Results 221 to 230 of about 186,089 (306)

Oxidation State Determines Solvent Structure Around a Manganese–Vanadium Polyoxometalate Water‐Oxidation Catalyst

Angewandte Chemie, EarlyView.
Oxidation state controls microsolvation in the polyoxometalate {MnV}n−$\{{\rm MnV}\}^{n-}$ water‐oxidation catalyst in acetonitrile/water mixtures. The reduced species {MnV}3− attracts a highly structured hydration layer even at low water content, preferentially binding terminal V═O sites and excluding acetonitrile, while oxidized species show weaker ...
Simon Tippner, Moritz Remmers, Sebastian Mai, Boris Mashtakov, Mihail Mondeshki, Carsten Streb, Leticia González   +6 more
wiley   +1 more source

Spin‐State Modulation of Atomic Iron Sites Enables Efficient CO2 Electroreduction in Acid Medium

Angewandte Chemie, EarlyView.
An axial oxygen ligand was added to shift the spin state of the single‐atom Fe site from low to medium spin. This change reduces the interfacial interaction with H3O+ and decreases the *CO desorption energy, thus enhancing CO2RR in acidic media.
Shanhe Gong, Yanjie Zhai, Qing Xia, Xu Han, Weisong Li, Yiran Ying, Jie Wu, Yingying Zhou, Xiaojie She, Zhaolong Wang, Chundu Wu, Xiaomeng Lv, Xiao Zhang, Shu Ping Lau   +13 more
wiley   +1 more source

Molecular Structure, Theoretical NBO Analysis, Vibrational Spectrum of CO₂-Responsive Hydroxyamidine-Based Ionic Liquid: A Combined Computational and Experimental Approach. [PDF]

Molecules
Abulyaissova L, Barashkov N, Irgibaeva I, Tashenov Y.   +3 more
europepmc   +1 more source

Solar‐Driven Ammonia Synthesis From Nitrate Reduction Paired With CO2 Capture for Sustainable Agriculture via a Robust CuPd Heterojunction

Angewandte Chemie, EarlyView.
Laser‐assisted synthesis of CuPd amorphous/crystalline heterojunction demonstrates >80% Faradaic efficiency for nitrate‐to‐ammonia electroreduction across wide potential windows. The integrated solar‐powered electrolyzer achieves 6% solar‐to‐ammonia energy efficiency at 0.4 sun, 6–20 mg h−1 CO2 capture rate, and stability exceeding 100 h.
Weihua Guo, Xiaofeng Huang, Yangbo Ma, Yun Song, Zihao Li, Qiang Zhang, Yinger Xin, Jianjun Su, Mingming He, Ruixuan Wang, Rui Xue, Xing Li, Shibo Xi, Jian Wang, Shenlong Zhao, Siwei Zhang, Ben Zhong Tang, Alex K. Y. Jen, Ruquan Ye   +18 more
wiley   +1 more source

Diamine Grafting of Pyrazole-Based MOF-303 for Diluted-Source CO₂ Capture. [PDF]

Small
Mastronardi G, Perego J, Bezuidenhout CX, Temmerman W, Van Speybroeck V, Crocellà V, Bracco S, Li Pira N, Comotti A, Bordiga S.   +9 more
europepmc   +1 more source

Coupling Electrochemical CO2 Reduction With Ethanol Oxidation for Acetate Production in a Dual‐Electrolyzer System

Angewandte Chemie, EarlyView.
A tandem cell system coupling electrochemical CO2 reduction and electrochemical ethanol oxidation is demonstrated for overall acetate production, providing concepts for a CO2‐negative bioethanol to acetate pathway. ABSTRACT Bioethanol production from biomass is suggested as a strategy for greener fuel production.
Anirudha Shekhawat, Shubhadeep Chandra, Ridha Zerdoumi, Bashir Eid, Muhammad Adib Abdillah Mahbub, Wolfgang Schuhmann   +5 more
wiley   +1 more source

Organorhodium and Iridium-Containing Derivatives of the 48-Tungsto-8-phosphate Wheel: Synthesis, Characterization, and Catalytic Activity. [PDF]

Inorg Chem
Mougharbel AS, Bhattacharya S, Sarkar A, Bons AJ, D'hondt T, Jaensch H, Kortz U.   +6 more
europepmc   +1 more source

Circularly Polarized Luminescent and Melt‐Processable Copper(I)‐Organic Glasses Based on 2,2′‐Bis(diphenylphosphino)‐1,1′‐binaphthyl

Angewandte Chemie, EarlyView.
Homochiral Cu(I) cyanide complexes based on 2,2’‐bis(diphenylphosphino)‐1,1’‐binaphthyl (BINAP) form melt‐quenched and desolvation‐derived metal–organic glasses that exhibit circularly polarized thermally activated delayed fluorescence (TADF) at room temperature, enabling processable chiroptical materials.
Zeyu Fan, Indranil Sen, Roman Pallach, Guo‐Qiang Li, Andreas Steffen, Sebastian Henke   +5 more
wiley   +1 more source