Results 171 to 180 of about 28,445 (269)

Improved Surgical Management of Complex Neonates With Heterotaxy Syndrome. [PDF]

open access: yesWorld J Pediatr Congenit Heart Surg
Mills AC   +7 more
europepmc   +1 more source

Hidden Diradical: Conformational Switch for Solvatochromic NIR Emission With Unity Quantum Yield in Thiele's Hydrocarbon

open access: yesAngewandte Chemie, EarlyView.
Halogen substitution controls a conformational switch between a folded closed‐shell and a flat singlet‐diradical conformer in an air‐stable Thiele‐diradical. This conformational switch allows for near‐unity photoluminescence quantum yield with a large Stokes shift, solvatochromism, and a long‐lived excited state.
Matteo Bevilacqua   +11 more
wiley   +2 more sources

Mining extreme properties from a large metamaterial database. [PDF]

open access: yesNat Commun
Chen J   +6 more
europepmc   +1 more source

Tellurophene‐Induced Triplet–Singlet Spin‐Flip Acceleration: An Advanced Design for Narrowband Organoboron Emitters with Fast Reverse Intersystem Crossing

open access: yesAngewandte Chemie, EarlyView.
Linking an auxiliary dibenzo[b,d]tellurophene unit markedly accelerates exciton spin conversion in multi‐resonance‐type thermally activated delayed fluorescence emitters. Owing to the heavy‐atom effect of tellurium, the corresponding OLEDs retain remarkably high external electroluminescence quantum efficiencies exceeding 25% even at an exceptionally ...
Peiyuan Yang   +3 more
wiley   +2 more sources

Construction of a Two‐Dimensional Molecular Slab with a π‐Extended Hexaarylbenzene Molecule

open access: yesAngewandte Chemie, EarlyView.
A 3D shape‐persistent molecule with a hexaarylbenzene structure consisting of six naphthothiophene diimide units enables the formation of a 2D molecular slab in the solid state, leading to a 2D interactive electronic structure suitable for application to n‐type organic field‐effect transistors.
Haruki Sanematsu   +3 more
wiley   +2 more sources

Copper‐Catalyzed Three‐Component Selective 1,4‐Amino Oxygenation of 1,3‐Dienes

open access: yesAngewandte Chemie, EarlyView.
Enclosed is a copper‐catalyzed selective 1,4‐amino oxgenation of 1,3‐dienes with the presence of a strong Brønsted acid. This three‐component transformation offers a novel and powerful approach to construct (E)‐1,4‐allylic amino oxygenated motifs by the simultaneous installation of structurally diverse alkylamines and alcohols directly onto 1,3‐dienes.
Guangshou Feng   +2 more
wiley   +2 more sources

Host‐Guest Doping Enables Room Temperature Phosphorescence from Triarylboranes

open access: yesAngewandte Chemie, EarlyView.
While pure triarylboranes show RTP in annealed PMMA films, they do not in crystalline form, contrary to our previous report. However, crystalline host‐guest triarylborane systems show persistent afterglow up to 8 s even at 1 ppb guest loading. Computations identify triplet‐triplet energy transfer as the mechanism governing this efficient RTP.
Zhu Wu   +4 more
wiley   +2 more sources

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