Results 51 to 60 of about 7,916 (223)
CO chemisorption on Ir(111) [PDF]
The adsorption of carbon monoxide on the (111) crystallographic orientation of iridium both at and below room temperature has been investigated using both low‐energy electron diffraction (LEED) and thermal desorption mass spectrometry.
Comrie, C. M., Weinberg, W. H.
core
Modeling adsorption equilibria of xylene isomers in a microporous metal–organic framework [PDF]
Single and multicomponent adsorption equilibria of xylene isomers: o-xylene (o-x), m-xylene (m-x), pxylene (p-x) and ethylbenzene (eb) was investigated on the three dimensional microporous metal–organic framework Zn(BDC)(Dabco)0.5 (BDC = 1,4 ...
Bárcia, Patrick da Silva +5 more
core +1 more source
Analyse Thermodynamique des Isothermes de Sorptions des Figues
In this study, the hygroscopicity and thermodynamic properties of figs were studied to simulate their hygroscopic behavior during storage and drying. The experimental results were analyzed by the nine models of sorption isotherms.
Abdelouahab Benseddik +4 more
doaj
Desorption isotherms and isosteric heat of araticum (Annona crassiflora Mart.) seeds [PDF]
The objective of this study was to determine the desorption isotherms and isosteric heat of Annona crassiflora Mart. seeds, using Akaike information criterion (AIC) and Schwarz’s Bayesian information criterion (BIC) to assist in the choice of the ...
Weder N. Ferreira Junior +5 more
doaj +1 more source
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve +4 more
wiley +1 more source
Dilation kinetics of glassy, aromatic polyimides induced by carbon dioxide sorption [PDF]
Over the past years, the equilibrium sorption of gases in polymers has been intensively studied. Mostly, glassy polymers were investigated because of their excellent selective mass transport properties.
Huisman, I. +4 more
core +2 more sources
Synthesis of a Carbon‐Linked Acyldepsipeptide Derivative
The synthesis of a methylene‐linked acyldepsipeptide (ADEP) is reported. Success relied upon an improve method to generate a versatile vinyl glycine methyl ester synthon and a rationally optimized Grubb’s metathesis. NMR and in silico studies revealed an unusual trans–trans proline orientation for this new unnatural ADEP analog, advancing the ...
Katelyn G. Stevens-Davis +6 more
wiley +1 more source
Diamine Grafting of Pyrazole‐Based MOF‐303 for Diluted‐Source CO2 Capture
Vapor‐phase diffusion of ethylenediamine (EDA) into the pyrazole‐based MOF‐303 framework enables efficient amine grafting via pyrazole deprotonation and ion‐pair–stabilized hydrogen bonding with the pore walls. Spectroscopic analyses elucidate the interaction, while breakthrough experiments confirm the material's performance and cyclability.
Giuseppe Mastronardi +9 more
wiley +1 more source
Adsorption of selected GHG on metal-organic frameworks in the context of accompanying thermal effects [PDF]
Thermal effects accompanying gas sorption on micro- and mesoporous materials provide unique insights into the type, course, and efficiency of sorption. In this study, metal-organic frameworks (MOFs) with different topologies and chemical structures were ...
Aleksandra Gajda +6 more
doaj +1 more source
Solution-Phase Synthesis of Heteroatom-Substituted Carbon Scaffolds for Hydrogen Storage [PDF]
This paper reports a bottom-up solution-phase process for the preparation of pristine and heteroatom (boron, phosphorus, or nitrogen)-substituted carbon scaffolds that show good surface areas and enhanced hydrogen adsorption capacities and binding ...
Ahn, Channing C. +9 more
core +2 more sources

