Results 161 to 170 of about 106,840 (308)

Unlocking Heterobimetallic Architectures in a Symmetric PNNP Ligand Environment

Chemistry – A European Journal, EarlyView.
A symmetric PNNP ligand enables the modular assembly of heterobimetallic ZnRu and CoRu complexes from a mononuclear Ru(II) precursor. Ligand deprotonation triggers dearomatization and contraction of the metal–metal distance. Combined DFT and QTAIM analyses reveal metallophilic interaction in CoRu but not in ZnRu, highlighting controllable geometric and
Stanislav Melnikov, Menne W. P. Verkooijen, Jop Verduin, Martin Lutz, Daniël L. J. Broere   +4 more
wiley   +1 more source

Self-modulated hydrogen electrocatalysis on sub-2-nm platinum nanoparticles by in situ generated surface hydrides. [PDF]

Nat Commun
Chang L, Shao Y, Miao L, Jiang Y, Lu Q, Wang S, Kang F, Li J, Gan L.   +8 more
europepmc   +1 more source

Relationships between Carbonyl Hydride Clusters and Interstitial Hydrides [PDF]

, 1978
P. Chini, G. Longoni, S. Martinengo, A.Ceriotti   +3 more
openaire   +2 more sources

Alkene Hydrogenation by a Cationic, Nine‐Coordinate Molybdenum(VI) Pentahydride Catalyst

Chemistry – A European Journal, EarlyView.
While late 3d metals dominate efforts to replace precious metals in homogeneous hydrogenation, molybdenum has remained largely ignored. This work reveals that a nine‐coordinate pentahydrido molybdenum complex can hydrogenate a broad range of alkenes efficiently, demonstrating that early‐metal polyhydrides can serve as genuine catalysts rather than mere
Arno Estival, Michel Sigrist, Nicolas Queyriaux, Jorge J. Cabrera‐Trujillo, Nina Durvin, Marie‐Christine Boegli, Laure Vendier, Mary Grellier, Karinne Miqueu, Antoine Simonneau   +9 more
wiley   +1 more source

Influence of B'-site vacancy on hydrogen storage, structural, elastic, thermodynamic and optoelectronic attributes of potassium based double perovskite K₂LiAlH₆hydride for green energy applications. [PDF]

Sci Rep
Murtaza H, Habib MA, Ain Q, Kumar A, Munir J, Ibrahim ABM, Oza AD, Al-Salimi MSS.   +7 more
europepmc   +1 more source

Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides.

Chemical Reviews, 2016
D. Schilter, James M. Camara, Mioy T. Huynh, S. Hammes‐Schiffer, T. Rauchfuss   +4 more
semanticscholar   +1 more source

Iridium Complexes of a Triazole‐Derived Pincer Ligand: Synthesis, Reactivity, and Transfer Dehydrogenation Catalysis

Chemistry – A European Journal, EarlyView.
Ir pincer complexes bearing a triazole architecture in the pincer backbone and O‐ancillary chelating ligands are presented. These were employed in the catalytic transfer dehydrogenation of alkanes as well as of saturated heterocycles. Reactivity of these complexes with silver salts and Lewis acids produced various cationic iridium complexes.
Jesvita Cardozo, Ouchan He, Aaron Prenzlow, Xinyang Peng, Kallol Ray, Thomas Braun   +5 more
wiley   +1 more source

Physically interpretable descriptors drive the materials design of metal hydrides for hydrogen storage. [PDF]

Chem Sci
Jang SH, Zhang D, Tran HB, Jia X, Konno K, Sato R, Orimo SI, Li H.   +7 more
europepmc   +1 more source

Iridium‐Catalyzed Linear‐Selective sp3 C−H Alkylation of N‐Methylamides Using Alkenes Enabled by Diphosphite Ligands

Chemistry – A European Journal, EarlyView.
An iridium‐catalyzed linear‐selective sp3 C─H alkylation of N‐methylamides with alkenes is described. This method tolerates various N‐methylacetamide derivatives and has a broad alkene scope. Mechanistic studies were also conducted. Internal alkenes can also be used through in situ consecutive alkene isomerization.
Haluhi Takahashi, Takanori Shibata
wiley   +1 more source

Solvent-temperature coupled hydride transfer controls product selectivity in the HSiR₃/KO ^<i>t</i> Bu catalytic system. [PDF]

Chem Sci
Yao H, Zhou Z, Liu Y, Zhang DH, Li G.
europepmc   +1 more source