Results 41 to 50 of about 7,455 (223)

Modelling and observations of molecules in discs around young stars [PDF]

open access: yes, 2013
This thesis contains a study of molecules within circumstellar discs around young stars. Firstly, the chemistry of a disc around a young, Class 0 protostar is modelled.
Ilee, John David
core  

Deep Search for Phosphine in a Prestellar Core

open access: yesThe Astrophysical Journal Letters
Understanding in which chemical forms phosphorus exists in star- and planet-forming regions and how phosphorus is delivered to planets are of great interest from the viewpoint of the origin of life on Earth.
Kenji Furuya, Takashi Shimonishi
doaj   +1 more source

Energy Landscapes in Chemical Reactions and Transport

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Kinetics/dynamics of chemical reactivity and transport of chemical species in a solid are both determined by the energy landscape in which they take place. Discussing common grounds but also distinct differences may help in advancing the understanding in both fields.
Karl‐Michael Weitzel
wiley   +1 more source

Interstellar atoms, molecules and diffuse bands toward

open access: yes, 2008
Aims. Supernovae offer the unique possibility to probe diffuse extra-galactic sightlines via observation of the optical transitions of atoms, molecules and the diffuse interstellar bands (DIBs).
N. L. J. Cox, F. Patat
core   +1 more source

Accelerated Discovery‐to‐Unveiling of High‐Performance and Affordable Ammonia Electrode Process by Human–Machine Collaboration Framework

open access: yesAngewandte Chemie, Volume 138, Issue 25, 15 June 2026.
By employing dimensionally reduced reaction descriptors, a human–machine collaboration framework for efficient electrochemical nitrate reduction to NH3 electrocatalysts screening is established and drastically shorten the discovery timeframe. A new kinetic model is established in combination with a rotating ring‐disk electrode, unveiling the pivotal ...
Yingying Cheng   +3 more
wiley   +2 more sources

A Framework for Incorporating Binding Energy Distribution in Gas-ice Astrochemical Models

open access: yesThe Astrophysical Journal
One of the most serious limitations of current astrochemical models with the rate equation (RE) approach is that only a single type of binding site is considered in grain surface chemistry, although laboratory and quantum chemical studies have found that
Kenji Furuya
doaj   +1 more source

Chemical Kinetics of 2‐, 4‐, and 2,4‐Seleno‐Uracils at Low Temperatures: Tautomerizations and Rotamerizations on Inert Matrices

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT In the interstellar medium, chemical reactions proceed under conditions vastly different to those on Earth; these include extremely low temperatures and densities and take place in the gas phase and on water–ice grains. Understanding the energetics and more importantly the kinetics of such reactions is of relevance to the consequences on how ...
Judith Wurmel, John M. Simmie
wiley   +1 more source

Organic Chemistry in the H2-bearing, CO-rich Interstellar Ice Layer at Temperatures Relevant to Dense Cloud Interiors

open access: yesThe Astrophysical Journal
Ice chemistry in the dense, cold interstellar medium (ISM) is probably responsible for the formation of interstellar complex organic molecules (COMs). Recent laboratory experiments performed at T ∼ 4 K have shown that irradiation of CO:N _2 ice samples ...
Rafael Martín-Doménech   +3 more
doaj   +1 more source

Size Matters: Barrier Heights and Widths in the Kinetics Of Tautomerisation and Rotamerisation of Thiotropolone and Its Five‐ and Three‐Membered Cyclic Analogues

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT Recent experiments by Nunes et al. have demonstrated that unprecedented control of chemical reactions is possible by narrowband infrared vibrational photo‐excitation at low temperatures in inert matrices. The generated higher energy level conformers may then undergo rotamerisation and tautomerisation reactions which provide extremely useful ...
Judith Wurmel, John M. Simmie
wiley   +1 more source

A Possible Chemical Clock in High-mass Star-forming Regions: N(HC3N)/N(N2H+)?

open access: yesThe Astrophysical Journal Supplement Series, 2023
We conducted observations of multiple HC _3 N ( J = 10−9, 12−11, and 16−15) lines and the N _2 H ^+ ( J = 1−0) line toward a large sample of 61 ultracompact (UC) H ii regions, through the Institut de Radioastronomie Millmétrique 30 m and the Arizona ...
Y. X. Wang   +7 more
doaj   +1 more source

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