Synthesis, Chemistry and Applications of 5-Hydroxymethyl-furfural And Its Derivatives [PDF]
The prospect of exciting research activity in the chemistry of furfural derived compounds such as 5-hydroxymethylfurfural (HMF), 2,5-furandicarbaldehyde and 2,5-furan-dicarboxylic acid prompted the writing of this article.
Lewkowski, Jarosław
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Electronic structure and magnetic anisotropy of the [Co_4(hmp)_4(CH_3OH)_4Cl_4] molecule [PDF]
Accurate density-functional based calculations have been performed on the Co_4(hmp)_4(CH_3OH)_4Cl_4 molecular magnet where hmp is deprotonated hydroxymethyl pyridine. In addition to the experimentally observed staggered geometry, we identify two isomers, referred to as eclipsed and half-staggered/half-eclipsed, that are reasonably low in energy.
arxiv +1 more source
Self-immolative linkers in polymeric delivery systems [PDF]
There has been significant interest in the methodologies of controlled release for a diverse range of applications spanning drug delivery, biological and chemical sensors, and diagnostics.
Blencowe, Christopher A+4 more
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Polyfunctional pyrazoles. 9. Synthesis of 1-alkyl(aryl)-3-[4-(hydroxymethyl)-1h-pyrazol-3-yl]ureas [PDF]
We have developed an effective method for the preparation of 1-alkyl(aryl)-3-[4-(hydroxymethyl)-1Н-pyrazol-3-yl]ureas based on the interaction of 4-hydroxymethylpyrazole-3-carbonyl azides with primary aliphatic and aromatic amines under the conditions of
Barus, M.M.+3 more
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Three New Phytoecdysteroids Containing a Furan Ring from the Roots of Achyranthes bidentata Bl.
Three new phytoecdysteroid compounds, named niuxixinsterone A (1), B (2) and C (3) with acetal functions in the side-chain were isolated from Achyranthes bidentata Bl.
Liu Yang+5 more
doaj +1 more source
The derivation of the formyl-group oxygen of chlorophyll b in higher plants from molecular oxygen. [PDF]
The mechanism of formation of the formyl group of chlorophyll b has long been obscure but, in this paper, the origin of the 7-formyl-group oxygen of chlorophyll b in higher plants was determined by greening etiolated maize leaves, excised from dark-grown
Abraham R. J.+27 more
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Three pyrrole alkaloid derivatives were isolated from the edible mushroom Basidiomycetes-X (Echigoshirayukidake) by water extraction followed by ethyl acetate fractionation.
Toshio Sakamoto+6 more
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Synthesis of a versatile (S)-3-(hydroxymethyl)butane-1,2,4-triol building block and its application for the stereoselective synthesis of N-homoceramides [PDF]
A versatile (S)-3-(hydroxymethyl)butane-1,2,4-triol building block has been synthesized starting from D-isoascorbic acid, a common food preservative. The key transformation in this approach was the introduction of branching through a high yield and fully
Hillaert, Ulrik, Van Calenbergh, Serge
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Branched deoxyaldaric acids from alkaline degradation of carbohydrates: Structure determination by mass spectrometry of trimethylsilyl derivatives [PDF]
The deoxyaldaric acids corresponding in structure to the 3-deoxy-2-C-(hydroxymethyl)aldonic (isosaccharinic) acids have been identified as products of treatment of various carbohydrates with alkali and oxygen-alkali.
Petersson, Göran
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