Results 121 to 130 of about 56,968 (297)

Adaptive Coordination Engineering for Efficient and Robust H2 Release

open access: yesAdvanced Science, EarlyView.
β‐H elimination is a pivotal but challenging step in homogeneous formic acid dehydrogenation reactions due to strict hydride‐metal matching. By using a rationally designed Pd1Ag2 bimetallic system with adaptive Pd1‐Ag2/L2 coordination and formate bridges, it enables boosted formic acid dehydrogenation under ambient air (7.7 times higher than a Pd ...
Xiaolin Jiang   +8 more
wiley   +1 more source

Au(I)-catalysis Enables Regioselective Hydrogen Isotope Labeling of Indoles [PDF]

open access: yes
The gold(I)-catalyzed hydrogen isotope exchange reaction on indoles and related heterocycles is described, under mild conditions and low catalyst loadings, using CD3OD and D2O as readily available deuterium sources.
Mohammed, Ramdani   +6 more
core   +1 more source

Advanced Mass Spectrometers for Hydrogen Isotope Analyses [PDF]

open access: yes, 2001
This report is a summary of the results of a joint Savannah River Laboratory (SRL) - Savannah River Plant (SRP) ''Hydrogen Isotope Mass Spectrometer Evaluation Program''.
Chastagner, P.
core   +1 more source

Effect of Water‐Rock Ratio on the Stable Isotope Record of Fluid‐Rock‐Deformation Interactions in Detachment Shear Zone

open access: yesGeochemistry, Geophysics, Geosystems
Oxygen and hydrogen stable isotope analyses of quartz and muscovite veins from the footwall of the Raft River detachment shear zone (Utah) provide insight into the hydrology and fluid‐rock interactions during ductile deformation.
Raphaël Gottardi   +3 more
doaj   +1 more source

Review of Water Hydrogen Isotope Separation Technology

open access: yesHe huaxue yu fangshe huaxue
Hydrogen isotopes, such as protium(H), deuterium(D), and tritium(T), are widely used in medical treatment, nuclear energy, national defense, and other fields.
SHI Zhang-hong   +2 more
doaj   +1 more source

How Proton Incorporation Reshapes Lattice Dynamics In BaSnO3‐Type Proton Conductors

open access: yesAdvanced Science, EarlyView.
Yttrium‐doped BaSnO3 exhibits isotope‐dependent changes in its low‐energy vibrational density of states upon hydration. Comparison of dry, H2O‐, and D2O‐treated samples re‐veals mass‐dependent phonon renormalization linked to proton dynamics near oxygen va‐cancies, providing experimental insight into hydrogen‐coupled lattice excitations in proton ...
Artur Braun   +9 more
wiley   +1 more source

Water‐Enabled Ultralong Full‐Color Organic Phosphorescence in Hydrogen‐Bonded Frameworks for 4D Encryption and Bio‐Imaging

open access: yesAdvanced Science, EarlyView.
Water‐induced quenching challenges organic RTP materials, but a counter‐intuitive strategy employs HOF to encapsulate carbonyl guests, where water functions as a structural reinforcer. This achieves water‐enhanced ultralong RTP with full‐color emission (blue to deep red), overcoming intracellular quenching for high‐signal cellular imaging, alongside 4D
Pengcheng Wu   +3 more
wiley   +1 more source

Geometric isotope effect of deuteration in a hydrogen-bonded host–guest crystal

open access: yesNature Communications, 2018
Deuterating a hydrogen bond can change the bond’s geometry, a phenomenon known as the geometric isotope effect (GIE). Here, the authors find that a hydrogen-bonded host–guest crystal, imidazolium hydrogen terephthalate, exhibits significant GIE on its ...
Chao Shi   +4 more
doaj   +1 more source

Real‐Time Stress Visualization of Hydrogels Enabled by Supramolecularly Switched Stretch‐Induced Phase Separation

open access: yesAdvanced Science, EarlyView.
Supramolecular hydrogels enable real‐time visualization of mechanical stress through supramolecular switching mechanotransduction. Adamantane‐modified cellulose functions as a responsive domain that undergoes an on–off transition between hydrated and dehydrated states via reversible β‐cyclodextrin–adamantane complexation and decomplexation.
Sooyeon Noh   +7 more
wiley   +1 more source

Hydrogen isotope mass spectrometers [PDF]

open access: yes, 1990
This report discusses historical aspects and current designs of hydrogen isotope mass spectrometers ...
Chastagner, P.
core  

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