Results 61 to 70 of about 5,505 (199)
Hydrogenolysis Recycling of Polycaprolactone Plastics Promoted by Trifluoromethanesulfonates
The widespread use of plastics results in the annual generation of large amounts of waste, posing significant environmental challenges due to inefficient treatment and the resulting pollution.
Jie SHEN, Hao CUI, Jin DENG
doaj +1 more source
Catalytic hydrogenolysis of fructose to acetol over Ni/CeO2 catalysts
Acetol is the important platform molecule, which showed diversified applications in organic synthesis, pharmaceutic, food and polymer industrials. The production of acetol from selective fructose hydrogenolysis is of scientific and practical interests ...
Tong Zhang +3 more
doaj +1 more source
A stereodivergent route from D‐mannitol enables access to enantiopure C5‐α‐substituted linezolid analogues with full configurational control. Biological evaluation reveals that α‐substitution abolishes antibacterial activity irrespective of stereochemistry, establishing a strict steric limitation at C5 and highlighting the dominant role of substituent ...
José A. Gálvez +3 more
wiley +1 more source
Thermocatalytic hydrogenation of CO2 to aromatic hydrocarbons represents a sustainable route for high‐value CO2 utilization. Bifunctional catalysts combining metal/metal oxide components with acidic zeolites enable the direct synthesis of BTX aromatics.
Weilin Wang +4 more
wiley +1 more source
A low‐loading (1.5 wt%) Ru/MAFO spinel catalyst with strong metal–support interaction achieves 100% glucose conversion and 59.3% 1,2‐PG selectivity. Its exceptional thermal stability and resistance to Ru sintering enable stable recycling, offering a highly active and durable system for sustainable biorefinery applications.
Qingsong Wang +5 more
wiley +1 more source
Conditional Variational AutoEncoder to Predict Suitable Conditions for Hydrogenation Reactions
Reaction conditions (RCs) are a crucial part of reaction definition, and their accurate prediction is an important component of chemical synthesis planning. The existence of multiple combinations of RCs capable of achieving the desired result complicates
Daniyar Mazitov +4 more
doaj +1 more source
Can an amide analog retain the high potency of the classic urea motif in soluble epoxide hydrolase inhibitors? Through a single unconventional switch, the introduction of the underexplored pentafluorosulfanyl group into an amide analog of TPPU, the authors restored high inhibitory potency.
Alba López‐Ruiz +17 more
wiley +1 more source
Polyolefin waste presents a major upcycling challenge because of its chemical inertness. Ruthenium catalysts are highly active for polyethylene hydrogenolysis, but often overproduce methane and linear alkanes and show limited substrate scope.
Jie Sun +9 more
doaj +1 more source
Alkene Hydrogenation by a Cationic, Nine‐Coordinate Molybdenum(VI) Pentahydride Catalyst
While late 3d metals dominate efforts to replace precious metals in homogeneous hydrogenation, molybdenum has remained largely ignored. This work reveals that a nine‐coordinate pentahydrido molybdenum complex can hydrogenate a broad range of alkenes efficiently, demonstrating that early‐metal polyhydrides can serve as genuine catalysts rather than mere
Arno Estival +9 more
wiley +1 more source
Here, we report isolation of acyl‐desferrioxamines from Actinoplanes teichomyceticus as a mixture of iron and aluminum complexes. The fraction containing these molecules exhibited antibacterial activity. We synthesized these molecules and found that they only exhibited antibacterial activity in the presence of aluminum.
Abiodun S. Oyedele +7 more
wiley +1 more source

