Results 141 to 150 of about 36,528 (313)

Synthesis of the Phospha‐Wittig Reagent Me3P = P(C2F5) and Generation of a Phospanyl‐Wittig Derivative Me3P = C(CF3)P(C2F5)F

open access: yesChemistry – A European Journal, EarlyView.
The first example of a simple alkylated phosphinidene‐adduct (“phospha‐Wittig”) is reported. The synthesis of Me3PPC2F5 was enabled through reaction of the cyclotetraphosphane (PC2F5)4 with PMe3. The phosphanyl‐functionalized Wittig reagent Me3PC(CF3)P(C2F5)F was prepared by treating the diphosphane P2(C2F5)4 with PMe3.
Lukas Hartmann   +7 more
wiley   +1 more source

The coupling of motion and conductive heating of a gas by localized energy sources

open access: yes, 2003
This paper investigates the time evolution of the near-isobaric flow field produced in a gas after the sudden application of a constant heat flux from a localized energy source.
Liñán Martínez, Amable   +5 more
core   +1 more source

Influence of Particle Size, Moisture, and Cloud Density on Wood Dust Ignition

open access: yesChemie Ingenieur Technik, EarlyView.
The ignition and combustion of particle clouds are strongly affected by particle interactions. This study uses spectroscopy to examine effects of particle size, water content, and cloud density. Results show ignition delay rises with larger size and density, whereas combustion duration depends mainly on water and density due to moisture‐driven ...
Matteo Giesen   +2 more
wiley   +1 more source

Design and implementation of a 3D‐printed modular distillation tower for experimental teaching in chemical engineering

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Several authors have reported the disconnection between the skills, abilities, and attitudes of graduates from STEM careers with the current needs of the labour market. In science and engineering fields, research has found the need for interdisciplinary approaches that encourage meaningful learning.
Úrsula Manríquez‐Tolsá   +7 more
wiley   +1 more source

The development of an enhanced autoignition sub-model for use in CFD combustion simulations

open access: yes, 2006
Includes bibliographical references.With the ever increasing pressure to manufacture more efficient engines that produce lowerexhaust emissions, there is a corresponding need for a greater understanding of the combustion processes within these engines ...
Cox, Ryan
core  

A‐optimal model‐based design of experiments for processes with uncertain inputs

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Model‐based design of experiments (MBDoE) techniques are tools for selecting experimental conditions that enable accurate parameter estimation for mechanistic models. Most MBDoE approaches assume that the selected experimental conditions will be implemented perfectly, without uncertainties in the independent variables.
Bright Ofori   +3 more
wiley   +1 more source

Studies on SI engine simulation and air/fuel ratio control systems design [PDF]

open access: yes, 2013
This thesis was submitted for the degree of Doctor of Philosophy and awarded by Brunel University.More stringent Euro 6 and LEV III emission standards will immediately begin execution on 2014 and 2015 respectively.
Bai, Yang, Yang Bai
core  

Natural South African iron‐rich sand as a functional catalyst in hybrid photocatalytic wet peroxide oxidation technology for the degradation of methyl orange dye pollutant

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
This research explored South African iron‐rich sand (SAIRS) as a natural catalyst for light‐mediated wet peroxide oxidation of methyl orange dye in wastewater and at an optimized of conditions of 3500 mg/L catalyst dose, 6 mM H2O2, and pH 2.5, SAIRS achieved 94% methyl orange degradation within 90 min under visible light.
Aaliyah Ebrahim   +3 more
wiley   +1 more source

First-stage ignition delay: Application of a fast in-situ temperature sensor

open access: yes, 2017
A fast temperature sensor based on intrapulse absorption has been applied to cases of two-stage ignition of iso-octane in a rapid compression machine. Two pulsed quantum cascade lasers at 5.46 and 5.60 µm respectively were used to record the spectra of ...
Farooq, Aamir, Nasir, Ehson Fawad
core  

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