Results 181 to 190 of about 93,580 (281)

Intermolecular Electrophilic Germylation Using GeCl4 and Al2Cl6

Angewandte Chemie, EarlyView.
While electrophilic aromatic substitution is well‐established for carbon and silicon‐based electrophiles, it is extremely underdeveloped for germanium. Herein we report the first effective intermolecular Germa–Friedel–Crafts reaction. The process can be modified to enable selective synthesis of the mono‐ or the di‐aryl germane derivatives, ArGeCl3 and ...
Justyna Łosiewicz, Milan Kumar Bisai, Zachary A. Bub, Stuart A. Macgregor, Michael J. Ingleson   +4 more
wiley   +2 more sources

Self‐Limiting Polymerization‐Induced Crystallization‐Driven Self‐Assembly (SL‐PI‐CDSA) Enables Templated Synthesis of Chiral Plasmonic, Hybrid 2D Hexagonal Assemblies

Angewandte Chemie, EarlyView.
This work details the rapid generation (t ≤ 5 min) of size‐tunable, ultralow dispersity (Ð ≤ 1.01) 2D hexagonal nanosheets by self‐limiting polymerization‐induced crystallization‐driven self‐assembly (SL‐PI‐CDSA) of modular and templating poly(aryl isocyanide) block copolymers, with functions that permit post‐polymerization modifications. Specifically,
Randall A. Scanga, Sean H. Sarault, Amin Kiani, Patryk Wąsik, Anthony J. Branco, Sophie A. Harris, Sangmin Jeong, Ali Shahrokhinia, Jake Borges, Cassidy M. Anunciacao, Jayant Kumar, Lawrence M. Wolf, Michael B. Ross, James F. Reuther   +13 more
wiley   +2 more sources

Exploring the Competition between Halogen Bonding and CH Hydrogen Bonding in Bromoarenes Using an Aryldiyne Template. [PDF]

ACS Org Inorg Au
Schultz MA, Randazzo ET, Stindt RA, Riha SC, Scanlon JD, Bosch E, Bowling NP.   +6 more
europepmc   +1 more source

Tandem Reactivity of Metal−Carbon and Carbon−Silicon Bonds in Mononuclear α‐Silyl Organolithium or Organosodium Complexes Towards CO, CO2 and Heteroallenes

Angewandte Chemie, EarlyView.
Anionic α‐silyl alkyl is one of the most used organometallic building blocks and funtional groups. Traditionally, the C─Si bond in these complexes is considered as inert. In this work, we report a series of reactions between mononuclear organo‐lithium and ‐sodium complexes with CO, CO2, or heteroallenes.
Xiao Yang, Jack M. Hemingway, Wataru Kanna, Nathan Davison, Hiroki Hayashi, Louise Male, Paul G. Waddell, James A. Dawson, Erli Lu   +8 more
wiley   +2 more sources

Bayesian Optimization for High-Dimensional Coarse-Grained Model Parameterization: A Case Study on Pebax Polymer. [PDF]

J Chem Theory Comput
Martins CA, Damasceno DA, Hue KY, Rodrigues Miranda C, Müller EA, Vargas-Hernández RA.   +5 more
europepmc   +1 more source

Oxidation State Determines Solvent Structure Around a Manganese–Vanadium Polyoxometalate Water‐Oxidation Catalyst

Angewandte Chemie, EarlyView.
Oxidation state controls microsolvation in the polyoxometalate {MnV}n−$\{{\rm MnV}\}^{n-}$ water‐oxidation catalyst in acetonitrile/water mixtures. The reduced species {MnV}3− attracts a highly structured hydration layer even at low water content, preferentially binding terminal V═O sites and excluding acetonitrile, while oxidized species show weaker ...
Simon Tippner, Moritz Remmers, Sebastian Mai, Boris Mashtakov, Mihail Mondeshki, Carsten Streb, Leticia González   +6 more
wiley   +2 more sources

Chiral Matching between Nucleic Acids and Polypeptides Facilitates Liquid-Liquid Phase Separation. [PDF]

J Phys Chem Lett
Pokhrel P, Zhang Z, Ji J, Shakya S, Jenyk J, Lower A, Janssen M, Mao H.   +7 more
europepmc   +1 more source

K16F/E22F Mutation Promotes Oligomerization and Alters β-Sheet Topology of Aβ16-22 Peptides: Insights from Molecular Dynamics Simulations. [PDF]

ACS Chem Neurosci
Man VH, He X, Niu T, Cai L, Han F, Nguyen P, Wang J.   +6 more
europepmc   +1 more source

Circularly Polarized Luminescent and Melt‐Processable Copper(I)‐Organic Glasses Based on 2,2′‐Bis(diphenylphosphino)‐1,1′‐binaphthyl

Angewandte Chemie, EarlyView.
Homochiral Cu(I) cyanide complexes based on 2,2’‐bis(diphenylphosphino)‐1,1’‐binaphthyl (BINAP) form melt‐quenched and desolvation‐derived metal–organic glasses that exhibit circularly polarized thermally activated delayed fluorescence (TADF) at room temperature, enabling processable chiroptical materials.
Zeyu Fan, Indranil Sen, Roman Pallach, Guo‐Qiang Li, Andreas Steffen, Sebastian Henke   +5 more
wiley   +2 more sources

Golden Molecular Tweezers: Dinuclear Corannulene-Au(I) Acetylide Hosts for Fullerene Binding. [PDF]

Inorg Chem
Álvarez-Llorente N, Diez-Varga A, Masson E, Barbero H, Álvarez CM.   +4 more
europepmc   +1 more source