Results 171 to 180 of about 106,840 (308)

A General Strategy for the Synthesis of Jerangolids Enabled by π‐allyl Stille Coupling

open access: yesChemistry – A European Journal, EarlyView.
A general strategy for the synthesis of jerangolids is established, featuring a late‐stage π‐allyl Stille coupling of two advanced, highly customizable building blocks to form the skipped diene core. The approach provides access to all naturally occurring jerangolids, including jerangolid H, whose configuration is confirmed by NMR analysis.
Janick Schug   +2 more
wiley   +1 more source

Amine‐Triggered Azabenz‐Annulation of Cyclic Secondary Amine‐Functionalized Perylene Diimides for Dual‐Mode Sensing

open access: yesChemistry – A European Journal, EarlyView.
Pictet‐Spengler Intermediate of a cyclic secondary amine perylene diimide undergoing amine‐triggered conversion to azabenz‐annulated perylene diimide, inducing a high‐contrast green‐to‐yellow color change along with fluorescence turn‐on, demonstrating intuitive “safe” to “warning” dual‐mode sensing.
Irene E. Park   +2 more
wiley   +1 more source

Simple s-block metal hydrides for selective hydrogenation of quinoline compounds. [PDF]

open access: yesChem Sci
Zhang S   +8 more
europepmc   +1 more source

Thermodynamic Hydricity of Transition Metal Hydrides.

open access: yesChemical Reviews, 2016
Eric S. Wiedner   +5 more
semanticscholar   +1 more source

[Ti(py)4I2] as an Entry Point to Titanium(II) Chemistry via Titanium Metal Oxidation

open access: yesChemistry – A European Journal, EarlyView.
A strategically novel approach based on the oxidation of Ti metal enables access to Ti(II) chemistry. Controlled formation and complexation of Ti diiodide affords the Ti(II) complex [Ti(py)4I2], which serves as a convenient entry point to Ti(II) compounds.
Alexander Sedykh
wiley   +1 more source

"DIVE" into hydrogen storage materials discovery with AI agents. [PDF]

open access: yesChem Sci
Zhang D   +10 more
europepmc   +1 more source

Monosubstituted N‐Arylhydroxylamine Chemistry: Integrating Contemporary Synthetic Approaches for the Efficient Construction of Diverse Heterocyclic Scaffolds

open access: yesChemistry – A European Journal, EarlyView.
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis   +2 more
wiley   +1 more source

State‐of‐the‐Art and Synthetic Challenges for Hydrosilane Production

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of hydrosilanes is currently energy intensive and their recycling is not considered. However, these compounds are important in many industrial fields but also for the valorization of oxygenated waste, towards a circular economy. This review compares the available synthetic routes and highlights the remaining challenges for the production ...
Gabriel Durin   +3 more
wiley   +1 more source

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