A General Strategy for the Synthesis of Jerangolids Enabled by π‐allyl Stille Coupling
A general strategy for the synthesis of jerangolids is established, featuring a late‐stage π‐allyl Stille coupling of two advanced, highly customizable building blocks to form the skipped diene core. The approach provides access to all naturally occurring jerangolids, including jerangolid H, whose configuration is confirmed by NMR analysis.
Janick Schug +2 more
wiley +1 more source
An approach towards next-generation hydrogen storage: a DFT study on A<sub>2</sub>LiTiH<sub>6</sub> (A = K, Ca) perovskite hydrides. [PDF]
Ullah MA +7 more
europepmc +1 more source
Pictet‐Spengler Intermediate of a cyclic secondary amine perylene diimide undergoing amine‐triggered conversion to azabenz‐annulated perylene diimide, inducing a high‐contrast green‐to‐yellow color change along with fluorescence turn‐on, demonstrating intuitive “safe” to “warning” dual‐mode sensing.
Irene E. Park +2 more
wiley +1 more source
Simple s-block metal hydrides for selective hydrogenation of quinoline compounds. [PDF]
Zhang S +8 more
europepmc +1 more source
Thermodynamic Hydricity of Transition Metal Hydrides.
Eric S. Wiedner +5 more
semanticscholar +1 more source
[Ti(py)4I2] as an Entry Point to Titanium(II) Chemistry via Titanium Metal Oxidation
A strategically novel approach based on the oxidation of Ti metal enables access to Ti(II) chemistry. Controlled formation and complexation of Ti diiodide affords the Ti(II) complex [Ti(py)4I2], which serves as a convenient entry point to Ti(II) compounds.
Alexander Sedykh
wiley +1 more source
"DIVE" into hydrogen storage materials discovery with AI agents. [PDF]
Zhang D +10 more
europepmc +1 more source
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis +2 more
wiley +1 more source
Tailoring hydrogenation, thermodynamic properties and oxidation resistance of TiFe alloy by only regulating the stoichiometric ratio of Ti and Fe elements. [PDF]
Xia S +8 more
europepmc +1 more source
State‐of‐the‐Art and Synthetic Challenges for Hydrosilane Production
The synthesis of hydrosilanes is currently energy intensive and their recycling is not considered. However, these compounds are important in many industrial fields but also for the valorization of oxygenated waste, towards a circular economy. This review compares the available synthetic routes and highlights the remaining challenges for the production ...
Gabriel Durin +3 more
wiley +1 more source

