Results 241 to 250 of about 480,870 (312)

Rhenium‐Based β‐Galactosidase Probe Allows Senescence Profiling by Mass Cytometry

open access: yesAngewandte Chemie, EarlyView.
Senescence‐associated β‐galactosidase (SA‐β‐Gal) activity is a widely accepted biomarker of cellular senescence, yet its integration with other senescence markers has been limited by available detection methods. Here, we introduce ReGal, a mass cytometry‐compatible SA‐β‐Gal activity probe that can be multiplexed with established markers of senescence ...
Adam Tam   +4 more
wiley   +1 more source

Tailoring High‐Valent Iron‐Oxo Species Redox via Extended π‐Fe3d–O2p Orbital Overlapping Toward Chemical‐Efficient Water Purification

open access: yesAngewandte Chemie, EarlyView.
We address the long‐standing challenge of reactivity–selectivity trade‐off by precisely tuning the redox properties of Fe(IV), rather than simply accelerating its formation, to enable chemically efficient and low‐emission water treatment. ABSTRACT High‐valent iron oxo species (Fe(IV)) are attractive for wastewater treatment because of their high ...
Hongyu Zhou   +9 more
wiley   +1 more source

Engineering Atomically Precise Cu4I4 Nanoclusters With Integrated Adsorption and Hydrogenation Functions for Efficient Photocatalytic Nitrate‐to‐Ammonia Conversion

open access: yesAngewandte Chemie, EarlyView.
Efficient photocatalytic nitrate‐to‐ammonia conversion is achieved over an atomically precise Cu4I4 motif through dual‐site cooperation. Lewis‐acidic Cu centers promote nitrate adsorption and activation, while adjacent I sites facilitate active hydrogen generation for stepwise hydrogenation.
Wanting Zhang   +13 more
wiley   +1 more source

Tracing de novo Lipids using Stable Isotope Labeling LC-TIMS-TOF MS/MS. [PDF]

open access: yesJ Vis Exp
Castro KD   +6 more
europepmc   +1 more source

Site‐Specific Molecular Engineering Redirects Radical Pathways for Selective Photocatalytic Coupling of Methane to C2+ Hydrocarbons

open access: yesAngewandte Chemie, EarlyView.
Site‐specific self‐assembly of alkyl thiols on Au/TiO2 enables precise modulation of interfacial electron distribution and the local microenvironment through covalent Au‐thiolate interactions. This site‐specific molecular engineering synergistically promotes surface kinetics and charge separation, suppressing ·O2−‐driven overoxidation and thereby ...
Yaru Shao   +11 more
wiley   +1 more source

Beyond the Oxo‐Wall: Synthesis and Reactivity of a Six‐Coordinate Formally CoIV‐Oxo Complex

open access: yesAngewandte Chemie, EarlyView.
We present the first example of a six‐coordinate formally Co(IV)‐oxo complex, [Co(TQA)(O)(OH)]+ (1), which exists as an admixture of CoIV‐oxo and CoIII‐oxyl resonance structures. Complex 1 is capable of performing oxygen atom transfer reactions and abstracting moderately strong hydrogen atoms at rates faster than other characterized CoIV‐oxo compounds.
Jason Shearer   +6 more
wiley   +1 more source

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