Results 121 to 130 of about 3,701 (179)
Some of the next articles are maybe not open access.
Isoxazoles I: Protonation of Isoxazole Derivatives in Aqueous Sulfuric Acid
Journal of Pharmaceutical Sciences, 1973The protonation of 3-amino-5-methylisoxazole, 5-amino-3,4-dimethylisoxazole, sulfamethoxazole (N-sulfanilamido-5-methyl-3-isoxazole), and sulfisoxazole (N-sulfanilamido-3,4-dimethyl-5-isoxazole) in aqueous sulfuric acid was studied. The pKSH+ and log SH+/S or log SH2+2/SH+ values were determined by UV spectrophotometry.
R H, Manzo, M M, De Bertorello
openaire +2 more sources
The Journal of Organic Chemistry, 2019
The first synthesis of isoxazole-4-carboxylic acid derivatives by domino isoxazole-isoxazole isomerization is reported. Fe(II)-catalyzed isomerization of 4-acyl-5-methoxy-/5-aminoisoxazoles (dioxane, 105 °C) leads to the formation of isoxazole-4-carboxylic esters and amides in good yields. 4-Formyl-5-methoxyisoxazoles give methyl oxazole-4-carboxylates
Anna V. Serebryannikova +3 more
openaire +2 more sources
The first synthesis of isoxazole-4-carboxylic acid derivatives by domino isoxazole-isoxazole isomerization is reported. Fe(II)-catalyzed isomerization of 4-acyl-5-methoxy-/5-aminoisoxazoles (dioxane, 105 °C) leads to the formation of isoxazole-4-carboxylic esters and amides in good yields. 4-Formyl-5-methoxyisoxazoles give methyl oxazole-4-carboxylates
Anna V. Serebryannikova +3 more
openaire +2 more sources
Acta Crystallographica Section C Crystal Structure Communications, 1996
The title compound, ethyl 3-(9-anthryl)-5-methyl-4-isoxazolecarboxylate, C 21 H 17 NO 3 , possesses two planar ring systems that lie at 80° from coplanarity. The bond linking the two ring systems is 1.489 (3) A, indicating only partial conjugation between the two ring systems.
M. D. Mosher, N. R. Natale, A. Vij
openaire +1 more source
The title compound, ethyl 3-(9-anthryl)-5-methyl-4-isoxazolecarboxylate, C 21 H 17 NO 3 , possesses two planar ring systems that lie at 80° from coplanarity. The bond linking the two ring systems is 1.489 (3) A, indicating only partial conjugation between the two ring systems.
M. D. Mosher, N. R. Natale, A. Vij
openaire +1 more source
Studies in isoxazole chemistry. IV. Isoxazoles via isoxazolines
Canadian Journal of Chemistry, 19704- or 5-Chloro- or cyanoisoxazoles, 5-chloromethylisoxazoles, and 5-methylisoxazoles were made by the 1,3-dipolar cycloaddition of nitrile oxides to α-halogeno- or α-alkoxyolefins. In the case of cis- and trans-1,2-dichloroethylene, (5a and b) the intermediate cis- and trans-4,5-dichloroisoxalines (6a and b) were isolated.
openaire +1 more source
Transition Metal‐Mediated Functionalization of Isoxazoles: A Review
Asian Journal of Organic Chemistry, 2021Suchithra Madhavan +2 more
exaly
Recent Developments in the Synthesis and Reactivity of Isoxazoles: Metal Catalysis and Beyond
Advanced Synthesis and Catalysis, 2015Michal Szostak, Feng Hu
exaly

