Results 31 to 40 of about 1,113,005 (163)

The Rich Chemistry of Ionized Methanol With Sulfur Dioxide: Pathways to Prebiotic and Elusive Species in Earth's Atmosphere and Space

open access: yesChemistry – A European Journal, EarlyView.
The reaction between the methanol radical cation and sulfur dioxide is remarkably fast and forms several ionic and neutral products (HOSOH+, CH2OSO+, CH2OH+, CH2O, H2O, HSO2). The chemistry goes beyond simple proton or hydrogen transfer, revealing a close interaction between the two species, relevant to atmospheric and astrochemical environments where ...
Mauro Satta   +3 more
wiley   +1 more source

The formation of molecular hydrogen in the interstellar medium [PDF]

open access: yes, 2010
H2 is the most abundant molecule in the interstellar medium and forms on the surface of interstellar dust grains. Laboratory studies have been conducted of HD formation on a dust grain analogue, which is a highly-oriented pyrolytic graphite surface ...
Islam, F.
core  

Interstellar Molecules [PDF]

open access: yes, 1978
Observations of the spectral lines of a great many interstellar molecules has made it possible for radio astronomers to construct a scenario for the formation of ...
Knapp, Gillian
core  

Clathrate hydrate crystallization

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Clathrate hydrate crystallization has been an area of interest to chemical engineers from the point of view of crystal structure, thermophysical properties, phase equilibria, kinetics, industrial applications, and environmental (climate change) implications.
Peter Englezos
wiley   +1 more source

A Complete HCN Survey of the Perseus Molecular Cloud

open access: yesThe Astrophysical Journal, 2023
We present a survey of the Perseus molecular cloud in the J = 1 → 0 transition of HCN, a widely used tracer of dense molecular gas. The survey was conducted with the CfA 1.2 m telescope, which at 89 GHz has a beamwidth of 11′ and a spectral resolution of
T. M. Dame, Charles J. Lada
doaj   +1 more source

Size Matters: Barrier Heights and Widths in the Kinetics Of Tautomerisation and Rotamerisation of Thiotropolone and Its Five‐ and Three‐Membered Cyclic Analogues

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT Recent experiments by Nunes et al. have demonstrated that unprecedented control of chemical reactions is possible by narrowband infrared vibrational photo‐excitation at low temperatures in inert matrices. The generated higher energy level conformers may then undergo rotamerisation and tautomerisation reactions which provide extremely useful ...
Judith Wurmel, John M. Simmie
wiley   +1 more source

Survey of CH3NH2 and its Formation Process

open access: yesThe Astrophysical Journal, 2023
We present the observational results of a precursor of glycine, methylamine (CH _3 NH _2 ), together with methanol (CH _3 OH) and methanimine (CH _2 NH) for the high-mass star-forming regions NGC 6334I, G10.47+0.03, G31.41+0.3, and W51 e1/e2 using the ...
Taiki Suzuki   +9 more
doaj   +1 more source

Cis–Trans Rotational Isomerism of Formic Acid, Sulfur, and Selenium Analogues and Their Dimers: Chemical Kinetics Under Interstellar Conditions

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT We present chemical kinetic rate constants for the cis to trans isomerisation or rotamerization of monomeric seleno‐, thio‐, and formic acids and that of three of their dimeric species, based on variational transition state theory and multidimensional tunneling calculations in the gas‐phase, from 10 K to 300 K. These provide, firstly, reliable
Judith Wurmel, John M. Simmie
wiley   +1 more source

The SPHEREx Target List of Ice Sources (SPLICES)

open access: yesThe Astrophysical Journal, 2023
One of the primary objectives of the SPHEREx mission is to understand the origin of molecules such as H _2 O, CO _2 , and other volatile compounds at the early stages of planetary system formation.
Matthew L. N. Ashby   +18 more
doaj   +1 more source

Proximity Proteomics Maps Candidate Cellular Uptake Pathways for Cell‐Derived Nanovesicles

open access: yesSmall Methods, EarlyView.
TurboID‐based dual‐sided proteomics compares mechanically generated cell‐derived nanovesicles with naturally secreted small extracellular vesicles. Vesicle proteomes define candidate interaction signatures, while recipient‐cell proximity labelling identifies exposure‐associated proteins.
Eisuke Kanao   +8 more
wiley   +1 more source

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