A catalytic network embedding a formal rearrangement enables the first catalytic enantioselective multicomponent reaction (MCR) of sulfur ylides. In the presence of a bulky chiral phosphoric acid, the reaction combines sulfoxonium ylides, aldehydes and thiols, and affords synthetically versatile β‐hydroxy‐α‐sulfanyl carbonyl compounds in ...
Nicolò Santarelli +10 more
wiley +1 more source
Ivemark syndrome in an adult with complete atrioventricular septal defect and a single ventricle with L-transposition of the great arteries: a case report. [PDF]
Hibatouallah H +4 more
europepmc +1 more source
Wet transfer of an atomically flat azo‐functionalized 2D covalent organic framework film onto monolayer MoS2 enables clean van der Waals heterostructure devices with reversible photoswitching and multilevel nonvolatile memory. ABSTRACT Two‐dimensional π‐conjugated covalent organic frameworks (2D π‐COFs) combine in‐plane π‐delocalization with periodic ...
Kexin Wang +11 more
wiley +1 more source
Pediatric Congenital Tracheobronchial Variants and Their Clinical Significance for Endotracheal Intubation and Airway Management: A Scoping Review of Fetal, Neonatal, and Pediatric Cases. [PDF]
Kanakaris S +6 more
europepmc +1 more source
A Neutral “Masked” Diborene and Its Reactivity Toward Metal‐Free Pyridine Homocoupling
An unprecedented neutral “masked” diborene, formed via intramolecular arene dearomatization of an N‐heterocyclic imine‐supported free diborene, can be photochemically released to regenerate the highly reactive triplet diborene intermediate. Computational analysis elucidates the bonding situation of the hitherto elusive free diborene species, and the ...
Ke Li +4 more
wiley +1 more source
Comprehensive comparison of fetal right and left atrial isomerism: cardiac and extracardiac malformations, diagnostic accuracy, and survival outcomes. [PDF]
Shu F +5 more
europepmc +1 more source
A 31P{1H} NMR method enabling direct measurement of transmetalation at Ni(II) is disclosed, providing an extensive kinetic dataset. Rates span five orders of magnitude and exhibit strong ligand dependence, with monodentate ligands promoting transmetalation.
Nicholas S. D. Solomon +3 more
wiley +1 more source
Cardiac conduction system malformations in heterotaxy result from dysregulated Pitx2 expression. [PDF]
Joo K +8 more
europepmc +1 more source
Multiphotochromic switching is controlled by silicon valency in a diarylethene‐based molecular architecture. Lewis base coordination gates electronic communication between the photochromic units, thereby enabling selective access to distinct switching states.
Lennart Stoess +2 more
wiley +1 more source
From multiple spleens to absence: Insights from two cases of heterotaxy syndromes. [PDF]
Paudel S +4 more
europepmc +1 more source

