Ag─S Sites Steer Furfural Electroreduction to Furfuryl Alcohol
A simple sulfide incorporation strategy turns silver into a highly active and selective catalyst for furfural electroreduction to furfuryl alcohol. Experiments combined with density functional theory reveal how isolated S sites promote hydrogenation while suppressing hydrofuroin coupling, enabling selective biomass upgrading.
Haibin Ma +6 more
wiley +2 more sources
Mechanochemically Disordered Li2Ta2OCl10 Oxyhalide Unlocks Superionic Conductivity (>10 mS.cm−1)
This work presents a new crystalline oxyhalide, Li2Ta2OCl10, built from [Ta2OCl10]2− dimers. The disorder induced by ball‐milling drives the dramatic 5000‐fold increase in ionic conductivity to reach 11 mS.cm−1. The material shows promise as a solid electrolyte for batteries and opens new prospects for the discovery of new dimer‐based compounds ...
Clément Morel +11 more
wiley +1 more source
Azamacrocycles provide a tunable platform for rapid N‐carboxyanhydride (NCA) Ring‐Opening Polymerization (ROP). Changing the methylation pattern switches the macrocycle from an external catalyst (N14Me3) to a covalent initiator‐catalyst (IniCat, N14Me1), delivering controlled polypeptide growth under open‐vessel conditions.
Paulina Maksym +10 more
wiley +2 more sources
Preparation and Anticancer Activities of Some Amino Acid Methyl Ester Schiff Bases
In this study, we prepared nine Schiff bases by condensation of amino acid methyl esters (isoleucine, phenylalanine and methionine) with salicylaldehyde derivatives (2,4-dihydroxybenzaldehyde, 2-hydroxy-3-methoxybenzaldehyde and 5-bromo-2 ...
Ali Aydın +2 more
doaj
Influence of Furfuryl Alcohol on the Cross-Linking Process of Selected Industrial Phenol-Formaldehyde Resins. [PDF]
Gubernat M +7 more
europepmc +1 more source
Decongested 2D IR Spectra Reveal N-Terminal Helices in Amyloid Oligomers Associated with Type 2 Diabetes. [PDF]
Shivani ST +4 more
europepmc +1 more source
To regulate a distinct degradation pathway introduced by residual monomers in in‐situ gel polymer electrolytes (GPEs), tris(4‐fluorophenyl)phosphine (TFPP) is coupled with a voltage hold (VH) protocol. TFPP first covers the high‐Ni cathode surface and then preferentially decomposes during the hold step, forming a cathode–electrolyte interphase (CEI ...
Sang Goo Kang +4 more
wiley +1 more source
Confined Oxidative Polymerization of Preorganized Aniline Within Cyclodextrin-Based Bimolecular Tube Nanochannels for the Synthesis of Bispolypseudorotaxanes. [PDF]
Deng M +8 more
europepmc +1 more source
Ping–Pong Energy Transfer in a Heteroleptic Mixed‐Chromophore Coordination Cage
Shape‐complementary assembly (SCA) opens access to Pd(II)‐based heteroleptic cages with mixed‐chromophore composition. Transient absorption studies, supported by calculations, point to a “ping–pong” excitation transfer mechanism, significantly extending excited‐state lifetimes and offering new design principles for light‐harvesting, emissive and ...
Irene Regeni +9 more
wiley +1 more source
Design, Synthesis, In Vitro Biological Evaluation, and In Silico Studies of Novel Imidazo[4,5-b]Pyridine-Acrylonitrile-Based Derivatives as VEGFR-2 Inhibitors Against Breast Cancer and Hepatocellular Carcinoma. [PDF]
Mohamed LW, Saadeldin AA, Farag AB.
europepmc +1 more source

