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Does decreasing ion–ion association improve cation mobility in single ion conductors?

Physical Chemistry Chemical Physics, 2013
We report on poly(ethylene oxide) based single ion conductors for solid polymer electrolytes. The widely agreed upon vehicle for cation movement in PEO-based solid polymer electrolytes is the single cation, in which the cation is solvated by PEO ether oxygens. Here we report a different vehicle that becomes active with strong anion-cation interactions.
Kan-Ju, Lin, Janna K, Maranas
openaire   +3 more sources

Dynamical Ion Association and Transport Properties in PEO-LiTFSI Electrolytes: Effect of Salt Concentration.

Journal of Physical Chemistry B, 2022
The association of ions describes the formation of ion species in electrolyte solutions and is strongly related to the salt concentration. However, the discussion of ion species and their transport is ambiguous in some studies on electrolyte materials ...
Peibin Kang   +7 more
semanticscholar   +1 more source

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