Results 21 to 30 of about 57,276 (400)

Residual Isocyanates in Medical Devices and Products: A Qualitative and Quantitative Assessment

open access: yesEnvironmental Health Insights, 2016
We conducted a pilot qualitative and quantitative assessment of residual isocyanates and their potential initial exposures in neonates, as little is known about their contact effect.
Gillian Franklin   +8 more
doaj   +1 more source

Reactivity of Isocyanate-Functionalized Lignins: A Key Factor for the Preparation of Lignin-Based Polyurethanes

open access: yesFrontiers in Chemistry, 2019
Using isocyanate-functionalized Kraft lignin as a reactive macromonomer for the preparation of polyurethane foams by a prepolymer technique is a well-known strategy to incorporate the biomacromolecule into a higher value polymer material.
Mareike Zieglowski   +9 more
doaj   +1 more source

Elimination kinetics of diisocyanates after specific inhalative challenges in humans: mass spectrometry analysis, as a basis for biomonitoring strategies

open access: yesJournal of Occupational Medicine and Toxicology, 2011
Background Isocyanates are some of the leading occupational causes of respiratory disorders, predominantly asthma. Adequate exposure monitoring may recognize risk factors and help to prevent the onset or aggravation of these aliments.
Lemiere Catherine   +4 more
doaj   +1 more source

Epigenetic Markers Are Associated With Differences in Isocyanate Biomarker Levels in Exposed Spray-Painters

open access: yesFrontiers in Genetics, 2021
Isocyanates are respiratory and skin sensitizers that are one of the main causes of occupational asthma globally. Genetic and epigenetic markers are associated with isocyanate-induced asthma and, before asthma develops, we have shown that genetic ...
Laura W. Taylor   +3 more
doaj   +1 more source

Isocyanic acid (HNCO) in the Hot Molecular Core G331.512-0.103: Observations and Chemical Modelling [PDF]

open access: yes, 2021
Isocyanic acid (HNCO) is a simple molecule with a potential to form prebiotic and complex organic species. Using a spectral survey collected with the Atacama Pathfinder EXperiment (APEX), in this work we report the detection of 42 transitions of HNCO in the hot molecular core/outflow G331.512-0.103 (hereafter G331).
arxiv   +1 more source

Direct Access to Chiral Secondary Amides by Copper-Catalyzed Borylative Carboxamidation of Vinylarenes with Isocyanates.

open access: yesJournal of the American Chemical Society, 2019
A Cu-catalyzed borylative carboxamidation reaction has been developed using vinylarenes and isocyanates. Alkynes, branched 1,3-dienes and bicyclic alkenes were also found to be competent coupling partners.
Daniele Fiorito   +3 more
semanticscholar   +1 more source

The ALMA-PILS survey: Detection of CH$_{3}$NCO toward the low-mass protostar IRAS 16293-2422 and laboratory constraints on its formation [PDF]

open access: yesMon. Not. R. Astron. Soc. 469 (2017) 2219-2229, 2017
Methyl isocyanate (CH$_{3}$NCO) belongs to a select group of interstellar molecules considered to be relevant precursors in the formation of larger organic compounds, including those with peptide bonds. The molecule has only been detected in a couple of high-mass protostars and potentially on comets.
arxiv   +1 more source

Thermal curing of an epoxy-anhydride system modified with hyperbranched poly(ethylene imine)s with different terminal groups [PDF]

open access: yes, 2017
New hyperbranched polymers (HBP) have been synthesized by reaction of a poly(ethylene imine) with phenyl and t-butyl isocyanates. These HBPs have been characterized by 1H-NMR (nuclear magnetic resonance of hydrogen) and Fourier transform infrared ...
Acebo Gorostiza, Cristina   +5 more
core   +2 more sources

Green Polyurethanes from Renewable Isocyanates and Biobased White Dextrins

open access: yesPolymers, 2019
Polyurethanes (PUs) are an important class of polymers due to their low density and thermal conductivity combined with their interesting mechanical properties—they are extensively used as thermal and sound insulators, as well as structural and comfort ...
J. Konieczny, K. Loos
semanticscholar   +1 more source

Plant‐based Basic Carbocatalyst for Lactone Ring‐Opening Polymerization and Isosorbide Transesterification with High Efficiency

open access: yesChemCatChem, Volume 15, Issue 1, January 9, 2023., 2023
Carbocatalysis: The synthesized basic carbocatalyst showed high performance in two different base‐catalyzed reactions namely ϵ‐caprolactone ring‐opening polymerization to biodegradable polycaprolactone, as well as isosorbide transesterification to isosorbide bis(methyl carbonate).
Majd Al‐Naji   +3 more
wiley   +1 more source

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