Results 51 to 60 of about 1,818 (183)
Detection of Deuterated Formaldehyde in Interstellar Clouds [PDF]
AbstractDeuterated formaldehyde has been detected for the first time in interstellar clouds; the observed ratio HDCO/H2CO implies formation by gas phase chemistry.
William D. Langer +3 more
openaire +1 more source
Prebiotic Organic Chemistry of Diketopiperazines
Diketopiperazines (DKPs) are considered essential in many life forms, but their prebiotic importance has not been fully understood. This review aims to discuss prebiotic organic chemistry for experimentally and computationally simulated reactions involving DKPs. ABSTRACT Even though the significance of amino acids and polypeptides is well recognized in
Jun Ohata
wiley +1 more source
New calculations have been applied to the pyrolysis of pyrrole under shock‐tube conditions and to the radical‐radical reaction between allyl and •CN at low temperature and pressure, using the same mechanistic scheme for both. ABSTRACT The pyrolysis of pyrrole has previously been studied in shock‐tube experiments and in jet‐stirred reactors. The results
Barry K. Carpenter
wiley +1 more source
The Determination of Electron Abundances in Interstellar Clouds [PDF]
A new method for estimating electron fractions in shielded molecular clouds is proposed on the basis of gas phase ion-molecule reactions which involves measuring the quantity . Applied to existing data, it yields upper limits to Xe in the range from 10−8 to 10−7 for a variety of clouds, warm as well as cool.
A. Wootten, R. Snell, A. E. Glassgold
openaire +1 more source
Abstract Xenon (Xe) is a heavy noble gas with intriguing chemical properties, such as having several stable isotopes and the ability to form compounds under extreme conditions. Despite the predictions based on cosmochemical models that suggest xenon should be relatively abundant in planetary reservoirs, empirical data indicate a significant depletion ...
Avinash Kumar Both +2 more
wiley +1 more source
Boron abundances in diffuse interstellar clouds [PDF]
AbstractWe present a comprehensive survey of B abundances in diffuse interstellar clouds from HST/STIS observations along 56 Galactic sight lines. Our sample is the result of a complete search of archival STIS data for the B II λ1362 resonance line, with each detection confirmed by the presence of absorption from other dominant ions at the same ...
Ritchey, A. M. +3 more
openaire +2 more sources
First Principles Rovibronic Absorption Spectra of HF Molecule
Hydrogen fluoride (HF) is astrophysically important, as it has been detected in sunspots, Venus, red giants, and the interstellar medium, serving as a probe of exoplanet atmospheres. This article presents an ab initio investigation of HF rovibronic spectroscopy, combining high‐level electronic‐structure data with nuclear‐motion solutions and refinement
Nariman Abu El Kher +5 more
wiley +1 more source
THE ABUNDANCE OF BORON IN DIFFUSE INTERSTELLAR CLOUDS [PDF]
We present a comprehensive survey of boron abundances in diffuse interstellar clouds from observations made with the Space Telescope Imaging Spectrograph (STIS) of the Hubble Space Telescope. Our sample of 56 Galactic sight lines is the result of a complete search of archival STIS data for the B II 1362 resonance line, with each detection confirmed by ...
Ritchey, A. M. +3 more
openaire +3 more sources
ABSTRACT Planetary nebulae represent a late evolutionary phase of low‐ to intermediate‐mass stars. In this article, we present the serendipitous discovery of a previously unknown, faint potential Galactic planetary nebula (PN) in the constellation Camelopardalis, identified during a survey‐inspection, aiming at the detection of dwarf companions of the ...
W. E. Celnik +12 more
wiley +1 more source
Confined Chemistry in Space: Zeolite‐Supported Fe13 Nanoclusters Modulate CS Reactivity
The study explores how an Fe13 cluster confined in chabazite reshapes the reaction of CS and H2 under astrochemical conditions. Confinement promotes C–S bond cleavage over hydrogenation, directing chemistry toward CH4 and H2S formation. Additional CS enables CS2 and C2 species. Microkinetic analysis identifies protoplanetary environments where zeolites
Gerard Pareras, Albert Rimola
wiley +1 more source

