Results 221 to 230 of about 82,211 (300)

Mechanophotochemistry: Lighting up EDA Complexes in the Solid State

open access: yesAngewandte Chemie, EarlyView.
Examples of mechanophotochemical EDA complex‐mediated radical reactions, including a Giese reaction, a C─S cross‐coupling reaction, a phosphorylation reaction, and a sulfonylation reaction are shown to rapidly proceed in air using visible light excitation.
Aniket Kumar Srivastawa   +1 more
wiley   +1 more source

Chalcogen‐Bond‐Driven Electrochemical Bromide Sequestration in Benzothiazole‐Functionalized Covalent Organic Frameworks

open access: yesAngewandte Chemie, EarlyView.
To address the unresolved challenge of selective bromide removal from reverse‐osmosis permeate, we developed benzothiazole‐functionalized COF/rGO electrodes that exploit directional chalcogen bonding to preferentially capture Br− over Cl−. The mesoporous BTzTp@rGO electrode achieved a maximum Br− uptake of 36.7 mg g−1, a Br−/Cl− selectivity factor of ...
Najat Maher Aldaqqa   +7 more
wiley   +1 more source

Fine Tuning of Catalyst Active Sites to Access Advanced Ultrahigh‐Melting Polyolefins

open access: yesAngewandte Chemie, EarlyView.
A redesign of the active site of the pyridylamido hafnium (Hf) catalysts can enhance the performance of this catalyst family and unlock previously inaccessible polymer structures. When the catalyst is precontacted with allyltrimethylsilane the active species is modified and the catalyst experiences a new life becoming able to polymerize sterically ...
Fabio De Stefano   +3 more
wiley   +1 more source

Diiron(I) Complexes with Promising Anticancer Properties Obtained by CO-To-Isocyanide Substitution of [Fe2Cp2(CO)4]. [PDF]

open access: yesInorg Chem
Benetti S   +13 more
europepmc   +1 more source

Redox‐Modulated σ‐Bond Reactivity in a Radical‐Anion Dimer

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 44, 26 October 2026.
A radialene‐based radical anion σ‐dimer comprising an elongated C‐C bond exhibits orthogonal stimuli responsiveness. Homolytic cleavage of the dimer to the radical state is triggered by mechanical strain and high temperature. Dimer scission is also achieved via oxidation, resulting in formation of neutral radialenes.
Sushil Ranjan Bhatta   +8 more
wiley   +1 more source

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