Results 51 to 60 of about 73,479 (225)

Synthesis and crystal structure of [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](isocyanato-κN)gold(I)

Acta Crystallographica Section E: Crystallographic Communications
The title complex, [Au(NCO)(C27H36N2)], was synthesized by ligand metathesis from [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I) chloride and sodium cyanate in anhydrous tetrahydrofuran and crystallized from toluene at 233 K in the ...
Abolghasem Bakhoda
doaj   +1 more source

Developing an Efficient and General Strategy for Immobilization of Small Molecules onto Microarrays Using Isocyanate Chemistry

Sensors, 2016
Small-molecule microarray (SMM) is an effective platform for identifying lead compounds from large collections of small molecules in drug discovery, and efficient immobilization of molecular compounds is a pre-requisite for the success of such a platform.
Chenggang Zhu, Xiangdong Zhu, James P. Landry, Zhaomeng Cui, Quanfu Li, Yongjun Dang, Lan Mi, Fengyun Zheng, Yiyan Fei   +8 more
doaj   +1 more source

Phosphorescent Iridium Hydrazinonicotinic Acid (HYNIC) Complexes That Bind to Prostate Specific Membrane Antigen: Potential Photodynamic Therapy of Prostate Cancer

Chemistry – A European Journal, EarlyView.
A phosphorescent iridium(III) complex has been prepared with a 6‐hydrazinonicotinic acid (HYNIC) ligand tethered to a lysine‐ureido‐glutamatic acid pharmacophore, which binds to an enzyme, called prostate‐specific membrane antigen (PSMA), which is overexpressed in prostate cancer.
La'El Kimchi, Emily R. McGowan, Katherine A. Morgan, Jonathan M. White, Trevor A. Smith, Stacey E. Rudd, Paul S. Donnelly   +6 more
wiley   +1 more source

Industrial Byproducts as Adhesive Allies: Unraveling the Role of Proteins and Isocyanates in Polyurethane Wood Bonding

BioResources
Wooden structures are becoming increasingly popular in the construction world. However, these structures often rely on synthetic adhesives, raising concerns about the environmental risks associated with their chemical composition.
Alex Mary, Pierre Blanchet, Simon Pepin, Aurélien Hermann, Stéphane Charron, Véronic Landry   +5 more
doaj   +2 more sources

Determination of phenylurethane and isocyanate groups in isocyanates

, 2020
Reactions of phenylurethane and isocyanate groups of arylisocyanates with secondary amines are studied by IR spectrometry and potentiometric titration. It is found that the rate of the reaction between isocyanate groups and diethylamine is nearly independent of the solvent nature.
Evtushenko Yu.M., Zaitsev B.E., Ivanov V.M.   +2 more
openaire   +1 more source

Low‐Temperature Initiation Enhances HCN and NH3 Formation From Methane and NO Over Pt/Al2O3

Chemistry – A European Journal, EarlyView.
Hydrogen cyanide (HCN) was formed from CH4 and NO over Pt/Al2O3 at low temperatures. Increasing NO concentration and optimizing reaction‐start conditions significantly enhanced HCN yield. In situ FTIR and DXAFS measurements revealed that dynamically balancing Pt‑CO and Pt‑CN surface species, particularly their desorption under temperature‑swing ...
Emika Yamashita, Kyoko K. Bando, Toshitaka Kubo, Atsushi Takagaki   +3 more
wiley   +1 more source

Strain Release of 1‐Azabicyclo[1.1.0]butanes as a Gateway to Highly Functionalized Azetidines: New Strategies and Structural Motifs

Chemistry – A European Journal, EarlyView.
Over the past decade, the interest in azetidines has continuously risen, by virtue of their highly appealing pharmaceutical properties. Monocyclic, spirocyclic, and bridged azetidines can be accessed by leveraging 1‐azabicyclo[1.1.0]butanes as precursors.
Yuri Gelato, Philipp Natho, Marco Colella, Renzo Luisi   +3 more
wiley   +1 more source

Synthesis and Reactivity of 3‐Aminosydnones in Cycloaddition Reactions With Alkynes

Chemistry – A European Journal, EarlyView.
The synthesis, functionalization, and reactivity as dipoles of 3‐aminosydnones have been investigated. These neglected compounds undergo smooth cycloaddition reactions with strained alkynes, leading to 1‐aminopyrazoles. ABSTRACT We present in this article the synthesis, functionalization, and properties of 3‐aminosydnones, a forgotten class of ...
Apolline Dominic, Timothée D'anfray, Guillaume Force, David‐Alexandre Buisson, Maxime Tricoire, Alexis Leblais, Davide Audisio, Frédéric Taran   +7 more
wiley   +1 more source

Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo, Vincenzo Patamia, Chiara Zagni, Antonio Rescifina, Giuseppe Floresta   +4 more
wiley   +1 more source

Rapid Determination of Residues and Migration of Seven Isocyanate Compounds in Food Composite Packaging Bags by Ultra-high Performance Convergence Chromatography [PDF]

Shipin Kexue
An ultra-high performance convergence chromatography (UPC2) method was developed to rapidly determine the residues and migration of seven isocyanate compounds in food composite packaging bags.
QIU Yue, LI Genrong, YU Qiuling, TAN Chaolan, LU Jiali, ZHANG Qing
doaj   +1 more source