Results 171 to 180 of about 82,211 (300)

Ag─S Sites Steer Furfural Electroreduction to Furfuryl Alcohol

open access: yesAngewandte Chemie, EarlyView.
A simple sulfide incorporation strategy turns silver into a highly active and selective catalyst for furfural electroreduction to furfuryl alcohol. Experiments combined with density functional theory reveal how isolated S sites promote hydrogenation while suppressing hydrofuroin coupling, enabling selective biomass upgrading.
Haibin Ma   +6 more
wiley   +2 more sources

Mechanochemically Disordered Li2Ta2OCl10 Oxyhalide Unlocks Superionic Conductivity (>10 mS.cm−1)

open access: yesAdvanced Energy Materials, EarlyView.
This work presents a new crystalline oxyhalide, Li2Ta2OCl10, built from [Ta2OCl10]2− dimers. The disorder induced by ball‐milling drives the dramatic 5000‐fold increase in ionic conductivity to reach 11 mS.cm−1. The material shows promise as a solid electrolyte for batteries and opens new prospects for the discovery of new dimer‐based compounds ...
Clément Morel   +11 more
wiley   +1 more source

Enhancing Reaction Kinetics and Structural Control in N‐Carboxyanhydride (NCA) Polypeptide Synthesis by Structurally Tuned Azamacrocyclic Ligands

open access: yesAngewandte Chemie, EarlyView.
Azamacrocycles provide a tunable platform for rapid N‐carboxyanhydride (NCA) Ring‐Opening Polymerization (ROP). Changing the methylation pattern switches the macrocycle from an external catalyst (N14Me3) to a covalent initiator‐catalyst (IniCat, N14Me1), delivering controlled polypeptide growth under open‐vessel conditions.
Paulina Maksym   +10 more
wiley   +2 more sources

Preparation and Anticancer Activities of Some Amino Acid Methyl Ester Schiff Bases

open access: yesJournal of the Turkish Chemical Society, Section A: Chemistry
In this study, we prepared nine Schiff bases by condensation of amino acid methyl esters (isoleucine, phenylalanine and methionine) with salicylaldehyde derivatives (2,4-dihydroxybenzaldehyde, 2-hydroxy-3-methoxybenzaldehyde and 5-bromo-2 ...
Ali Aydın   +2 more
doaj  

Influence of Furfuryl Alcohol on the Cross-Linking Process of Selected Industrial Phenol-Formaldehyde Resins. [PDF]

open access: yesPolymers (Basel)
Gubernat M   +7 more
europepmc   +1 more source

Mechanistic Control of Cathode–Electrolyte Interphase Formation in Gel Polymer Electrolyte for Lithium‐Ion Batteries

open access: yesAngewandte Chemie, EarlyView.
To regulate a distinct degradation pathway introduced by residual monomers in in‐situ gel polymer electrolytes (GPEs), tris(4‐fluorophenyl)phosphine (TFPP) is coupled with a voltage hold (VH) protocol. TFPP first covers the high‐Ni cathode surface and then preferentially decomposes during the hold step, forming a cathode–electrolyte interphase (CEI ...
Sang Goo Kang   +4 more
wiley   +1 more source

Ping–Pong Energy Transfer in a Heteroleptic Mixed‐Chromophore Coordination Cage

open access: yesAngewandte Chemie, EarlyView.
Shape‐complementary assembly (SCA) opens access to Pd(II)‐based heteroleptic cages with mixed‐chromophore composition. Transient absorption studies, supported by calculations, point to a “ping–pong” excitation transfer mechanism, significantly extending excited‐state lifetimes and offering new design principles for light‐harvesting, emissive and ...
Irene Regeni   +9 more
wiley   +1 more source

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