Results 181 to 190 of about 384 (242)
Chemistry – A European Journal, EarlyView.Solvent effects: vibrational circular dichroism (VCD) revealed pronounced solvent‐induced conformational shifts for a tetradentate salen ligand in CDCl3, a solvent generally considered benign. Contrary to the DFT prediction of a single dominant conformer family, quantum cluster growth together with the genetic algorithm guided VCD analysis uncovered ...
Amanda Nhi Tran +9 more
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The Role of Iron‐Hyponitrite Intermediates in Biology and Insights From Synthetic Model Complexes
Chemistry – A European Journal, EarlyView.Despite the difference in active site architecture, NO reduction by different NOR enzymes is expected to be linked by a common intermediate: hyponitrite (N2O22−). However, experimentally, very little is known about the coordination chemistry of iron with hyponitrite and the expected Fe‐hyponitrite intermediates.
Michael O. Lengel, Nicolai Lehnert
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Chemistry – A European Journal, EarlyView.Understanding aromaticity has evolved from benzene‐centric concepts to a broad multidimensional framework spanning organic, inorganic, and excited‐state systems. This review highlights ambiguities between magnetic, electronic, geometric, and energetic descriptors, emphasizing the need for unified, multi‐criteria approaches.
Sílvia Escayola +2 more
wiley +1 more source
The Canadian Journal of Chemical Engineering, EarlyView.Abstract Carbon dioxide‐reduced hydrogen can be synthesized through various methods such as dry‐reforming (DRM), steam reforming (SMR), and partial oxidation (POX). Tri‐reforming of methane (TRM) is a promising technology which combines all the above‐mentioned processes for the simultaneous production of hydrogen and syngas with high energy efficiency.
Paulo A. L. de Souza +3 more
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The Canadian Journal of Chemical Engineering, EarlyView.Abstract Engineering graduate students confuse the scientific method and problem solving when presenting their pre‐doctoral exams and theses: Science discourse adopts question and hypotheses to assert and establish a study's rationale, while it is problem and objectives in engineering design.
Gregory S. Patience +4 more
wiley +1 more source
An Entropy-Based Knowledge Measure for Atanassov's Intuitionistic Fuzzy Sets and Its Application to Multiple Attribute Decision Making. [PDF]
Entropy (Basel), 2018 Wang G, Zhang J, Song Y, Li Q.
europepmc +1 more source
Vine copula knockoffs for variable selection in gene expression studies
Canadian Journal of Statistics, EarlyView.Abstract Identifying clinical and genetic markers is essential for stratifying cancer patients by survival outcomes and guiding personalized treatment strategies. However, gene expression studies often involve high‐dimensional predictors with mixed data types and complex dependence, which complicates reliable variable selection.
José Ulises Márquez Urbina +3 more
wiley +1 more source
Stability of Viscous Three‐Dimensional Stratified Couette Flow via Dispersion and Mixing
Communications on Pure and Applied Mathematics, EarlyView.ABSTRACT This article explores the stability of stratified Couette flow in the viscous 3d$3d$ Boussinesq equations. In this system, mixing effects arise from the shearing background, and gravity acts as a restoring force leading to dispersive internal gravity waves.
Michele Coti Zelati +2 more
wiley +1 more source