Results 211 to 220 of about 92,642 (284)

Neue molekulare Vorstufen zur Herstellung ungeschützter Gold- und Goldsilberlegierungs- Nanopartikel für druckbare Nanostrukturen [PDF]

, 2012
Zopes, David
core  

Synthesis and Characterization of π‐Extended Azulenes via Nucleophilic Substitution and Intramolecular Cyclization of 5‐Alkynyl‐6‐Fluoroazulenes

ChemistryEurope, EarlyView.
A modular synthetic approach enables the preparation of azulene‐fused heterocycles via nucleophilic aromatic substitution followed by intramolecular cyclization of alkynyl fluoroazulenes. The method allows the incorporation of various heteroatoms (N, O, S, Se, and Te), leading to structurally diverse heteroannulated azulenes.
Martin C. Dietl, Matthias Scherr, Christopher Hüßler, Henrik T. Habeck, Carmen L. M. Henel, Jürgen Graf, Frank Rominger, Matthias Rudolph, A. Stephen K. Hashmi   +8 more
wiley   +1 more source

Gold Nanoparticles–Dynamic Constitutional Frameworks as Adaptive Hybrid Conjugates for Enzyme Immobilization

ChemistryEurope, EarlyView.
Dynamic constitutional frameworks (DCFs) and gold nanoparticles (AuNps) assemble into larger and well‐distributed conjugates providing an efficient platform for biosensing and biocatalytic applications. Dynamic constitutional frameworks (DCFs), connecting monomers via reversible covalent bonds, can initiate the assembly of gold nanoparticles (AuNps ...
Sanaa Daakour, Rosalinda Mazzei, Fabio Bazzarelli, Giuseppe Vitola, Lidietta Giorno, Mihail Barboiu   +5 more
wiley   +1 more source

Distribution of polychlorinated organic by-products during the hydrolytic oxidation of chlorinated volatile organic pollutants over Pd-Ni-based catalysts. [PDF]

RSC Adv
Li Y, Lv B, Li N, Song W, Zhou J, Ni C, Fu W, Han Z.   +7 more
europepmc   +1 more source

Hydroxyl Self‐Trapping Strategy Enables Electrocatalysis at Ampere‐Level Current Densities: Kinetics‐Driven Lattice Oxygen Activation for Cl−‐Rich Alkaline Water Electrooxidation

Carbon Energy, EarlyView.
This study designs a CrOx‐engineered Ni‐based catalyst enabling efficient and stable seawater electrolysis. The catalyst utilizes a dynamic interfacial barrier that selectively adsorbs OH− to repel Cl− corrosion while activating lattice oxygen‐mediated pathways.
Rui Liu, Hui Kan, Xiangdong Ma, Shan Yue, Jiayi Gao, Mingjing Zhao, Haijiao Xie, Xiaohong Xia   +7 more
wiley   +1 more source

A Michaelis‐Arbuzov‐Type Pathway to a Protected 2ʹ‐Deoxy‐2ʹ‐Selenomethyl‐Adenosine‐3ʹ,5ʹ‐Phosphoroselenolate Guanosine Dinucleotide for Use in Modified m7G Cap Synthesis

Chemistry – A European Journal, EarlyView.
Here we report a synthesis of the dinucleotide 4 for a projected future total synthesis of the m7G cap 1. Highlights of the route include: 1) a 3ʹ‐H‐phosphonate/5ʹ‐selenocyanate Michaelis‐Arbuzov coupling to forge the 3ʹ,5ʹ‐phosphoroselenolate; 2) an Amosova reductive selenomethylation to install the 2ʹ‐SeMe; 3) a solid CPR II 5ʹ‐O‐phosphitylation; and
K. Lawrence E. Hale, Helen O. McCarthy, Mark G. McLaughlin   +2 more
wiley   +1 more source

Modified Polycaprolactone Films for Temporary Protection in Saline Conditions: A Preliminary Assessment. [PDF]

Polymers (Basel)
John AP, Santoro S, Curcio E, Argurio P, Chidichimo F, Straface S, Ruffolo SA, La Russa MF.   +7 more
europepmc   +1 more source

Controlling Aggregation‐Induced Emission by Sterics in Nitrogen–Boron–Nitrogen (NBN)‐Doped Tetraphenylethylene‐Like Molecular Propellers

Chemistry – A European Journal, EarlyView.
Nitrogen–boron–nitrogen (NBN)‐substituted molecular propellers are presented as structural framework for aggregation induced emission (AIE) applications. Steric hindrance is revealed to steer maximum‐AIE behavior, leading to refined control over assembly‐induced luminescence.
Nico Groß, Bojan Tanović, Frank Hampel, Henry Dube, Ani Ozcelik   +4 more
wiley   +1 more source

The Esterase Gs Derived from <i>Geobacillus</i> sp. JM6 Exhibits Hydrolytic Activity on the PET Model Substrates. [PDF]

Biology (Basel)
Duan S, Wei Z, Wei Y, Cai X, Liu Y, Fan R.   +5 more
europepmc   +1 more source

Catalytic Amyloids: Turning Fibrils Into Biocatalysts

Chemistry – A European Journal, EarlyView.
Amyloids, traditionally associated with diseases, have emerged as versatile catalytic scaffolds. From natural amyloid sequences to bioinspired and de novo designs, we highlight strategies to construct catalytic active sites and anchor enzymes onto fibrils, creating versatile nanomaterials with tunable activities. ABSTRACT Amyloids have been regarded as
Alessandra Esposito, Linda Leone, Flavia Nastri, Angela Lombardi   +3 more
wiley   +1 more source