Cross-Coupling Hydrogen Evolution Reactions [PDF]
During the past decade, transition metal-catalyzed dehydrogenative cross-couplings have emerged as an attractive strategy in synthetic chemistry due to its high step- and atom-economy as well as the less functionalized coupling partners. However, such reactions have to always use stoichiometric amount of sacrificial oxidants such as peroxides, high ...
Kui Dong, Qiang Liu, Li-Zhu Wu
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Carbon-based electrocatalysts for hydrogen evolution reaction
In the pursuit of clean and sustainable hydrogen energy production, water splitting has emerged as a promising method. However, the cost and scarcity of Pt-group metals as effective electrocatalysts hydrogen evolution reaction (HER) poses challenges for ...
Khalid Ahmed +4 more
doaj +1 more source
Hydrogen adsorption/desorption behavior plays a key role in hydrogen evolution reaction catalysis. Here, the authors demonstrate the rational balancing of hydrogen adsorption/desorption by orbital modulation for significantly enhanced hydrogen evolution ...
Feng Li +10 more
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Secondary Impact of Manganese on the Catalytic Properties of Nitrogen-Doped Graphene in the Hydrogen Evolution Reaction [PDF]
Catalysts play a key role in hydrogen production as green energy carriers. We show herein for the first time that manganese impurities in graphene can improve the catalytic activity of synthesized N‐doped graphene (NG) for the hydrogen evolution reaction
Arrigo +28 more
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A Perspective on Low-Temperature Water Electrolysis – Challenges in Alkaline and Acidic Technology
Water electrolysis is considered as an important technology for an increased renewable energy penetration. This perspective on low-temperature water electrolysis joins the dots between the interdisciplinary fields of fundamental science describing ...
Maximilian Schalenbach +4 more
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Mechanisms of hydrogen evolution on chromium [PDF]
In this work, the mechanisms of hydrogen evolution on the metal chromium in a solution of 0.1 M Na2SO4 + H2SO4, pH 1 to pH 7 were analysed. In the pH < 3 range, hydrogen is evolved according to three different mechanisms, depending on the experimental ...
Jegdić Bore +3 more
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Minimal‐power control of hydrogen evolution reactions
AbstractAn integral approach to solve finite‐horizon optimal control problems posed by set‐point changes in electrochemical hydrogen reactions is developed. The methodology extends to nonlinear problems with regular, convex Hamiltonians that cannot be explicitly minimized, i.e.
Costanza, Vicente +1 more
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Electrolytic preparation and characterization of Ni-Fe-Mo alloys: Cathode materials for alkaline water electrolysis [PDF]
Ni-Fe-Mo alloys have been electroplated by using suitable bath solution and plating conditions. SEM and XRD analysis showed that the deposited alloys are partially amorphous. Polarization studies indicated a dependence of the hydrogen evolution mechanism
Mayanna, S.M +2 more
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Study on Hydrogen Evolution Reaction at a Graphite Electrode in the All-Vanadium Redox Flow Battery
The hydrogen evolution reaction in the negative half-cell of a vanadium redox battery is studied at a graphite electrode. Hydrogen evolution behavior is included by potentiostatic method.
Fuyu Chen +3 more
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Directed Growth of Hydrogen Lines on Graphene: High Throughput Simulations Powered by Evolutionary Algorithm [PDF]
We set up an evolutionary algorithm combined with density functional tight-binding (DFTB) calculations to investigate hydrogen adsorption on flat graphene and graphene monolayers curved over substrate steps.
Brandbyge, M. +4 more
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