Ca2Te3O8, a new phase in the CaO–TeO2 system [PDF]
Single crystals of dicalcium octaoxidotritellurate(IV), Ca2Te3O8, were obtained from a CsCl/NaCl melt with CaO and TeO2 as educts in the molar ratio of 1:2.
Matthias Weil
doaj +2 more sources
Cadmium phosphates Cd2(PO4)OH and Cd5(PO4)2(OH)4 crystallizing in mineral structures [PDF]
Single crystals of two basic cadmium phosphates, dicadmium orthophosphate hydroxide, Cd2(PO4)OH, and pentacadmium bis(orthophosphate) tetrakis(hydroxide), Cd5(PO4)2(OH)4, were obtained under hydrothermal conditions. Cd2(PO4)OH adopts the triplite [(Mn,Fe)
Felix Eder, Matthias Weil
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Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodide [PDF]
The title salt, [Mn(C2H6OS)6]I4, is made up from discrete [Mn(DMSO)6]2+ (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I42− tetraiodide anions.
Md Azimul Haque +3 more
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Tetrakis(4-benzoylpyridine-κN)bis(isothiocyanato-κN)manganese(II) [PDF]
The asymmetric unit of the title compound, [Mn(NCS)2(C12H9NO)4], consists of one MnII cation located on a centre of inversion, one thiocyanate anion and two 4-benzoylpyridine co-ligands.
Carsten Wellm, Christian Näther
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Orthorhombic cerium(III) carbonate hydroxide studied by synchrotron powder X-ray diffraction [PDF]
Cerium(III) carbonate is a precursor material for the synthesis of various Ce-containing compounds. In this work, a synchrotron powder X-ray diffraction study of commercially obtained ‘cerium(III) carbonate hydrate' indicates that multiple Ce-containing ...
Liam A. V. Nagle-Cocco +2 more
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Crystal structure of calcium perchlorate anhydrate, Ca(ClO4)2, from laboratory powder X-ray diffraction data [PDF]
The crystal structure of calcium perchlorate anhydrate was determined from laboratory X-ray powder diffraction data. The title compound was obtained by heating hydrated calcium perchlorate [Ca(ClO4)2·xH2O] at 623 K in air for 12 h. It crystallizes in the
Dongmin Lee +4 more
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Crystal structures of the alkali aluminoboracites A4B4Al3O12Cl (A = Li, Na) [PDF]
Single crystals of alkali aluminoboracites, A4B4Al3O12Cl (A = Li, Na), were grown using the self-flux method, and their isotypic cubic crystal structures were determined by single-crystal X-ray diffraction.
Sho Yoshino +3 more
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Crystal structures of fac-trichloridotris(trimethylphosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs [PDF]
The crystal structures of two solvates of fac-trichloridotris(trimethylphosphane-κP)rhodium(III) are reported, i.e. one with water in the crystal lattice, fac-[RhCl3(Me3P)3]·H2O, and one with methanol in the crystal lattice, fac-[RhCl3(Me3P)3]·0.5CH3OH ...
Joseph S. Merola, Marion A. Franks
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Photochemistry with Chlorine Trifluoride: Syntheses and Characterization of Difluorooxychloronium(V) Hexafluorido(non)metallates(V), [ClOF2 ][MF6 ] (M=V, Nb, Ta, Ru, Os, Ir, P, Sb). [PDF]
Pairing up: Compounds of the [ClOF2]+ cation, [ClOF2][MF6], were obtained from photochemical reactions of oxides or of metals and oxygen with chlorine trifluoride. Two different structural types were observed, depending on the effective ionic radius, reff, of the MV ion.
Scheibe B +3 more
europepmc +2 more sources
The crystal structures of 21 new pyridine‐based Pb(II)‐bromides show that there is a complex relationship between geometrical, steric and electronic aspects in the formation of N−H⋅⋅⋅Br bridges. The interactions also influence the linkage pattern of the PbBrx polyhedra and vice versa. Abstract We have synthesised and characterised 21 new ternary Pb(II)
Michael Krummer +5 more
wiley +1 more source

