising alternative to hydrogen storage in high pressure cylinders and cryogenic tanks is the hydrogen storage in solid form as metal hydrides or complex metal hydrides. However, much research is still necessary in this direction.
Agresti F
core  

Up and Down the Hill-Plot: Hydrides of CeGe-Structure and Magnetism. [PDF]

Inorg Chem
Dorsch LY, Haferkorn N, Baldauf JA, Michak M, Hansen TC, Pöttgen R, Kohlmann H.   +6 more
europepmc   +1 more source

High-Pressure Synthesis of Quantum-Stabilised Manganese Superhydride MnH₇. [PDF]

Angew Chem Int Ed Engl
Kuzovnikov MA, Shuttleworth HA, Osmond I, Hu H, Meskauskaite E, Chen B, Stevens C, Huxley A, Hermann A, Peña-Alvarez M, Howie RT.   +10 more
europepmc   +1 more source