Results 291 to 300 of about 311,275 (344)

Cascade Grignard Addition: Propargyl Claisen Rearrangement for the Stereoselective Synthesis of α-Allene Quaternary Centers in Cyclohexanones. [PDF]

open access: yesOrg Lett
Armendariz-Gonzalez E   +8 more
europepmc   +1 more source

Deconstructive Radical–Radical Coupling for Programmable Remote Acylation

open access: yesAngewandte Chemie, EarlyView.
A unified approach to access a variety of 1,n‐dicarbonyls through a radical‐promoted deconstructive process utilizing dual photocatalysis/carbene catalysis is reported. The utility of this strategy is demonstrated with a broad scope with robust functional group tolerance along with application in the preparation of γ‐amino esters, three‐component ...
Jing Cao   +2 more
wiley   +1 more source

On‐Demand Photodegradable and Thermo‐Reversible, Soft, Transparent Dithioacetal Hydrogels

open access: yesAngewandte Chemie, EarlyView.
A versatile chemical platform for the development of photodegradable and thermally–reversible hydrogels is presented. The hydrogels were synthesized via a step‐growth reaction of a difunctional PEG‐thiol with an aromatic dialdehyde cross‐linker. The photosensitive dithioacetal bonds endowed the material with photodegradable and thermo‐reversible ...
Maria Psarrou   +5 more
wiley   +1 more source

An Atomically Dispersed Photocatalyst for Undirected para‐Selective C─H Bond Functionalizations

open access: yesAngewandte Chemie, EarlyView.
This study presents an atomically dispersed recyclable heterogeneous photocatalytic method for para‐selective trifluoromethylation of electron‐deficient arenes without directing groups. Unlike previous substrate‐dependent approaches, this recyclable, atomically dispersed photocatalyst enables scalable synthesis of bioactive trifluoromethylated ...
Suman Pradhan   +16 more
wiley   +1 more source

Cardiopulmonary responses to acute exogenous ketosis at rest, and during submaximal and maximal exercise. [PDF]

open access: yesPhysiol Rep
Crabtree CD   +14 more
europepmc   +1 more source

Direct Activation of Sulfides by C–H Oxidation with Photoexcited Nitroarenes: Formal Manipulations of the C─S Bond

open access: yesAngewandte Chemie, EarlyView.
Photochemical anaerobic oxidation of sulfides, using nitroarenes as bifunctional reagents, enables the formal manipulation of the C─S bond. The method allows direct and selective access to versatile carbonyl compounds from largely inert sulfides by C–H oxidation, thus avoiding multistep activation by sulfur oxidation.
Valentina D. Cuomo   +2 more
wiley   +1 more source

Breath Acetone Correlates With Capillary β-hydroxybutyrate in Type 1 Diabetes. [PDF]

open access: yesJ Diabetes Sci Technol
Jones KE   +8 more
europepmc   +1 more source

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