Mechanically Activated Luminescence in Polyurethanes Incorporating Calixarene Mechanophores
Angewandte Chemie, EarlyView.The conformational flexibility of a calix[4]arene is exploited to obtain a reversible mechanoluminophore featuring a pyrene excimer couple at the upper rim. Stretching a linear polyurethane incorporating such mechanophore results in luminescence color change from yellow–green to blue, consistent with a force‐induced conformational motion of the ...
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