Results 201 to 210 of about 28,089 (235)

Ni2‐Imido Bispincer Platforms: Cooperative Reactivity Enabled Through Substrate Addition Across a Ni2N Unit

Chemistry – A European Journal, EarlyView.
Ni2 bispincer complexes with an embedded central imido anchor are presented. The bispincer complexes leverage the high basicity of imido ligands to facilitate 1,2 addition of weak B─H and Si─H bonds, resulting in hydrido–amido complexes and resultingly a contortion of a Ni─Ni sigma bond to form an S = 1 species. The 1,2 addition is proposed to serve as
David de los Santos, Kritika Gour, Manar M. Shoshani   +2 more
wiley   +1 more source

π‐Extended Salphen Scaffolds Enable CO2 Electroreduction and Singlet Oxygen Generation

Chemistry – A European Journal, EarlyView.
New family of π‐extended salen ligands bearing phenylene bridge and tunable phenyl‐based substituents, and their corresponding boron difluoride complexes. Thanks to the extended π‐delocalization over the molecule, the ligands themselves show promising results in electrochemical CO2 reduction to CO, while the complexes act as efficient photosensitizers ...
Vincenzo Langellotti, André Korzun, Morgan J. McKee, Massimo Melchiorre, Taegeun Jo, J. Felipe Estrada‐Ruiz, Gregor Schnakenburg, Stefano Crespi, Francesco Ruffo, Nikolay Kornienko, Alessandro Bismuto   +10 more
wiley   +1 more source

Hydrogen storage potential of cubic InXH₃ (X = Be, Mg, Ca, Sr, Ba, Ra) hydride perovskites: a comprehensive first principles investigation. [PDF]

Sci Rep
Amin AB, Naeem H, Rizwan M, Usman Z, Wang Y.   +4 more
europepmc   +1 more source

Silica‐Supported Mononuclear Methyl‐Platinum Complexes Stabilized by Trimethylphosphine—Synthesis, Structure, and Reactions Under Reducing Conditions

Chemistry – A European Journal, EarlyView.
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz, Sven Schaefer, Oksana Storcheva, Gabriele Raudaschl‐Sieber, Johannes Bitzer, Wolfgang Kleist, Klaus Köhler   +6 more
wiley   +1 more source

Pyridinium amidate (PYA) substituents impact ligand-centered hydride formation and (catalytic) hydride transfer reactivity.

Dalton Trans
Monte L, Lentz N, Albrecht M.
europepmc   +1 more source

Computational analysis of X₂CaZnH₆ (X = K, Rb and Cs) hydrides for hydrogen storage. [PDF]

Sci Rep
Al-Zoubi N, Almahmoud A, Almahmoud A, Jaradat A, Obeidat A.   +4 more
europepmc   +1 more source

Expanding the Scope of Indium in Frustrated Lewis Pair Chemistry

Chemistry – A European Journal, EarlyView.
All good things come in threes: The pyridine‐“protected” FLP tBu2InCH2PtBu2·Py shows three different kinds of reactivity: Besides “typical” FLP activity, it prefers formation of the “soft” isomers for substrates with multiple sites for FLP attack, but reacts with SO2 as a “masked” In/C FLP by insertion into the In─C bond.
Daniel N. Heuer, Jan‐Hendrik Lamm, Beate Neumann, Andreas Mix, Yury V. Vishnevskiy, Norbert W. Mitzel   +5 more
wiley   +1 more source

Density functional study of barium and strontium boron hydrides for hydrogen storage and optoelectronic applications. [PDF]

Sci Rep
Kumar A, Etabti H, Kumar K, Kumar A.
europepmc   +1 more source

Iridium-Catalyzed Diorganosilylene Insertion into C(sp²)-O Bond of Oxacycles Using Aryldiorganosilanes as Silylene Transfer Reagents. [PDF]

ACS Cent Sci
Song Y, Suginome M.
europepmc   +1 more source

Computational discovery of high-temperature superconducting ternary hydrides via deep learning. [PDF]

Natl Sci Rev
Wang X, Zhang C, Wang Z, Liu H, Lv J, Wang H, Weinan E, Ma Y.   +7 more
europepmc   +1 more source