Direct separation of optical isomers of propranolol by HPLC method.
Satoru Kanno
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Geometric Nonuniformity Localizes Valence Orbitals in Gold Clusters: Case Study on [Au23(SC6H11)16]–
The electronic structure of [Au23(SC6H11)16]–, a monolayer‐protected gold cluster with a nonuniform Au13 core, was investigated. Anion photoelectron spectroscopy and density functional theory calculations revealed that the highest occupied molecular orbital (HOMO) and HOMO‐1 are localized on the two triangular Au3 units at the ends of the Au13 core ...
Yosuke Asami +3 more
wiley +1 more source
Halogenated azobenzene acrylates: from efficient solution photoswitching to stable solid-state photochromic materials. [PDF]
Vachtlová M +10 more
europepmc +1 more source
Polymerization of Propenyl Chloride Isomers
Akihiko Shimizu, Takayuki Otsu
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Asymmetric Iron‐Catalyzed Vicinal C(sp3)─H Diamination of Carboxylic Acids
An iron‐catalyzed vicinal α,β‐C(sp3)─H diamination of readily available carboxylic acids furnishes chiral α,β‐diamino acids in a single pot with high regio‐, diastereo‐, and enantioselectivity (up to >20:1 dr and >99% ee). ABSTRACT The direct construction of chiral 1,2‐diamines through the stereoselective functionalization of two vicinal C(sp3)─H bonds
Bing Zhou +5 more
wiley +1 more source
Impact of Counterions on the Electronic Structure and Optical Properties of Water-Soluble Au<sub>25</sub> Clusters. [PDF]
Verma M, Malola S, Häkkinen H.
europepmc +1 more source
Stereoselective Synthesis of the Indole Alkaloids Nitrarine, Nitramidine, and Isomers. A Biomimetic Approach [PDF]
Martin J. Wanner, Gerrit‐Jan Koomen
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Catalytic Functionalization of Unactivated π‐Bonds Enabled by Bidentate Directing Auxiliaries
This review explores how bidentate directing auxiliaries have advanced transition‐metal catalysis for unactivated alkene/alkyne functionalization. By leveraging chelated intermediates, bidentate directing auxiliaries enable precise hydrofunctionalization, difunctionalization, and C─H activation of π‐bonds with unique selectivity and reactivity.
Seunghyeon Cho +4 more
wiley +1 more source
Engineering nitrogen-doped carbon quantum dots: investigating the role of dopant isomer configuration. [PDF]
Rasouli M +5 more
europepmc +1 more source
In situ Raman and FTIR spectroscopic study on the formation of the isomers MIL-68(Al) and MIL-53(Al)
Heidemarie Embrechts +5 more
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