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Indonesian Journal of Chemistry, 2023 This paper describes the synthesis of two complexes from the ligand α-(2-Salsayl)-N-phenyl nitrone with CoCl2 and CrCl2. The ligand was characterized by several spectroscopic techniques (ultraviolet/visible (UV/Vis), nuclear magnetic resonance (1H-NMR ...
Dhamiaa Abdul-Shaheed Issa +2 more
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5,5,7,7-Tetrametyl-6,7-dihydro-5H-dibenzo[c,e]azepine
Molbank, 2023 5,5,7,7-Tetrametyl-6,7-dihydro-5H-dibenzo[c,e]azepine has been synthesized as a possible pro-chiral (or tropos) unit for the construction of a chiral catalyst and as a molecular chirality sensor for the absolute configuration assignment by chiroptical ...
Roberto Bisaccia +3 more
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Acta Crystallographica Section E: Crystallographic Communications, 2021 The conformation of the title compound, C13H11NO2, is partially determined by a strong, intramolecular O—H...O hydrogen bond. The crystal packing consists of strongly corrugated layers parallel to the ac plane and associated through C—H...π(ring ...
Shaaban K. Mohamed +5 more
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2-Butyl-2-tert-butyl-5,5-diethylpyrrolidine-1-oxyls: Synthesis and Properties
Molecules, 2020 Nitroxides are broadly used as molecular probes and labels in biophysics, structural biology, and biomedical research. Resistance of a nitroxide group bearing an unpaired electron to chemical reduction with low-molecular-weight antioxidants and enzymatic
Irina F. Zhurko +8 more
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Kinugasa Reactions in Water: From Green Chemistry to Bioorthogonal Labelling
Molecules, 2015 The Kinugasa reaction has become an efficient method for the direct synthesis of β-lactams from substituted nitrones and copper(I) acetylides. In recent years, the reaction scope has been expanded to include the use of water as the solvent, and with ...
Mariya Chigrinova +4 more
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Molecules, 2022 Sterically shielded nitroxides, which demonstrate high resistance to bioreduction, are the spin labels of choice for structural studies inside living cells using pulsed EPR and functional MRI and EPRI in vivo.
Sergey A. Dobrynin +8 more
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A mechanistic investigation of the oxidation of N,α-diphenylnitrones by dichloramine-T in aqueous acetonitrile medium - a non-linear Hammett plot [PDF]
Journal of the Serbian Chemical Society, 2009 The kinetics of oxidation of a number of meta- and para-substituted N,α-diphenylnitrones (nitrone) by dichloramine-T (DCT) was investigated in the presence of alkali in aqueous acetonitrile medium.
Manivarman S. +5 more
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(Z)-1-(1,3-Diphenyl-1H-pyrazol-4-yl)-N-phenylmethanimine N-oxide
IUCrData, 2018 In the title nitrone, C22H17N3O, the dihedral angles between the central pyrazole ring and pendant N-bound, C-bound and nitrone-bound phenyl rings are 20.93 (6), 41.27 (6), and 32.57 (6)°, respectively.
Shaaban K. Mohamed +5 more
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Antioxidants, 2020 Nitrones have a well-recognized capacity as spin-traps and are considered powerful free radical scavengers, which are two important issues in hypoxia-induced oxidative stress and cell death in brain ischemia.
Emma Martínez-Alonso +9 more
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STUDY OF CYCLOREVERSION OF NTTRONE-CY CLODIMERS [PDF]
Journal of Sciences, Islamic Republic of Iran, 1993 A series of 1,3-dipolar cycloaddition reactions are carried out using cyclodimers of simple nitrones and various dipolarophiles; substituted isoxazolidines are isolated and identified.
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