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Transaminase and Norcoclaurine Synthase One‐Pot Cascades Towards (1S)‐Tetrahydroisoquinolines

ChemBioChem, Volume 27, Issue 6, 27 March 2026.
A TAm‐NCS cascade towards THIQs has been established, starting from amines with the in situ production of aldehydes. The cascade was used with a variety of nonfunctionalized and functionalized amines, and reaction conditions modified to enhance formation of the desired cross‐products.
Jianxiong Zhao +5 more
wiley +1 more source

EDA Complex-Mediated C(sp3)-H Cross-Dehydrogenative Coupling Enables Synthesis of Noncanonical α,β-Diamino Acids. [PDF]

European J Org Chem
Sachidanandan K +4 more
europepmc +1 more source

Structured Electrodes Enable High‐Rate and Selective Electrochemical Nicotinamide Adenine Dinucleotide Regeneration for Biocatalysis

ChemSusChem, Volume 19, Issue 6, 27 March 2026.
Direct electrochemical regeneration of the key enzymatic cofactor NADH is demonstrated in a scalable zero‐gap electrolyzer. Systematic screening of copper, silver, and titanium catalysts reveals that titanium felt achieves 100% selectivity for active 1,4‐NADH, while optimized copper mesh delivers record reaction rates. Electrode structuring and current
Jonas Wolf +7 more
wiley +1 more source

Fluorinated Glycan Frameshifts: Automated Synthesis Expedites the Study of Glycan‐Protein Interactions by 19F‐BioNMR

Angewandte Chemie, Volume 138, Issue 12, 16 March 2026.
Given the prominence of 19F‐bioNMR in structural research, fluorinated glycans hold enormous potential in glycomimetic frameshift design. However, challenges associated with the stereocontrolled synthesis of these disruptive actors continue to frustrate advances. To address this, the automated synthesis of selectively C‐2 fluorinated glycans related to
James Suri +6 more
wiley +2 more sources

From Plastic Waste to Pharmaceutical Precursors: PET Upcycling Through Ruthenium Catalyzed Semi-Hydrogenation. [PDF]