Results 41 to 50 of about 5,505 (199)

Exploring Calixarene‐Based Pseudorotaxane Architectures: Threading Ammonium Axles With an Exo‐Rim π‐Functionalized Calix[6]Arene Macrocycle

Chemistry – A European Journal, EarlyView.
This research presents a novel 1,4‐π‐functionalized calix[6]arene with enhanced interactions with dialkylammonium axles. We investigate threading behavior in CDCl3, highlighting how exo‐rim π‐functionalization affects binding affinity and stereoselectivity.
Veronica Iuliano, Paolo Della Sala, Placido Neri, Donato De Simone, Rocco Del Regno, Margherita De Rosa, Carmine Gaeta, Carmen Talotta   +7 more
wiley   +1 more source

Silica‐Supported Mononuclear Methyl‐Platinum Complexes Stabilized by Trimethylphosphine—Synthesis, Structure, and Reactions Under Reducing Conditions

Chemistry – A European Journal, EarlyView.
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz, Sven Schaefer, Oksana Storcheva, Gabriele Raudaschl‐Sieber, Johannes Bitzer, Wolfgang Kleist, Klaus Köhler   +6 more
wiley   +1 more source

Hydrogenolysis of Coal

Journal of the Fuel Society of Japan, 1957
石炭の水素化分解によりケミカルズを得る方法について論説し, 石炭の液相水素化分解と液化曲の改質とを組合わせるプロセスの可能性を, 三池炭およびその他の炭化水素類を用いた断続実験の結果より考察した。
Shigeo Noda, Takao Matsuda, Takashi Takahashi, Tsuneo Kakuzen   +3 more
openaire   +3 more sources

N‐Sulfonyl Azalevoglucosan: A Versatile Platform for the Synthesis of Polysubstituted Piperidines

Chemistry – A European Journal, EarlyView.
Gain by strain: The synthesis of a levoglucosan analog, in which the pyranose oxygen has been replaced by a nitrogen, allows navigation on the piperidine ring to iteratively install functional groups at C1, C2, C3, C4, and C6 positions using simple experimental protocols with minimal protecting group manipulation.
Dylan Yorga, Jérôme Marrot, Ana Poveda, Nicolas Auberger, Jesús Jiménez‐Barbero, Jérôme Désiré, Yves Blériot   +6 more
wiley   +1 more source

A Stable Isopterin Mimic of a Potent Bacterial Stimulant of T Cells

Chemistry – A European Journal, EarlyView.
A microbial metabolite covalently binds immunological protein MR1 to potently activate specific lymphocytes called MAIT cells, but it is too unstable for biological applications. Here, using synthesis, assays, protein crystallography, and computer modelling, we report a water‐stable analogue that activates reporter cells expressing the MAIT T cell ...
Jeffrey Y. W. Mak, Huy N. Hoang, Wael Awad, Xin Yi Lim, Damica D. Laurie, Ryan J. D. Rivero, James McCluskey, Alexandra J. Corbett, Jamie Rossjohn, David P. Fairlie   +9 more
wiley   +1 more source

Catalytic Hydrothermal Liquefaction of Polyethylene With Pt/C to Tune Product Selectivity

CleanMat, EarlyView.
Pt/C‐catalyzed hydrothermal liquefaction of polyethylene in supercritical water enables time‐dependent control of product selectivity, producing paraffin‐rich oils at shorter reaction times and aromatic‐enriched products at longer times without external hydrogen. ABSTRACT Hydrothermal liquefaction (HTL) represents a promising thermochemical pathway for
Taofeng Lu, Wan‐Ting Chen
wiley   +1 more source

Circular and Bio‐Sourced Polymers for Energy Applications: Natural Feedstocks, Recycling, and Upcycling Routes

EcoEnergy, EarlyView.
This review provides a critical comparative analysis of circular and bio‐sourced polymers for energy storage, systematically evaluating natural feedstocks alongside recycling and upcycling strategies for battery components. Key structure–property–performance relationships and inherent trade‐offs between sustainability metrics and electrochemical ...
Priyank Sinha, Amul Jain, Koushik Mahata, Sanjib Banerjee   +3 more
wiley   +1 more source

Selective hydrogenolysis of glycerol to 1,3-propanediol over bifunctional Pt/KIT-6 catalysts

Sustainability Science and Technology
Glycerol hydrogenolysis represents an important route for biomass valorization, enabling the sustainable conversion of glycerol, a major byproduct of biodiesel production, into value-added chemicals and thereby improving the utilization of renewable ...
Joaquin Herrero, Tobias K Misicko, Vijaya Gopu, Yang Xiao   +3 more
doaj   +1 more source

Enhancing Mass and Yield Product of Propylene Glycol Production through Glycerol Hydrogenolysis

Journal of Chemical Engineering Research Progress
The chemical industry in Indonesia continues to experience significant growth in both innovation and technology. One of the significant areas of improvement is in supporting materials, exemplified by propylene glycol.
Dhea Wahyu Amanda Arifin, Luthfi Maulana Firdaus, Muhammad Danil Huda, Muhammad Saefillahil Abdat, Navira Amalia Indriani   +4 more
doaj   +1 more source

Low‐Temperature in Situ Upgrading of Ultra‐Deep Heavy Oil Using Ni–Ce/MOF–OTf Superacid Catalysts to Enhance Energy Utilization and Sustainability

EcoEnergy, EarlyView.
A triflate‐functionalized Ni–Ce/MOF–OTf superacid enables low‐temperature (∼140°C) in situ upgrading of ultra‐deep heavy oil. It reduces viscosity by 92.11% in 12 h, maintains activity over cycles, and delivers 90.25% recovery with a lower carbon footprint by selective bond cleavage. ABSTRACT Ultra‐deep heavy oil is an important unconventional resource,
Li Wang, Ji‐Xiang Guo, Qiming Huang, Kunpeng Li, Chi Li, Yajie Wu   +5 more
wiley   +1 more source