“Überschuss”‐Elektronen in LuGe
Angewandte Chemie, Volume 133, Issue 12, Page 6531-6535, March 15, 2021., 2021 Das Germaniummonogermanid wird durch Hochdruck‐ und Hochtemperatur‐Synthese dargestellt. Die chemische Bindung in LuGe wird als kovalent gebundene Zickzackketten von Ge‐Atomen und Lu4‐Polykationen beschrieben, die mit Hilfe „überschüssiger“ Elektronen im Sinne der Zintl‐Bilanz Lu3+(2b)Ge2− × 1 e− gebildet werden.
Riccardo Freccero +7 more
wiley +1 more source
Na3SO4H – ein erster Vertreter der Materialklasse der Sulfathydride
Angewandte Chemie, Volume 133, Issue 11, Page 5747-5751, March 8, 2021., 2021 Mittels exakter Reaktionskontrolle konnte ein neuartiges Sulfathydrid – der erste Vertreter einer neuen Materialklasse – hergestellt werden. Eine Reihe an verschiedenen Methoden, wie Neutronen‐ und Röntgenbeugung, Festkörper‐NMR, Schwingungsspektroskope und Dichtefunktionalberechnungen, wird angewendet.
Alexander Mutschke +6 more
wiley +1 more source
Die ersten zwei Bismutborosulfate – eines davon enthält Oxonium und ein tektosilicatanaloges Anion
Angewandte Chemie, Volume 133, Issue 3, Page 1525-1529, January 18, 2021., 2021 Das erste tektosilicatanaloge Oxoniumbismutborosulfat wurde durch Reaktion von Oleum mit Bismutnitrat und Borsäure erhalten; es zersetzt sich zum ersten Bismutborosulfat, einer ringsilicatanalogen Verbindung, und liefert interessante Einblicke in die Chemie und die Kristallstrukturen dieser weiterhin rasch wachsenden Materialklasse.
Matthias Hämmer +2 more
wiley +1 more source
The Stacking Faulted Nature of the Narrow Gap Semiconductor Sc$_{2}$Si$_{2}$Te$_{6}$ [PDF]
, 2023 Crystals of Sc$_{2}$Si$_{2}$Te$_{6}$ have been grown and its crystal, micro- and electronic structures were investigated. The layered character of the title compound exhibits stacking faults that impede a full structural characterization by single ...
Bette, Sebastian +7 more
core +2 more sources
Synthesis and Crystal Structure of Nb0.84N [PDF]
, 2011 A new compound of the composition Nb0.84N was prepared by ammonolysis of NbO2 at 1100 °C. The crystal structure refinement was performed by the Rietveld method using X-ray and neutron powder diffraction data.
Buchsteiner, Alexandra +3 more
core +2 more sources
catena-Poly[[bis[1-(2-hydroxyethyl)-1H-tetrazole-κN 4]copper(II)]-di-μ-chlorido]: a powder study [PDF]
, 2008 The crystal structure of the title polymeric complex, [CuCl2(C3H6N4O)2]n, was obtained by the Rietveld refinement from laboratory X-ray powder diffraction data collected at room temperature.
Alexander S. Lyakhov +15 more
core +3 more sources
catena-Poly[cobalt(II)-di-μ-chlorido-κ4 Cl:Cl-μ-1,5-dimethyl-1H-tetrazole-κ2 N 3:N 4]: an X-ray powder investigation [PDF]
, 2009 The asymmetric unit of the title compound, [CoCl2(C3H6N4)]n, contains two Co atoms, both lying on inversion centres, two Cl atoms and one 1,5-dimethyltetrazole ligand.
Alexander S. Lyakhov +10 more
core +3 more sources
NaSr(AsO4)(H2O)9: the (Sr,As) analogue of nabaphite and nastrophite [PDF]
, 2009 The crystal structure of the title compound, sodium strontium orthoarsenate(V) nonahydrate, is isotypic with NaSr(PO4)(H2O)9 and the minerals nabaphite [NaBa(PO4)(H2O)9] and nastrophite [Na(Sr,Ba)(PO4)(H2O)9].
Weil, Matthias
core +4 more sources
Acta Crystallographica Section E: Crystallographic Communications, 2016 The title isotypic complexes, bis[μ-5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylato]-κ4N1,O2,N6:O3;κ4O3:N1,O2,N6-bis[diaquamanganese(II)] tetrahydrate, [Mn2(C16H8N4O4)2(H2O)4]·4H2O, (I), and bis[μ-5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylato]-κ4N1,O2 ...
Monserrat Alfonso, Helen Stoeckli-Evans
doaj +1 more source
A contribution to the mineralogy of the Larderello geothermal field. X-ray crystallographic studies on borate minerals "bechilite" and "lagonite" and crystal structure determination of ginorite [PDF]
, 2016 This work reports the results of mineralogical studies on some borate minerals from the Larderello geothermal field. XRD patterns of “bechilite” and “lagonite” confirmed they actually are respectively admixtures of sassolite and ammonioborite, and of ...
Armienti, Pietro +3 more
core +1 more source