Results 151 to 160 of about 106,840 (308)

Arene Incorporation and Ring Expansion in the Thermal Decomposition of a Divanadium(III) Complex With Four Bridging Methyl Groups

Chemistry – A European Journal, EarlyView.
Thermolysis of [{VCp*(µ‐CH3)2}2] (Cp* = η5‐C5Me5) in hexane leads to a tetranuclear cube‐type methylidene complex [{VCp*(µ3‐CH2)}4], while in benzenic solvents C6H5R produces the formal insertion of a CH fragment into the six‐membered aromatic ring of a solvent molecule to give trovacene derivatives with η7‐cycloheptatrienyl ligands [VCp*(η7‐C7H6R ...
Adrián Calvo‐Molina, Rodrigo González‐Prieto, Jesús Jover, Adrián Pérez‐Redondo, José Luis Priego, Carlos Yélamos   +5 more
wiley   +1 more source

Synthesis of high-entropy hydride from the cantor alloy (fcc-CoCrFeNiMn) at extreme conditions. [PDF]

Nat Commun
Glazyrin K, Spektor K, Bykov M, B Carvalho PH, Dong W, Körmann F, Sano-Furukawa A, Hattori T, Beyer DC, Sahlberg M, Ikeda Y, Yu JH, Sangsun Y, Lee JS, Bhat S, Hanfland M, Grabowski B, Divinski S, Yusenko KV.   +18 more
europepmc   +1 more source

Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth‐Ligand Cooperation

Chemistry – A European Journal, EarlyView.
ABSTRACT Over the past twenty years, main group chemistry has significantly expanded its scope to include reactivities once considered the exclusive domain of transition metals. Among the emerging concepts, element‐ligand cooperation has proven to be a powerful strategy for enabling bond activation reactions but remains relatively unexplored for ...
Lennart Hensle, Viktoria H. Gessner
wiley   +1 more source

Hydrogen storage capacity, strain-improved formation enthalpy, desorption temperature, and high energy harvesting performance of SrGaH₅. [PDF]

RSC Adv
Shahzadi S, Ibrahim A, Nazir S.
europepmc   +1 more source

Synthesis of 1‐Alkynylboronates, 1,1‐Diborylalkenes, and 1,1,1‐Triborylalkanes: Challenges and Opportunities

Chemistry – A European Journal, EarlyView.
ABSTRACT In the field of organoboron chemistry, multi(boronate) esters have emerged as crucial intermediates, with various applications in synthetic chemistry, material technology, and life sciences. This mini‐review discusses recent advancement in the synthesis of these versatile compounds, particularly alkynylboronates, 1,1‐diborylalkenes, and 1,1,1 ...
Son Hoai Doan, Vu Nguyen Tran, Thanh Vinh Nguyen   +2 more
wiley   +1 more source

A Crystalline In(II) Hydride. [PDF]

J Am Chem Soc
Mouriki O, Tizzard GJ, Coles SJ, Andrada DM, Planas O.   +4 more
europepmc   +1 more source

Metal Nanoparticles on Halloysite Applied in Stereoselective Hydrogenation of Tetrasubstituted Alkenes

Chemistry – A European Journal, EarlyView.
Composite materials based on metal nanoparticles supported on a naturally occurring nanotubular clay, halloysite (HAL), led to the diastereoselective hydrogenation of tetra‐substituted alkenes under relatively smooth conditions, mainly oxazolidinone‐based heterocycles.
Rosa Pich, Gabriel Domínguez, Leo Westrey, Pierre Lavedan, Sonia Mallet‐Ladeira, Jérôme Esvan, Jean‐François Lahitte, Jean‐Christophe Remigy, Daniel Pla, Montserrat Gómez   +9 more
wiley   +1 more source

Cu₁₄H₁₂(P<i>^t</i>Bu₃)₆Cl₂-The Expanse of Stryker's Reagent. [PDF]

Molecules
Strienz M, Kimmich R, Conzelmann A, Schnepf A.   +3 more
europepmc   +1 more source

Asymmetric Reduction of Unactivated Alkenes

Chemistry – A European Journal, EarlyView.
Unactivated alkenes rank among the most inert functional groups in synthesis and their selective reduction remains challenging. This Review charts the evolution from classical metal‐catalyzed hydrogenation to radical hydrogen atom transfer (HAT) and emerging biocatalytic concepts, highlighting how complementary mechanistic strategies, including the ...
Nico D. Fessner, Sebastian Roth, Richard Niese, Michael Müller   +3 more
wiley   +1 more source

Formation of Molybdenum Deuteride at High Pressure: A Neutron Diffraction Study. [PDF]

Inorg Chem
Wei Z, Funnell NP, Ridley CJ, Klotz S, Pulham CR, Bull CL.   +5 more
europepmc   +1 more source