Combining Stable Isotope Labeling and Candidate Substrate-Product Pair Networks Reveals Lignan, Oligolignol, and Chicoric Acid Biosynthesis in Flax Seedlings (<i>Linum usitatissimum</i> L.). [PDF]
Thiombiano B +6 more
europepmc +1 more source
Rhenium‐Based β‐Galactosidase Probe Allows Senescence Profiling by Mass Cytometry
Senescence‐associated β‐galactosidase (SA‐β‐Gal) activity is a widely accepted biomarker of cellular senescence, yet its integration with other senescence markers has been limited by available detection methods. Here, we introduce ReGal, a mass cytometry‐compatible SA‐β‐Gal activity probe that can be multiplexed with established markers of senescence ...
Adam Tam +4 more
wiley +1 more source
Efficient Segmental Isotope Labeling of Integral Membrane Proteins for High-Resolution NMR Studies. [PDF]
Daniilidis M +4 more
europepmc +1 more source
We address the long‐standing challenge of reactivity–selectivity trade‐off by precisely tuning the redox properties of Fe(IV), rather than simply accelerating its formation, to enable chemically efficient and low‐emission water treatment. ABSTRACT High‐valent iron oxo species (Fe(IV)) are attractive for wastewater treatment because of their high ...
Hongyu Zhou +9 more
wiley +1 more source
Analytical methods for stable isotope labeling to elucidate rapid auxin kinetics in Arabidopsis thaliana. [PDF]
Tang Q, Tillmann M, Cohen JD.
europepmc +1 more source
Efficient photocatalytic nitrate‐to‐ammonia conversion is achieved over an atomically precise Cu4I4 motif through dual‐site cooperation. Lewis‐acidic Cu centers promote nitrate adsorption and activation, while adjacent I sites facilitate active hydrogen generation for stepwise hydrogenation.
Wanting Zhang +13 more
wiley +1 more source
Tracing de novo Lipids using Stable Isotope Labeling LC-TIMS-TOF MS/MS. [PDF]
Castro KD +6 more
europepmc +1 more source
Site‐specific self‐assembly of alkyl thiols on Au/TiO2 enables precise modulation of interfacial electron distribution and the local microenvironment through covalent Au‐thiolate interactions. This site‐specific molecular engineering synergistically promotes surface kinetics and charge separation, suppressing ·O2−‐driven overoxidation and thereby ...
Yaru Shao +11 more
wiley +1 more source
Unraveling Calcium Absorption and Distribution in Peach and Nectarine during Fruit Development through 44Ca Isotope Labeling. [PDF]
Carrasco-Cuello F +3 more
europepmc +1 more source
Beyond the Oxo‐Wall: Synthesis and Reactivity of a Six‐Coordinate Formally CoIV‐Oxo Complex
We present the first example of a six‐coordinate formally Co(IV)‐oxo complex, [Co(TQA)(O)(OH)]+ (1), which exists as an admixture of CoIV‐oxo and CoIII‐oxyl resonance structures. Complex 1 is capable of performing oxygen atom transfer reactions and abstracting moderately strong hydrogen atoms at rates faster than other characterized CoIV‐oxo compounds.
Jason Shearer +6 more
wiley +1 more source

