Results 61 to 70 of about 10,848 (250)

Inter‐Atomic Synergy on Single‐Atom Alloy Promotes Cyclohexanone Oxime Electrosynthesis

open access: yesAdvanced Materials, EarlyView.
Electrosynthesis of cyclohexanone oxime using renewable electricity offers a greener alternative to traditional energy‐intensive methods. Here, we develop a Fe1Bi single‐atom alloy that delivers 70.9% Faradaic efficiency and 0.94 mmol cm−2 h−1 yield rate through the atomic‐scale synergistic mechanism.
Panlong Zhai   +10 more
wiley   +1 more source

Integrated Study of the Dinitrobenzene Electroreduction Mechanism by Electroanalytical and Computational Methods

open access: yesInternational Journal of Electrochemistry, 2011
Electroreduction of 1,2-, 1,3-, and 1,4-dinitrobenzenes in DMF has been investigated by a set of experimental (cyclic voltammetry, chronoamperometry, and controlled potential electrolysis) and theoretical methods (digital simulation and quantum chemical ...
Andrey S. Mendkovich   +5 more
doaj   +1 more source

Catalytic dechlorination of diclofenac by biogenic palladium in a microbial electrolysis cell [PDF]

open access: yes, 2012
Diclofenac is one of the most commonly detected pharmaceuticals in wastewater treatment plant (WWTP) effluents and the receiving water bodies. In this study, biogenic Pd nanoparticles (bio-Pd) were successfully applied in a microbial electrolysis cell ...
Boon, Nico   +5 more
core   +1 more source

Nitroxide‐Mediated Photo‐Polymerization: A Swiss Army Knife for Microfluidic Design

open access: yesAdvanced Materials Technologies, EarlyView.
This article illustrates the application of NMP2 to the rapid (less than 1 h) photostructuring and sealing of model structures intended for microfluidic applications. Remarkably, the careful design of resin composition allows completing these steps by simply spreading bare monomer (i.e., no added photoinitiator) on top of the bottom layer embedding ...
Carlo Gonzato   +5 more
wiley   +1 more source

Quantum mechanics/molecular mechanics modeling of drug metabolism:Mexiletine N-hydroxylation by cytochrome P450 1A2 [PDF]

open access: yes, 2016
The mechanism of cytochrome P450­(CYP)-catalyzed hydroxylation of primary amines is currently unclear and is relevant to drug metabolism; previous small model calculations have suggested two possible mechanisms: direct N-oxidation and H-abstraction ...
Adrian J. Mulholland   +8 more
core   +3 more sources

Cancer Cell‐Intrinsic Cholesterol Induces Lipid‐Associated Macrophage Differentiation via SP1 Palmitoylation to Promote Prostate Cancer Progression

open access: yesAdvanced Science, EarlyView.
Cancer cell‐intrinsic cholesterol promotes the S‐palmitoylation of SP1, increasing its nuclear translocation and driving the transcription and secretion of MDK, which in turn facilitates the differentiation of macrophages into a lipid‐associated phenotype.
Shirong Peng   +12 more
wiley   +1 more source

The alpha-effect in cyclic secondary amines: new scaffolds for iminium ion accelerated transformations [PDF]

open access: yes, 2009
Five-membered secondary amine heterocycles containing an α-heteroatom were prepared and shown to be ineffective as catalysts for the iminium ion catalysed Diels–Alder reaction between cinnamaldehyde and cyclopentadiene.
Cavill, Julie L.   +7 more
core   +1 more source

Palmitoylation‐Mediated Ubiquitination of SRPK1 Regulates Ferroptosis in High‐Fat‐Induced Erectile Dysfunction

open access: yesAdvanced Science, EarlyView.
Elevated exogenous palmitic acid promotes the S‐palmitoylation of SRPK1 in endothelial cells, a dynamic process governed by ZDHHC24 and APT1. This post‐translational modification strengthens the interaction between SRPK1 and the E3 ubiquitin ligase MIB1, thereby facilitating the proteasomal degradation of SRPK1.
Xiao‐Hui Tan   +11 more
wiley   +1 more source

Improving the Photovoltaic Properties and Stability of Inverted Perovskite Solar Cells with Hydroxylamine‐Based Additives

open access: yesAdvanced Materials Interfaces
Organic–inorganic halide perovskite solar cells (PVSCs) are considered a promising emerging photovoltaic technology that offer exceptional optoelectronic properties and the potential for economic solar energy conversion.
Keisuke Nagasawa   +8 more
doaj   +1 more source

Combined effect of biopriming and polymer coating on chemical constituents of root exudation in chilli (Capsicum annuum L.) cv. K 2 seedlings [PDF]

open access: yes, 2016
A study was carried out to analyze the different volatile compounds in bioprimed chilli (Capsicum annuum L.) seedlings of 15 and 30 day old. A common compound found in two stages of chilli seedlings was hydroxylamine, dimethoxydimethyl silane ...
Lakshmi, S., Nakkeeran, S., Sathya, S.
core   +2 more sources

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