Results 191 to 200 of about 78,627 (266)

Photochemical Ring Opening of Cyclopropyl Silyl Ethers Enables β–β Coupling, Radical‐Polar Crossover and Annulation

Angewandte Chemie, EarlyView.
A photochemical platform enables β–β coupling of cyclopropyl silyl ethers with electron‐deficient alkenes. The resulting adducts serve as entry points into annulative and radical–polar crossover pathways, providing rapid access to fused, bridged, and spirocyclic architectures, including late‐stage scaffold diversification to diterpene‐like carbocyclic ...
Jacop Rydén, Eilidh Young, Wilma Olsson, Eskil Flodén, Mattias Tan, Sebastian Clementson   +5 more
wiley   +1 more source

Combustion and Pyrolysis EA-IRMS Techniques to Determine the δ²H of Diamonds. [PDF]

Rapid Commun Mass Spectrom
Fourel F, Lécuyer C, Thomassot E, Deloule E, Ojeimi C.   +4 more
europepmc   +1 more source

Ionic Liquid Electrolytes for Extreme Temperature Conditions: Challenges and Perspective

Angewandte Chemie, EarlyView.
Ionic liquids (ILs) have gained great attention as safe electrolyte components in recent years. This review elucidates the temperature effects on IL‐based electrolytes from molecular configurations, physicochemical properties, and interfacial chemistry, raises the challenges and design strategies operating at low‐ and HT, providing valuable guidance ...
En Xie, Chengdong Liu, Xinghao Wang, Jian Wang, Zhen Chen, Huihua Li, Wenlong Cai, Hao Li, Yang Peng, Fanglin Wu, Stefano Passerini, Haolin Tang   +11 more
wiley   +1 more source

Fluorination of Silver Phosphate in Nickel Reaction Vessels for Triple Oxygen Isotope Analysis. [PDF]

Rapid Commun Mass Spectrom
Wostbrock JAG, Yarian D, Chiaravalloti I, Moller SR, Blake RE.   +4 more
europepmc   +1 more source

Water‐Dispersible Ruthenium Nanocatalyst for Carbonyl Reduction With D2 or T2 in Aqueous Media

Angewandte Chemie, EarlyView.
We report the synthesis and characterization of water‐dispersible ruthenium nanoparticles that catalyze the reductive deuteration and tritiation of carbonyl compounds in aqueous media, enabling efficient access to a broad range of isotopically labeled polar molecules, including cyclic peptides, antibody‐drug conjugate linkers, pegylated derivatives ...
Elisa Martinelli, Rafael Jiménez Rioboo, Remo Weck, Sophie Feuillastre, Luis M. Martínez‐Prieto, Grégory Pieters, Volker Derdau   +6 more
wiley   +1 more source

Copper isotope fractionation and copper-to-zinc ratios reveal altered metal homeostasis in prostate cancer. [PDF]

Sci Rep
Raad RJ, Yang SC, Wang JL, Rosenbaum JJ, Nieva J, Kolatkar A, Shishido SN, Berelson WM, West AJ, Kuhn P, John SG.   +10 more
europepmc   +1 more source

An Enzymatic Platform for Late‐Stage (Radio)isotope Labelling of Oligonucleotides With Methyltransferases

Angewandte Chemie, EarlyView.
State‐of‐the‐art synthesis of radiolabelled oligonucleotides involves multi‐step synthesis with high costs, extended timelines and significant radioactive waste generation. Herein, a dual‐methyltransferase platform enables late‐stage, site‐specific labelling, overcoming these limitations through reduced costs, faster turnaround and minimal radioactive ...
Christopher R. B. Swanson, Ulrich Kauhl, Martin R. Edelmann, Florian P. Seebeck   +3 more
wiley   +1 more source

Cupriavidus necator, an alternative source for isotopic enrichment of proteins expressed in insect cells for NMR investigations. [PDF]

J Biomol NMR
Gande SL, Sreeramulu S, Saxena K, Rupprecht F, Langer JD, Heumann H, Schwalbe H.   +6 more
europepmc   +1 more source

Synergy Between Photon‐to‐Phonon Pathway and Active Lattice Oxygen Enables Efficient and Stable Syngas Synthesis

Angewandte Chemie, EarlyView.
This work reports the design of a multifunctional MnOx support coupled with classic Rh catalytic centers for light‐driven dry reforming of methane. Benefiting from efficient photon‐to‐phonon conversion pathway and a dynamic OL‐OV cycle, the catalyst achieves high syngas production rates and light‐to‐chemical energy efficiency without external heating ...
Chengzhi Guo, Apoorv Jain, Junrun Feng, Xinyu Li, Xinru Li, Shuya Jia, Juncong Wang, Leirun Chen, Xinjie Luo, Xiaolei Zhang, Xiyi Li, Yang Lan   +11 more
wiley   +1 more source

Clumped Isotope Temperature Reconstruction Using Stalagmite Drip Cups. [PDF]

Rapid Commun Mass Spectrom
Umbo S, Box M, Intveld A, Longman J, Modestou S, Carolin SA, James DH, Martínez-García A, Lope CP, Brenner M, Hodell D, Breitenbach SFM.   +11 more
europepmc   +1 more source