Results 51 to 60 of about 10,893 (225)

The Investigation of the Deactivation of the Metal‐Modified ZSM‐5 Zeolites for the Catalytic Dehydration of Glycerol

Carbon and Hydrogen, EarlyView.
During the glycerol dehydration over ZSM‐5 zeolite, the modification by metal promoters results in the suppression of the bicyclic and tricyclic aromatics over the modified ZSM‐5 zeolite catalysts. However, the issue of the fast deactivation still remains an apparent challenge, which requires more different perspectives to understand the deactivation ...
Yonghua Yu, Lili Yu, Yunxuan Ji, Dazhi Zhang, Hui Ding, Peidong Li, Shengjun Huang, Jiaxu Liu   +7 more
wiley   +1 more source

Selective Oxidation Strategies for Cost‐Efficient Green Hydrogen Production via Hybrid Water Electrolysis

Carbon Energy, EarlyView.
Hybrid water electrolysis has emerged as a promising alternative to conventional electrolysis for sustainable hydrogen production. The economic potential of replacing water oxidation with organic substrates is assessed. For each substrate, representative electrocatalysts and mechanistic insights are reviewed to identify design principles for optimized ...
Conor Brennan‐Pollak, Lua Henderson, Cian Clarke, Maida A. Costa de Oliveira, Dídac A. Fenoll, Sreedhanya Pallilavalappil, Aswathy Babu, Shaista Jabeen, Pranav K. Gangadharan, Huabin Zhang, Suresh C. Pillai, Paula E. Colavita, Max García‐Melchor   +12 more
wiley   +1 more source

Mechanism of Hydrogenolysis. II. A Molecular Orbitals Study of Hydrogenolysis of Toluene [PDF]

Bulletin of the Chemical Society of Japan, 1970
Abstract In hydrogenolysis of toluene to produce benzene and methane, atomic cracking process H+C6H5CH3→C6H6CH3 (a) or H+C6H5CH3→C6H5+CH4 (b) has been presumed as rate controlling in chain propagation step of the radical chain mechanism. These two alternative processes are compared on the energetics calculated by the extended Hückel M.O.
Hiroo Tominaga, Hiromichi Arai, Taiseki Kunugi, Akira Amano, Masao Uchiyama, Yoshiki Sato   +5 more
openaire   +1 more source

Upcycling Real‐World Post‐Consumer Polyolefins Plastics Into Light Olefins Via Microwave‐Assisted Processing

Carbon Energy, EarlyView.
Microwave‐driven Ru@α‐Fe2O3 selectively upgrades real‐world post‐consumer mixed polyolefin waste into light olefins with high gas yields and olefin selectivity at markedly reduced temperatures compared with conventional thermal pyrolysis. Strong tolerance of additives and feed heterogeneity highlights an energy‐efficient and scalable route for circular
Yi Su, Chunlin Luo, Md Emdadul Haque, Kangqi Gao, Brandon Robinson, Yujuan Chen, Debangsu Bhattacharyya, Jianli Hu, Yuxin Wang   +8 more
wiley   +1 more source

Synthetic O‐Polysaccharide Backbone Units for a Single Antigen Vaccine Against Two Major Non‐Typhoidal Salmonella Serovars

Angewandte Chemie, Volume 138, Issue 26, 22 June 2026.
A modular strategy was developed to synthesize tri‐, hexa‐, and nona‐saccharides representing repeating units of the conserved O‐polysaccharide backbone of Salmonella. Conjugates of these glycans to bacteriophage Qβ induced strong IgG responses in mice and rabbits. Antibodies elicited recognized native O‐polysaccharides and conferred protection against
Xingling Pan, Changxin Huo, Soham Maity, Herbert Kavunja, Rachel Moszyk, Cameron Talbot, Scott M. Baliban, Xuefei Huang   +7 more
wiley   +2 more sources

Alkene Hydrogenation by a Cationic, Nine‐Coordinate Molybdenum(VI) Pentahydride Catalyst

Chemistry – A European Journal, EarlyView.
While late 3d metals dominate efforts to replace precious metals in homogeneous hydrogenation, molybdenum has remained largely ignored. This work reveals that a nine‐coordinate pentahydrido molybdenum complex can hydrogenate a broad range of alkenes efficiently, demonstrating that early‐metal polyhydrides can serve as genuine catalysts rather than mere
Arno Estival, Michel Sigrist, Nicolas Queyriaux, Jorge J. Cabrera‐Trujillo, Nina Durvin, Marie‐Christine Boegli, Laure Vendier, Mary Grellier, Karinne Miqueu, Antoine Simonneau   +9 more
wiley   +1 more source

Microkinetic modeling of n-butane hydrogenolysis on Ru(0001)

Vlachos, Dionisios G.Plastic waste is an untapped opportunity to reintroduce valuable resources into the value chain. Hydrogenolysis is a promising technology that achieves this while operating at milder temperatures than similar technologies.
Raike, Roel
core   +1 more source

State‐of‐the‐Art and Synthetic Challenges for Hydrosilane Production

Chemistry – A European Journal, EarlyView.
The synthesis of hydrosilanes is currently energy intensive and their recycling is not considered. However, these compounds are important in many industrial fields but also for the valorization of oxygenated waste, towards a circular economy. This review compares the available synthetic routes and highlights the remaining challenges for the production ...
Gabriel Durin, Albane Fontaine, Jean‐Claude Berthet, Thibault Cantat   +3 more
wiley   +1 more source

Stereospecific hydrogenolysis of benzylic alcohols over Pd/C

, 2020
Hydrogenolysis of tertiary benzylic alcohols on palladium on carbon (Pd/C) generally proceeds with inversion of configuration. However, little is known about the hydrogenolysis mechanism of primary and secondary benzylic alcohols.
Harvey, Freya M., Bochet, Christian G., Bochet, Christian, Harvey, Freya   +3 more
core   +1 more source

Bioinspired Design and Synthesis of Polyphenolic Star‐Like and Hyperbranched Polyester Models

Chemistry – A European Journal, EarlyView.
Gallotannin‐inspired star‐like and hyperbranched aromatic polyesters were synthesized from D‐glucose and ABn‐type phenolic acid monomers, such as protocatechuic acid. This bioinspired approach afforded polyphenolic polymeric nanoparticles able to encapsulate hydrophobic dyes, opening new perspectives for biobased encapsulation and delivery systems ...
Guanfei Shen, Laurent Pouységu, Christophe Schatz, Etienne Grau, Stéphane Quideau   +4 more
wiley   +1 more source