Results 41 to 50 of about 35,607 (205)

Structure and Spectroscopy of Criegee Intermediates in Gas‐ and Aqueous Environments

Helvetica Chimica Acta, EarlyView.
ABSTRACT The dynamics and spectroscopy of the small (H2COO) and large (CH3CHOO) Criegee intermediates (CIs) in the gas phase, inside/on water droplets, on amorphous solid water (ASW) and in bulk water are investigated using validated energy functions.
Cangtao Yin, Meenu Upadhyay, Markus Meuwly   +2 more
wiley   +1 more source

A Framework for Incorporating Binding Energy Distribution in Gas-ice Astrochemical Models

The Astrophysical Journal
One of the most serious limitations of current astrochemical models with the rate equation (RE) approach is that only a single type of binding site is considered in grain surface chemistry, although laboratory and quantum chemical studies have found that
Kenji Furuya
doaj   +1 more source

Mind and Cosmos as Throughput Systems: A Convergence Through the Throughput Model

Systems Research and Behavioral Science, EarlyView.
ABSTRACT This paper advances a conceptual and mathematical foundations approach by applying the throughput model (TPM) to cosmic phenomena, reframing the universe as an extended information processing system. TPM's four stages, Perception, Information, Judgement and Decision Choice, are reformulated in explicit information‐theoretic and dynamical ...
Waymond Rodgers
wiley   +1 more source

Synthesis of Conjugated Linear and Cyclic Polyynes by Selective Alkyne Metathesis

Angewandte Chemie, Volume 138, Issue 17, 20 April 2026.
The formation of polyynes with an odd number of conjugated triple bonds is challenging, particularly for complex architectures since most established methods rely on irreversible C–C bond‐forming reactions. To address this, we have developed the synthesis of triynes via alkyne metathesis.
Julien Escudero, Jonathan Long, Dylan Bouëtard, Jennifer Morvan, Mehdi Koohgard, Angelika Neitzel, Dirk Bockfeld, Shedrack Nwachukwu, Thierry Roisnel, Rik R. Tykwinski, Matthias Tamm, Marc Mauduit, Yann Trolez   +12 more
wiley   +2 more sources

Organic Chemistry in the H2-bearing, CO-rich Interstellar Ice Layer at Temperatures Relevant to Dense Cloud Interiors

The Astrophysical Journal
Ice chemistry in the dense, cold interstellar medium (ISM) is probably responsible for the formation of interstellar complex organic molecules (COMs). Recent laboratory experiments performed at T ∼ 4 K have shown that irradiation of CO:N _2 ice samples ...
Rafael Martín-Doménech, Alexander DelFranco, Karin I. Öberg, Mahesh Rajappan   +3 more
doaj   +1 more source

The futuristic manifolds of REM sleep

Journal of Sleep Research, Volume 34, Issue 2, April 2025.
Summary Since one of its first descriptions 70 years ago, rapid eye movement sleep has continually inspired and excited new generations of sleep researchers. Despite significant advancements in understanding its neurocircuitry, underlying mechanisms and microstates, many questions regarding its function, especially beyond the early neurodevelopment ...
Liborio Parrino, Ivana Rosenzweig
wiley   +1 more source

A Possible Chemical Clock in High-mass Star-forming Regions: N(HC3N)/N(N2H+)?

The Astrophysical Journal Supplement Series, 2023
We conducted observations of multiple HC _3 N ( J = 10−9, 12−11, and 16−15) lines and the N _2 H ^+ ( J = 1−0) line toward a large sample of 61 ultracompact (UC) H ii regions, through the Institut de Radioastronomie Millmétrique 30 m and the Arizona ...
Y. X. Wang, J. S. Zhang, H. Z. Yu, Y. Wang, Y. T. Yan, J. L. Chen, J. Y. Zhao, Y. P. Zou   +7 more
doaj   +1 more source

Synthetic Approaches to Complex Organic Molecules in the Cold Interstellar Medium

Frontiers in Astronomy and Space Sciences, 2022
The observation and synthesis of organic molecules in interstellar space is one of the most exciting and rapidly growing topics in astrochemistry.
Eric Herbst, Eric Herbst, Robin T. Garrod, Robin T. Garrod   +3 more
doaj   +1 more source

Ryugu Reference Project: Recommendations from the Measurement Definition Team

Meteoritics &Planetary Science, EarlyView.
Abstract Sample return missions play a significant role in planetary science by providing pristine extraterrestrial materials. JAXA's Hayabusa2 and NASA's OSIRIS‐REx missions have returned samples from the C‐type asteroids Ryugu and Bennu, respectively. The chemical and mineralogical compositions of these samples closely resemble those of CI chondrites,
Tetsuya Yokoyama, Guillaume Avice, Henner Busemann, Nicolas Dauphas, Daniel P. Glavin, Ashley J. King, Thorsten Kleine, Katharina Lodders, Frederic Moynier, Maria Schönbächler, Yoshinori Takano, Kun Wang, Hikaru Yabuta, Yuma Enokido, Ryota Fukai, Shogo Tachibana, Tomohiro Usui   +16 more
wiley   +1 more source

Exploring molecular complexity in the Galactic Center with ALMA

, 2017
The search for complex organic molecules (COMs) in the ISM has revealed chemical species of ever greater complexity. This search relies heavily on the progress made in the laboratory to characterize the rotational spectra of these molecules ...
Belloche, Arnaud
core   +1 more source