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Formation of Ion Pairs and Complex Coacervates
2015Over the past several decades, there have been important advances in the field of transdermal drug delivery. However, for most drugs, the successful transdermal delivery is still limited due to the barrier function of the skin. The skin, especially its outermost layer, the stratum corneum (SC), poses a formidable barrier to the penetration of exogenous
Liang Fang, Honglei Xi, Dongmei Cun
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Ion-Pair Interactions of Lanthanide(III) Complexes in Aqueous Solutions
Inorganic Chemistry, 2000The formation of ion-pair adducts between the cationic complex La(THP)3+ (THP = 1,4,7,10-tetrakis(2-hydroxypropyl)-1,4,7,10-tetraazacyclododecane) and the anionic complexes Tm(DOTA)- (DOTA = 1,4,7,10-tetraazacyclododecane-N,N',N",N"'-tetraacetate), Tm(DTPA)2- (DTPA = diethylenetriamine-N,N,N',N",N"-pentaacetate), Tm(TTHA)3- (TTHA ...
D M, Corsi, H, van Bekkum, J A, Peters
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Primary radical ion pairs in photosystem II core complexes
Biochemistry (Moscow), 2014Ultrafast absorption spectroscopy with 20-fs resolution was applied to study primary charge separation in spinach photosystem II (PSII) reaction center (RC) and PSII core complex (RC complex with integral antenna) upon excitation at maximum wavelength 700-710 nm at 278 K. It was found that the initial charge separation between P680* and ChlD1 (Chl-670)
V A, Nadtochenko +5 more
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Ion pair complexes and anion binding in the solution of a ditopic receptor
Dalton Transactions, 2016A comprehensive solid-state and solution study of a ditopic benzo-15-crown-5 bis-urea receptor L toward alkali halides has been presented.
Rissanen Kari, Mäkelä Toni
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Instrumentation Science & Technology, 1999
Abstract A theoretical function model and four correlation equations between slope of electrode, and parameters such as: logβs (where βs is the stability constant of ion-pair complex), dipole moment (μ), molecular refraction coefficient (n20d), plasticizer polarity (er), and partition coefficient of various ions between solution and membrane (k) are ...
Raluca-Ioana Stefan +1 more
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Abstract A theoretical function model and four correlation equations between slope of electrode, and parameters such as: logβs (where βs is the stability constant of ion-pair complex), dipole moment (μ), molecular refraction coefficient (n20d), plasticizer polarity (er), and partition coefficient of various ions between solution and membrane (k) are ...
Raluca-Ioana Stefan +1 more
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Ion-Pairing Assemblies of Oxacorrole AgIII Complex
Organic LettersIn this study, ion pairs of 10-oxacorrole AgIII complex as an aromatic [17]oxaannulene were synthesized, leveraging its small inner cavity. The cation formed solid-state ion-pairing assemblies whose packing structures were governed by the stacking of π-planes along with dipole-dipole, hydrogen-bonding, and C-H···π interactions, depending on the ...
Rima Sengupta +4 more
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Lanthanoid — Transition‐Metal Complexes: From Ion Pairs to Extended Arrays
ChemInform, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
Christine E, Plecnik +2 more
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Ion Pair Complex for Drug Delivery System
2008Isan Journal ofPharmaceutical Sciences, 4, 2, 140 ...
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Size-exclusion chromatography of lignin as ion-pair complex
Journal of Chromatography A, 1997Abstract A high-performance ion-pair size-exclusion chromatography method was developed for analysis of underivatised lignin samples using styrene–divinylbenzene gel columns with tetrahydrofuran as solvent. An extraction method using the quaternary amine methyltrioctylammonium chloride allowed quantitative extraction of kraft lignin, lignosulfonic ...
A Majcherczyk, A Hüttermann
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Formation of a Ferric-Perchlorate Ion-Pair Complex
Nature, 1952IN the course of a spectrophotometric investigation of the hydrolysis of the ferric ion in solutions of ionic strength greater than unity, evidence was obtained that ferric ions entered into complex formation with perchlorate ions. Although it has hitherto been widely assumed that perchlorate anions form no complexes, such interaction might well be ...
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