Synthesis and Characterization of Solvent-Complexes of <i>per</i>-Hydroxy Pillar[5]arene and Pillar[5]quinone: Experimental and Computational Insights. [PDF]
Bollabathini V +3 more
europepmc +1 more source
Modulation of Local Environment for Selective Bicarbonate Conversion to Multi‐Carbon Products
Highly porous Cu electrode partially coated with an ionomer/carbon composite enables efficient conversion of bicarbonate to multi‐carbon products. By regulating the local reaction microenvironment, this strategy overcomes selectivity and reaction‐rate limitations, achieving Faradaic efficiencies of 43% for ethylene and 60% for total multi‐carbon ...
Tai Nguyen +15 more
wiley +1 more source
Synthesis and structural elucidation of a novel bis-spirooxindole from isatin and ethylenediamine. [PDF]
Moreno-Gutiérrez I +7 more
europepmc +1 more source
Fluorination of polytriphenylamine lowers the HOMO energy, enabling high‐voltage operation of the PFTPA cathode. Electron‐withdrawing F substituents stabilize the nitrogen redox center and suppress polarization, leading to fast kinetics. The optimized polymer delivers ∼3.75 V vs.
Natalia Voronina +6 more
wiley +1 more source
Preparation and recrystallization of amorphous l-glutamic acid. [PDF]
Liu Y +8 more
europepmc +1 more source
Synthesis of functionalized polyolefins in a new continuous bench‐scale reactor apparatus
Abstract In‐reactor functionalized polyolefins (FPOs), produced by molecular catalysts, are a new class of polymer materials with applications ranging from high performance adhesives to bitumen compatibilization. In this work, we disclose a procedure for the synthesis of FPOs in a new Continuous Bench‐scale Reactor Apparatus (COBRA).
Miloud Bouyahyi +7 more
wiley +1 more source
Cyclometalated Ir(iii) complexes bridged by µ-OH and µ-3,5-bis(4-methoxyphenyl)-pyrazole ligands. [PDF]
Mausami +8 more
europepmc +1 more source
Carbon‐Confined Fe3C/Fe3N Janus Interfaces for Selective Nitric Oxide‐to‐Ammonia Electroreduction
A defect‐rich, graphitic‐carbon‐confined Fe3C/Fe3N Janus catalyst integrates NO transport, adsorption/activation, and interfacial H supply for efficient nitric oxide electroreduction to ammonia. Built from earth‐abundant elements, this architecture enables high‐yield and high‐efficiency NH3 synthesis while valorizing industrial NO emissions.
Jialing Song +10 more
wiley +1 more source
Synthesis of N-Acetyl-D- and -L-Leucine-<sup>13</sup>C<sub>6</sub> Tool Compounds in Neurodegenerative Disease. [PDF]
Crepin D +10 more
europepmc +1 more source
Formation of Gallium Monofluoride in the Coordination Sphere of Nickel
The elusive gas‐phase species gallium monofluoride forms selectively in the coordination sphere of a nickel(II) centre as a product of C(sp3)–F bond activation, with a weakly coordinating anion as the fluorine source. The herein reported gallium monofluoride ligand acts as a very strong σ‐donor ligand at nickel and serves as a fluorine donor towards ...
Johannes Stephan +6 more
wiley +1 more source

