Results 181 to 190 of about 140,654 (327)

AgBF4‐Induced Site‐Selective Synthesis of 4‐Sulfonylindoles in Au‐Catalyzed Cyclization‐Sulfonyl Migration Reactions

open access: yesChemistry – A European Journal, EarlyView.
Site‐selective synthesis 4‐suflonylindoles was achieved by a cyclization‐rearrangement strategy by π‐Lewis acidic gold catalysts and the aid of silver cocatalyst. Particularly, the use of 3 equivalents of AgBF4 to SPhosAuCl is crucial for C4‐selective migration of the sulfonyl group.
Itaru Nakamura   +2 more
wiley   +1 more source

Leveraging microbiota-metabolites to reduce inflammation and promote functional recovery following spinal cord injury in female mice. [PDF]

open access: yesBrain Behav Immun Health
Douthitt AJ   +5 more
europepmc   +1 more source

Catalytic Amyloids: Turning Fibrils Into Biocatalysts

open access: yesChemistry – A European Journal, EarlyView.
Amyloids, traditionally associated with diseases, have emerged as versatile catalytic scaffolds. From natural amyloid sequences to bioinspired and de novo designs, we highlight strategies to construct catalytic active sites and anchor enzymes onto fibrils, creating versatile nanomaterials with tunable activities. ABSTRACT Amyloids have been regarded as
Alessandra Esposito   +3 more
wiley   +1 more source

Reprogramming offspring liver health: maternal indole supplementation as a preventive strategy against MASLD. [PDF]

open access: yesEBioMedicine
Mandala A   +15 more
europepmc   +1 more source

Harnessing Toluene Solvent as a Reactant: Regioselective Benzyl Radical Addition to Multi‐π 1,5‐Enynes in a Copper‐Catalyzed Cascade to Indenes

open access: yesChemistry – A European Journal, EarlyView.
A copper‐catalyzed three‐component radical cascade of 1,5‐enynes with toluene and benzoic acids enables regioselective benzyl radical addition to multi‐Π systems, efficiently delivering polysubstituted indenes from an abundant solvent feedstock. ABSTRACT C─H activation of toluene generates a benzyl radical that undergoes C─C coupling, converting an ...
Saideh Rajai‐Daryasarei   +7 more
wiley   +1 more source

Synthetic Studies towards Darobactin A

open access: yesChemistry – A European Journal, EarlyView.
The urgent need for new antibiotics led us to develop a new methodology for the synthesis of the natural product darobactin A selectively targeting gram‐negative bacteria. This study provides new insights into the synthesis of strained indole‐containing macrocycles.
Till Steiner   +4 more
wiley   +1 more source

Phosphoserine phosphatase B facilitates indole metabolism to indole-3-lactic acid. [PDF]

open access: yesAppl Microbiol Biotechnol
Konishi H   +5 more
europepmc   +1 more source

Bottom‐up Strategies for Generating Polymer Protocells That Mimic Cellular Communication

open access: yesChemistry – A European Journal, EarlyView.
This review focuses on polymeric protocells produced using a bottom‐up approach. Polymer‐based assemblies guarantee stability and designability by adjusting the properties of the amphiphilic copolymers used. The review covers protocell architectures, production, and their intra‐ and intercellular communication mechanisms.
Gloria Saorin   +3 more
wiley   +1 more source

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