Crystal structure of K0.75[FeII3.75FeIII1.25(HPO3)6]·0.5H2O, an open-framework iron phosphite with mixed-valent FeII/FeIII ions [PDF]
Single crystals of the title compound, potassium hexaphosphitopentaferrate(II,III) hemihydrate, K0.75[FeII3.75FeIII1.25(HPO3)6]·0.5H2O, were grown under mild hydrothermal conditions. The crystal structure is isotypic with Li1.43[FeII4.43FeIII0.57(HPO3)6]·
Edurne S. Larrea +4 more
doaj +8 more sources
Hydroxonium creatininium bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)nickelate(II) trihydrate [PDF]
The title compound, (C4H8N3O)(H3O)[Ni(C7H3NO4)2]·3H2O, exhibits isotypism with its CoII analogue. All intramolecular distances and angles are similar for the two structures.
Jafar Attar Gharamaleki +3 more
doaj +3 more sources
TlPO3 and its comparison with isotypic RbPO3 and CsPO3 [PDF]
The crystal structure of thallium(I) catena-polyphosphate, TlPO3, contains a polyphosphate chain extending parallel to [010] with a repeating unit of two phosphate tetrahedra.
Matthias Weil
doaj +2 more sources
Synthesis, crystal structure and thermal properties of poly[bis[μ-3-(aminomethyl)pyridine-κ2N:N′]bis(thiocyanato-κN)manganese(II)] [PDF]
The reaction of Mn(NCS)2 with a stoichiometric amount of 3-(aminomethyl)pyridine in ethanol led to the formation of the title compound, [Mn(NCS)2(C6H8N2)2]n, which is isotypic to its Zn, Co and Cd analogues. The manganese cation is located on a centre of
Christoph Krebs +2 more
doaj +2 more sources
Garnet-type Na3Te2(FeO4)3 [PDF]
Na3Te2(FeO4)3 or Na3Te2Fe3O12, trisodium ditellurium(VI) triiron(III) dodecaoxide, was obtained in the form of single-crystals under hydrothermal conditions.
Felix Eder, Matthias Weil
doaj +2 more sources
The crystal structure of a new CdTe2O5 polymorph, isotypic with ∊-CaTe2O5 [PDF]
Single crystals of cadmium pentaoxidoditellurate(IV), CdTe2O5, were obtained as by-products in a hydrothermal reaction of Cd(NO3)2·4H2O, TeO2, H6TeO6 and NH3 (molar ratios 2:1:1:6) at 483 K for seven days.
Felix Eder, Matthias Weil
doaj +2 more sources
Syntheses, Raman spectroscopy and crystal structures of alkali hexafluoridorhenates(IV) revisited [PDF]
The A2[ReF6] (A = K, Rb and Cs) salts are isotypic and crystallize in the trigonal space group type P\overline{3}m1, adopting the K2[GeF6] structure type. Common to all A2[ReF6] structures are slightly distorted octahedral [ReF6]2− anions with an average
James Louis-Jean +5 more
doaj +4 more sources
Single crystals of SnTe3O8 in the millimetre range grown by chemical vapor transport reactions [PDF]
Tin(IV) trioxidotellurate(IV), SnTe3O8, is a member of the isotypic MIVTeIV3O8 (M = Ti, Zr, Hf, Sn) series crystallizing with eight formula units per unit cell in space group Ia\overline{3}.
Michael Ketter, Matthias Weil
doaj +2 more sources
The title compound, dicerium(III) oxidodisilicate, Ce2[Si2O7], was obtained as a by-product in its H-type structure after attempts to synthesize CeSb2O4Cl from fused silica ampoules. It crystallizes isotypically with H-La2[Si2O7].
Ralf Jules Christian Locke +2 more
doaj +2 more sources
The crystal structure of KScP2O7 [PDF]
Single crystals of KScP2O7, potassium scandium diphosphate, were grown in a borate flux. The title compound crystallizes isotypically with KAlP2O7 in space-group type P21/c, Z = 4.
Günther J. Redhammer, Gerold Tippelt
doaj +2 more sources

