Hydration‐Gated Photoinduced Electron Transfer in BODIPY Dyes
Hydration switches photoinduced electron transfer (PET) ON in alkoxy‐coordinated BODIPY dyes via specific hydrogen bonding. This gating yields a fluorescence lifetime span of ∼6 ns, enabling fluorescence lifetime imaging microscopy (FLIM) contrast in live cells and organoids. ABSTRACT Fluorescent probes based on photoinduced electron transfer (PET) are
Venkata N. K. Mamillapalli +9 more
wiley +1 more source
Automated Metadata Review to Support Result Release in Quantitative Liquid Chromatography Coupled With Tandem Mass Spectrometry Applications. [PDF]
Endt V, Habler K, Vogeser M.
europepmc +1 more source
A Mild Disilane‐Enabled Halide‐to‐Deuterium Manifold With D2O for Aryl and Benzylic Halides
A broadly applicable Pd‐catalyzed dehalogenative deuteration enables efficient conversion of aryl and benzylic halides with inexpensive deuterium oxide (D2O). The method proceeds under exceptionally mild conditions without strong bases, harsh reductants, or stoichiometric Lewis acid halide scavengers, and tolerates a wide range of functional groups ...
Wenliang Wang +5 more
wiley +1 more source
Deer Antler δ<sup>18</sup>O Records Desalination in Israel's Water Supply. [PDF]
Laposki C, Darcy A, Werner N, Hartman G.
europepmc +1 more source
Elucidating Photo‐Kinetic Control in Photothermal Reverse Water‐Gas Shift Reaction
Light directly regulates the rate‐determining step (RDS) in photothermal catalysis. In a Mars–van Krevelen (MvK)‐type reverse water‐gas shift (RWGS) reaction over In‐doped MoO2, light shifts the RDS from the H2‐related reduction half‐reaction to the CO2‐related oxidation half‐reaction, enhancing catalytic activity and lowering the apparent activation ...
Junchuan Sun +13 more
wiley +1 more source
CO<sub>2</sub> and N<sub>2</sub>O Emissions From Vehicles in Seoul Megacity, South Korea: Insights From Mixing Ratio and Stable Isotope Ratios. [PDF]
Kim J +7 more
europepmc +1 more source
One‐Pot Biphasic Photocatalytic CO2‐to‐Carbonylation Cascades
Bioinspired biphasic compartmentalization enables one‐pot cascades where photocatalytic CO2 reduction generates CO for carbonylative cross‐couplings to synthesize complex organic products, including a pharmaceutical. ABSTRACT Photosynthesis compartmentalizes reactions across the thylakoid membrane in vivo to upcycle CO2 into complex chemicals that are ...
Sampurna Mitra +3 more
wiley +1 more source
Direct Competitive Kinetic Isotope Effect Measurement Using Quantitative Whole Molecule Matrix-Assisted Laser Desorption Ionization Time-of-Flight Mass Spectrometry. [PDF]
Kljaic T +5 more
europepmc +1 more source
Mesopore geometry programs the working‐state interface of Fe single sites during nitrate electroreduction. Hexagonal channels reorganize interfacial water and accompany the reversible evolution of isolated Fe─O4‐like sites toward Fe─O─Fe‐like motifs, promoting successive hydrogenation toward NH3 with a Faradaic efficiency of 99.1%.
Xiangyang Liu +8 more
wiley +1 more source

