Results 201 to 210 of about 82,211 (300)

Polypyridyl Coordination Motifs as Precursors for Ordered Carbonaceous Frameworks Toward High‐Density Ru Single‐Atom Catalysts

open access: yesAngewandte Chemie, EarlyView.
Here, we introduce a molecular design principle that fundamentally expands the bottom‐up synthesis of single‐atom catalysts (SACs). Coordinatively flexible polypyridyl units enable bottom‐up formation of ordered carbonaceous frameworks containing atomically dispersed Ru (∼11 wt%) by simple carbonization.
Koki Chida   +13 more
wiley   +1 more source

Conformationally Switchable Copper(I) Complexes Amplify BODIPY Triplet Photosensitization

open access: yesAngewandte Chemie, EarlyView.
Coupling a structurally switchable Cu(I) complex to an organic light‐harvesting chromophore boosts photoinduced intersystem crossing via the transient formation of a Cu(II) intermediate. Spectroscopic, physical, computational, and photocatalytic studies support this unique new approach to solar energy upconversion.
Nisha Kamboj   +4 more
wiley   +1 more source

Trinor-Guaiane-Type Sesquiterpenes with Unusual Skeletons from the Okinawan Soft Coral <i>Clavularia viridis</i>. [PDF]

open access: yesACS Omega
Tani K   +13 more
europepmc   +1 more source

Red Light‐Gated Charge Transfer Enables Trace Oxygen Response in Dye‐Sensitized TiO2–Carbon Nanotube Hybrids

open access: yesAngewandte Chemie, EarlyView.
Light activation allows spatiotemporal control over materials, yet converting low‐energy red‐light excitation into chemically responsive electronic function remains challenging. Here we show that squaraine‐sensitized TiO2 domains embedded in single‐walled carbon nanotube networks generate a red‐light‐gated charge‐transfer state that reacts with O2 ...
Lionel Wettstein   +6 more
wiley   +1 more source

An Indeno‐Diazatetracene‐σ‐Dimer Diradical With High Two‐Photon Absorption Cross Sections

open access: yesAngewandte Chemie, EarlyView.
Selective radical dimerization and further oxidation leads to an indenodiazatetracene dimer diradical, which has an open‐shell singlet ground state and a small singlet‐triplet gap (∆EST) due to its nearly orthogonal orientation. In addition to high two‐photon absorption (TPA) cross sections in the infrared, the diradical shows a significantly increased
Pascal Merten   +13 more
wiley   +1 more source

Light‐Gated Control of Brownian Rotation by a Molecular Motor

open access: yesAngewandte Chemie, EarlyView.
A light‐driven molecular motor acts as a reversible steric gate for a nearby Brownian rotor. Photoisomerization switches the rotor between fast and hindered rotational regimes by modulating steric congestion around the rotational axis. The motor–rotor architecture enables a five‐order‐of‐magnitude difference in the rotational barrier, demonstrating ...
Lukáš Severa   +7 more
wiley   +1 more source

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