Results 41 to 50 of about 74,679 (236)

Reduction and Cycloaddition of Heteroalkenes at Ga(I) Bisamide Center

Reactions
The reactivity of the complex [(dpp-bian)GaNa(DME)2] (1) (dpp-bian = 1,2-bis[(2,6-di-isopropylphenyl)imino]acenaphthene) towards isocyanates, benzophenone, diphenylketene, and 1,2-dibenzylidenehydrazine has been studied.
Vladimir A. Dodonov, Olga A. Kushnerova, Evgeny V. Baranov, Igor L. Fedushkin   +3 more
doaj   +1 more source

Regioselective (thio)carbamoylation of 2,7-di-tert-butylpyrene at the 1-position with iso(thio)cyanates

Beilstein Journal of Organic Chemistry, 2017
It has been found that 2,7-di-tert-butylpyrene reacts with aliphatic iso(thio)cyanates in the presence of trifluoromethanesulfonic acid to exclusively afford the corresponding 1-substituted (thio)amides in high yields.
Anna Wrona-Piotrowicz, Marzena Witalewska, Janusz Zakrzewski, Anna Makal   +3 more
doaj   +1 more source

Bio‐Based Polyurethanes for Sustainable and Multifunctional Applications

Advanced Science, EarlyView.
Bio‐based polyurethanes prepared from vegetable oils, lignin, and polysaccharides have attracted increasing interest as alternatives to fossil‐derived polyurethanes. This review summarizes recent progress in their chemistry, structural engineering, and advanced applications, highlighting the roles of feedstocks, chain‐segment design, dynamic covalent ...
Xin Li, Henghui Deng, Shiwei Yu, Jiawei Huang, Zehong Chen, Dawei Zhao, Chaoqun Zhang   +6 more
wiley   +1 more source

Glutathione reactivity with aliphatic polyisocyanates.

PLoS ONE, 2022
Isocyanate chemicals known to cause adverse health effects when inhaled are essential to making important products and are used in multiple industries. Glutathione (GSH), a major antioxidant of the lower airways with a well described role in xenobiotic ...
Adam V Wisnewski, Jian Liu
doaj   +1 more source

Imbalance of mitochondrial-nuclear cross talk in isocyanate mediated pulmonary endothelial cell dysfunction

Redox Biology, 2013
Mechanistic investigations coupled with epidemiology, case-control, cohort and observational studies have increasingly linked isocyanate exposure (both chronic and acute) with pulmonary morbidity and mortality.
Hariom Panwar, Deepika Jain, Saba Khan, Neelam Pathak, Gorantla V. Raghuram, Arpit Bhargava, Smita Banerjee, Pradyumna K. Mishra   +7 more
doaj   +1 more source

Carbamoylating activity associated with the activation of the antitumor agent laromustine inhibits angiogenesis by inducing ASK1-dependent endothelial cell death. [PDF]

PLoS ONE, 2014
The anticancer agent 1,2-bis(methylsulfonyl)-1-(2-chloroethyl)-2-[(methylamino)carbonyl]hydrazine (laromustine), upon decomposition in situ, yields methyl isocyanate and the chloroethylating species 1,2-bis(methylsulfonyl)-1-(2-chloroethyl)hydrazine ...
Weidong Ji, Mei Yang, Alexandra Praggastis, Yonghao Li, Huanjiao Jenny Zhou, Yun He, Roxanne Ghazvinian, Dylan J Cincotta, Kevin P Rice, Wang Min   +9 more
doaj   +1 more source

Molecular cleft or tweezer compounds derived from trioxabicyclo[3.3.1]nonadiene diisocyanate and diacid dichloride

Beilstein Journal of Organic Chemistry, 2015
The structures of two derivatives of the bisdioxine diisocyanate 1, the bisurea 4 and the biscarbamate 5, are established by X-ray crystallography and DFT calculations.
Gert Kollenz, Ralf Smounig, Ferdinand Belaj, David Kvaskoff, Curt Wentrup   +4 more
doaj   +1 more source

Identification of Isocyanate Number on IPDI and TDI Due to Storage Period and Their Impact on Composite Solid Propellant

Reaktor
Isocyanate compounds serve as a curing agent in the production of composite propellants, playing a crucial role in determining their characteristics. Due to its high reactivity with moisture, it is essential to determine the isocyanate number of stored ...
Anita Pinalia, Ratnawati Ratnawati
doaj   +1 more source

Increase of Exhaled Nitric Oxide (eNO) after Methylene Diphenyl Diisocyanate (MDI) Exposure in Isocyanate Workers with Bronchial Hyperresponsiveness

Allergology International, 2005
Background: : Isocyanates have become one of the most important causes of occupational asthma in industrialized countries. Increased exhaled nitric oxide (eNO) levels have been shown to be associated with allergic airway inflammation.
Xaver Baur, Luba Barbinova
doaj   +1 more source

Durch anomere Amide ermöglichte divergente Synthese unsymmetrischer Harnstoffe, Carbamate, Thioester und Amide aus Aldehyden

Angewandte Chemie, EarlyView.
Eine divergente Aldehyd‐Funktionalisierungssequenz, ermöglicht durch ein anomeres Amid, erlaubt den Ein‐Topf‐Zugang zu unsymmetrischen Harnstoffen, Carbamaten, Thiocarbamaten, Thioestern und Amiden. Entscheidend für diese Transformation ist die Bildung von N‐Boc‐Hydroxamat‐Intermediaten, die als Plattformen für eine orthogonale Aktivierung über Lossen ...
Jasper L. Tyler, Meiyi Zeng, Julius Wiener, Marie‐Christin Leusmann, Colin Stein, Constantin G. Daniliuc, Frank Glorius   +6 more
wiley   +1 more source