Recent Advances in Photocatalyst‐Driven Protein Labeling and Proximity Mapping
Photocatalyst‐driven protein labeling and proximity mapping have rapidly advanced as powerful strategies for spatiotemporal control in complex biological environments. This review integrates recent developments across single‐electron transfer and energy transfer‐based mechanisms and highlights how catalyst design, reactive intermediates, and diffusion ...
Shinichi Sato +3 more
wiley +1 more source
Halogen bond-driven azo-hydrazone tautomerisation: a computational study. [PDF]
Siiskonen A, Priimagi A.
europepmc +1 more source
Oxygen Attachment Dissociation of Protonated Reserpine and Its Analogs
ABSTRACT Rationale Carbon–carbon double bonds are ubiquitous structural motifs in natural products and pose a key challenge in locating their presence in analytes via MS‐based methods. Here, we use the alkaloid reserpine as a model system to examine whether OAD reactions can locate quaternary double bonds embedded in fused multicyclic structures ...
Jack G. Li +5 more
wiley +1 more source
Enabling Fluoroalkyl-Sulfonylalkylation and Fluoroalkyl-Halogenation of Alkenes and Alkynes via Photoredox Catalysis. [PDF]
Hewa Inaththappulige SIN +4 more
europepmc +1 more source
Sultams as Dual Inhibitors of Human Carbonic Anhydrase and Thioredoxin Reductase
A series of sultam‐based N‐acyl derivatives with potential applications as dual TrxR1 and CA inhibitors were synthesized and evaluated. TrxR1 screening identified several active compounds, with inhibitory potency influenced by the type and orientation of substituents.
Aleksandrs Pustenko +8 more
wiley +1 more source
Regioselective Iodination of Arenes Using Iron- or Silver-Catalyzed Activation of <i>N</i>-Iodosaccharin. [PDF]
Majhi PK, Fleming CM, Sutherland A.
europepmc +1 more source
Hydrocarbon α,ω‐dienes are mainly produced from steam‐cracking derivatives, but high costs, complexity, and environmental impact limit their use. This review highlights sustainable paths from biomass and plastic upcycling, and surveys catalytic transformations into carbocycles and specialty polymers, emphasizing their role as modular building blocks ...
Rosa Villaccio, Giuseppe Leone
wiley +1 more source
<i>N</i>-Mesyl-Enabled Cu<sub>2</sub>O Catalysis: Synthesis of (<i>E</i>)-3-Alkylideneisoindolin-1-ones and 3,4-Unsubstituted Isoquinolones via Sequential Alkynylation/Annulation. [PDF]
Ali AR, Hu L.
europepmc +1 more source
Late‐Stage Functionalization of Peptides on the Solid Phase
Peptide modifications are essential to control pharmacodynamic and pharmacokinetic properties of peptide drugs. Consequently, strategies that allow for efficient and rapid incorporation of non‐canonical modifications into peptides in parallel formats are highly sought after.
Marius Werner +2 more
wiley +1 more source
Novel catalytic properties of pyridyl-bonded Pd-catalysts in cross-couplings of aryl halides with phenyl boronic acid under aerobic conditions. [PDF]
Aggarwal R, Bala R, Lobana TS.
europepmc +1 more source

