Results 211 to 220 of about 106,840 (308)

Hydride Nitrides: Crystal Structure Redetermination of LiSr2H2N and the Isostructural LiBa2H2N

European Journal of Inorganic Chemistry, EarlyView.
The quaternary hydride nitrides LiSr2H2N and LiBa2H2N are obtained in a non‐centrosymmetric crystal structure, different from previous reports. Crystal growth of the honey‐ and pale‐yellow compounds and essentially single phase synthesis is successful using alkali metal flux. The resulting fully ordered structures do not account for a structural reason
Chen Liang, Rainer Niewa
wiley   +1 more source

The path to room-temperature superconductivity: A programmatic approach. [PDF]

Proc Natl Acad Sci U S A
Prasankumar RP, Julian M, Hutcheon M, Heil C, Deng L, Basov D, Chu CW, Comin R, Kim P, Meredig B, Pickard C, E Pickett W, Strobel T, Wolf S, Zurek E, Myhrvold N.   +15 more
europepmc   +1 more source

Rational Optimization of Self‐Reporting Alcohol‐Oxidizing RhIII$^{\mathrm{III}}$ Complexes

European Journal of Inorganic Chemistry, EarlyView.
A series of four different [(NN)Rh(Cp*)X]n+$^{\mathrm{n+}}$ complexes (NN = chelating α$\alpha$‐diimine ligand, Cp* = pentamethylcyclopentadienyl, X = Cl, solvent) are reported which all do possess a colorimetric self‐reporting property upon alcohol oxidation formation of the Rh(I) state. Analysis of alcohol oxidation rates
Luca Hefty, Giada Caniglia, Muhammed Abdel‐Hamied, Alexander K. Mengele, Christine Kranz, Sven Rau   +5 more
wiley   +1 more source

Identification of Au-hydrides as key intermediates in the reduction of Au(iii) prodrugs to active Au(i) species under protic conditions. [PDF]

Chem Sci
Ochs J, Metzler-Nolte N.
europepmc   +1 more source

Masked Silylenes: Controlled Generation and Reactivity Under Thermal and Equilibrium Conditions

European Journal of Inorganic Chemistry, EarlyView.
This Review provides an overview of masked silylenes as bench‐stable precursors that release silylenes (R2Si:) under thermal activation or reversible equilibria. Precursor preparation, generation pathways, and characteristic reactivity are summarized, including trapping chemistry, reversible interconversions, insertion‐type processes, and small ...
Kei Ota, Kanata Miyahara, Norio Nakata
wiley   +1 more source

Structural, Mechanical, Electronic, and Optical Properties of Hydrogen-Storage Magnesium-Based Mg₂XH₉ (X = Cs, Rb). [PDF]

Materials (Basel)
Li W, Wei Q, Luo J, Jia X, Zhang M, Zhu X.   +5 more
europepmc   +1 more source

From Phosphinimines to Four‐Membered SiCPN Cations: Insights Into N–Si Bonding and Ring Strain

European Journal of Inorganic Chemistry, EarlyView.
Sterically tuned N‐silyl phosphinimines enable four‐membered SiCPN cations. Hydride abstraction yields cyclic cations for Me and iPr substituents at silicon, while tBu gives a protonated intermediate. Multinuclear NMR spectroscopy, X‐ray crystallography, thermochemical density functional theory investigations, and natural bond orbital analyses reveal ...
Alexander Falk, Jonathan O. Bauer
wiley   +1 more source

Crystal Structure of the High-Pressure Phase of Ca(BH₄)₂ and Further Structural Changes up to 70 GPa. [PDF]

Inorg Chem
Nakano S, Fujihisa H, Yamawaki H, Shibazaki Y, Kikegawa T, Orimo SI.   +5 more
europepmc   +1 more source

Ligand‐Level Chemical Activation: Coordination with Benefits

European Journal of Inorganic Chemistry, EarlyView.
While often perceived as a liability, ligand‐based reactivity in carefully designed settings becomes a powerful synthetic tool. The key to streamlined processes overriding classical ionic reactivity is the selective electron redistribution induced by metal coordination. This enables storage of electrons and protons or incorporation of functional groups
Oscar Charpentier, Agnideep Das, Marine Desage‐El Murr   +2 more
wiley   +1 more source

Hydrogen storage performance of Ti_0.75Zr_0.25Mn_0.9CrFe_0.1 alloy with different preparation methods. [PDF]

RSC Adv
Mu Y, Zhou Y, Yang G, Xu L, Xu H, Zhu L, Han X, Chu X, Liu W, Lv L.   +9 more
europepmc   +1 more source