Results 71 to 80 of about 3,896 (225)

Electrophilic fluorination at saturated carbon [PDF]

, 2000
Chapter 1 - Chapter 1 contains a discussion of the preparation and properties of elemental fluorine. A review of the use of elemental fluorine as a selective fluorinating in organic chemistry is given and the preparation and use of other selective ...
Parsons, Mandy
core  

Characteristics, properties and limitations of per‐ or polyfluoroalkyl substances (PFASs) and fluoropolymers

Polymer International, EarlyView.
An overview and categorization of man‐made per‐ or polyfluoroalkyl substances (PFASs) including low‐molar‐mass and high‐molar‐mass fluorochemicals, and their international regulations is presented. Though certain PFASs are toxic, bioaccumulative and cross the human cellular membranes, others, such as fluoropolymers, are safe, reliable and involved in ...
Bruno Améduri
wiley   +1 more source

The Combustion of Highly Fluorinated Organic Compounds

, 1995
The special problems associated with the destruction of highly fluorinated one and two carbon organics under combustion conditions are discussed in terms of their fundamental chemical kinetic properties.
Tsang, Wing; Burgess, D. F. R.; Babushok, Valeri
core  

Impacts of Fluorination at the Ortho‐Position of Carboxy Groups on Tetrakis(biphenyl)ethene‐Based Hydrogen‐Bonded Framework

Small, EarlyView.
This work provides new findings on the effect of fluorination on the substitution of TPE derivatives and the modulation of the structure and fluorescence properties of hydrogen‐bonded organic framework (HOF) of F‐CBPE. ABSTRACT Fluorination of building block molecules is one of the effective engineering approaches to modulate molecular assembly in ...
Takuto Fujii, Mario de la Hoz Tomás, Ryusei Oketani, Boiko Cohen, Ken‐ichi Otake, Kazuki Shiga, Norimitsu Tohnai, Abderrazzak Douhal, Ichiro Hisaki   +8 more
wiley   +1 more source

Smart cellulose‐based room temperature phosphorescent materials: From mechanisms to construction strategies and applications

Smart Molecules, EarlyView.
This review elucidates the photophysical mechanisms of cellulose‐based room temperature phosphorescent materials and systematically outlines their construction strategies, such as cluster emission center engineering. This article demonstrates their applications in fields like information encryption and bioimaging, and looks ahead to the core challenges
Shasha Wu, Yifan Zhou, Wanjin Wu, Yan Tang, Mengfan Jing, Jianyu Zhang, Haoke Zhang, Zheng Zhao, Junwei Wang, Laurent Maron, Lijie Liu   +10 more
wiley   +1 more source

Metal-Organic Frameworks: Fluorinated Frameworks

, 2014
The synthesis of fluorinated metal‐organic frameworks (FMOFs) having fluorine‐lined channels has been reported in the literature. The hydrophobic channels present in FMOFs, wherein protruding fluorine atoms into the pores persuades hydrophobicity, have ...
Rahul Banerjee, Pachfule, Pradip, Pradip Pachfule, Banerjee, Rahul   +3 more
core   +1 more source

Perfluorohexanone for Clean Fire Suppression: Mechanisms, System Design, Applications, and Future Directions

Safety Science and Technology, EarlyView.
Driven by halon and high GWP agent phase out, perfluorohexanone is increasingly deployed in enclosures such as data centers, marine machinery spaces, and industrial process lines. This review summarizes application performance, discharge and distribution design, material compatibility, and byproduct control and maps practical gaps for large volume and ...
Zhilei Yu, Haibin Dong, Yanfeng Sheng, Xuelei Xian, Dehua Zhang, Feiran Li, Liang Liu, Junchao Zhao, Heping Zhang   +8 more
wiley   +1 more source

In Situ Colloidal Activated Carbon for PFAS Remediation in Groundwater: Principles, Performance Expectations, and Lessons from the First Decade

Groundwater Monitoring &Remediation, EarlyView.
Abstract Injectable colloidal activated carbon (CAC) has been commercially used to remediate per and polyfluoroalkyl substances (PFAS) in groundwater since 2016. The basis of the technology is enhanced PFAS retention within the aquifer from engineered increases in aquifer‐matrix sorptivity (“PFAS enhanced retention”), with re‐equilibration from the ...
Jeremy Birnstingl
wiley   +1 more source

SYNTHESIS AND PROPERTIES OF INTERACTION PRODUCTS OF TRIS[TRI(BUTOXY)TITANATE]BORON AND ALIPHATIC FLUORINATED ALCOHOLS

, 2018
Synthesis and properties of products based on tris[[tri(butoxy)titanate]boron with complete or partial substitution of butoxy groups linked with titanium by fluorinated alkoxy group were described. Extracted products were liquid or solid substances which
V.V. Bugrym, O.V. Skrinnik, S.N. Kuzmenko, N.Ya. Kuzmenko   +3 more
core   +1 more source

Specific Ion Effects of Chaotropic and Superchaotropic Anions Probed by Raman Hydration‐Shell Spectroscopy

Angewandte Chemie, Volume 138, Issue 27, 1 July 2026.
The vibrational frequencies of “dangling” water O─H bonds can be determined by Raman hydration‐ shell spectroscopy and used to differentiate chaotropes from kosmotropes and hydrophobes. Dangling O─H bonds are also detected around superchaotropic anions of the borate cluster type (B12X122−; X = H, F, Cl, Br, and I) but their frequencies do not directly ...
Werner M. Nau, Denilson Mendes de Oliveira, Andres S. Urbina, Harald Knorke, Jonas Warneke, Andrea Barba‐Bon, Dor Ben‐Amotz   +6 more
wiley   +2 more sources