Cascade Grignard Addition: Propargyl Claisen Rearrangement for the Stereoselective Synthesis of α-Allene Quaternary Centers in Cyclohexanones. [PDF]
Armendariz-Gonzalez E+8 more
europepmc +1 more source
Deconstructive Radical–Radical Coupling for Programmable Remote Acylation
A unified approach to access a variety of 1,n‐dicarbonyls through a radical‐promoted deconstructive process utilizing dual photocatalysis/carbene catalysis is reported. The utility of this strategy is demonstrated with a broad scope with robust functional group tolerance along with application in the preparation of γ‐amino esters, three‐component ...
Jing Cao+2 more
wiley +1 more source
Not Just an Alternative Energy Source: Diverse Biological Functions of Ketone Bodies and Relevance of HMGCS2 to Health and Disease. [PDF]
Suresh VV+5 more
europepmc +1 more source
On‐Demand Photodegradable and Thermo‐Reversible, Soft, Transparent Dithioacetal Hydrogels
A versatile chemical platform for the development of photodegradable and thermally–reversible hydrogels is presented. The hydrogels were synthesized via a step‐growth reaction of a difunctional PEG‐thiol with an aromatic dialdehyde cross‐linker. The photosensitive dithioacetal bonds endowed the material with photodegradable and thermo‐reversible ...
Maria Psarrou+5 more
wiley +1 more source
Comparison between blood ketone and blood gas analysis indices in management of diabetic ketoacidosis. [PDF]
Yamagishi H+4 more
europepmc +1 more source
An Atomically Dispersed Photocatalyst for Undirected para‐Selective C─H Bond Functionalizations
This study presents an atomically dispersed recyclable heterogeneous photocatalytic method for para‐selective trifluoromethylation of electron‐deficient arenes without directing groups. Unlike previous substrate‐dependent approaches, this recyclable, atomically dispersed photocatalyst enables scalable synthesis of bioactive trifluoromethylated ...
Suman Pradhan+16 more
wiley +1 more source
Cardiopulmonary responses to acute exogenous ketosis at rest, and during submaximal and maximal exercise. [PDF]
Crabtree CD+14 more
europepmc +1 more source
Photochemical anaerobic oxidation of sulfides, using nitroarenes as bifunctional reagents, enables the formal manipulation of the C─S bond. The method allows direct and selective access to versatile carbonyl compounds from largely inert sulfides by C–H oxidation, thus avoiding multistep activation by sulfur oxidation.
Valentina D. Cuomo+2 more
wiley +1 more source
Effect of different cross sections of polyetheretherketone splinting bars in maxillary All-on-4<sup>®</sup> implant supported interim prosthesis: finite element analysis study. [PDF]
Abdelrahman RM+2 more
europepmc +1 more source
Breath Acetone Correlates With Capillary β-hydroxybutyrate in Type 1 Diabetes. [PDF]
Jones KE+8 more
europepmc +1 more source