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Journal of Polymer Science, 1959
AbstractThe cyclic C6 and C8 dimers of isoprene have been prepared by thermal dimerization and their physical and chemical properties obtained. The infrared spectra of these substances are also given and are used to confirm the structures deduced chemically.
John L. Binder, Kenneth C. Eberly, George E. P. Smith +2 more
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Dimerisation of isoprene

Journal of Applied Chemistry, 1969
AbstractIsoprene was dimerised by lithium naphthalene to linear isoprene dimer, a mixture of 2,6‐dimethyl‐2,6‐octadiene and 2,7‐dimethyl‐2,6‐octadiene, in 80% yield.
K. Suga +3 more
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Isomerization of OH-Isoprene Adducts and Hydroxyalkoxy Isoprene Radicals

The Journal of Physical Chemistry A, 2002
This paper employs quantum chemical methods to investigate gaps in our understanding of the fates of radical intermediates in the OH-initiated degradation of isoprene. We employ two density functional theory (DFT) approaches: the well-known B3LYP functional and the recently constructed MPW1K functional.
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Isoprene functionalisation